**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 76-05-1 |Trifluoroacetic acid, biochemical grad| | 200-929-3 |
| |e | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 35 20 52/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes severe burns. Harmful by inhalation. Harmful to aquatic
organisms, may cause long-term adverse effects in the aquatic
environment.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes severe eye burns. May cause blindness. Causes redness and
pain.
Skin:
Causes skin burns. Causes redness and pain. Prolonged contact may
lead to necrosis.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns. May cause
perforation of the digestive tract. Causes cough, sore throat, chest
pain, and lightheadedness.
Inhalation:
Harmful if inhaled. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
Repeated inhalation may cause chronic bronchitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Non-combustible, substance itself does not burn but
may decompose upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 76-05-1:
Russia: 2 mg/m3 TWA
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: APHA: 5 max
Odor: pungent odor
pH: ca.2(100g/l aq.sol.)
Vapor Pressure: 107 mbar @ 25 deg C
Viscosity: 0.813 cP @ 25 deg C
Boiling Point: 72 deg C @ 760 mmHg
Freezing/Melting Point: -15 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density: 1.535g/cm3
Molecular Formula: C2HF3O2
Molecular Weight: 114.02
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, exposure to moist air or water, heat.
Incompatibilities with Other Materials:
Bases, oxidizing agents, reducing agents, metals, acids, caustics
(e.g. ammonia, ammonium hydroxide, calcium hydroxide, potassium
hydroxide, sodium hydroxide), alkalies.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 76-05-1: AJ9625000
LD50/LC50:
CAS# 76-05-1: Inhalation, mouse: LC50 = 13500 mg/m3; Inhalation,
rat: LC50 = 10 gm/m3.
Carcinogenicity:
Trifluoroacetic acid, biochemical grade -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
log POW = -4.1
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TRIFLUOROACETIC ACID
Hazard Class: 8
UN Number: 2699
Packing Group: I
IMO
Shipping Name: TRIFLUOROACETIC ACID
Hazard Class: 8
UN Number: 2699
Packing Group: I
RID/ADR
Shipping Name: TRIFLUOROACETIC ACID
Hazard Class: 8
UN Number: 2699
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 20 Harmful by inhalation.
R 35 Causes severe burns.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 76-05-1: 2
Canada
CAS# 76-05-1 is listed on Canada's DSL List.
CAS# 76-05-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 76-05-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/18/1998 Revision #2 Date: 3/20/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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3-Bromo-4-methylaniline, 97%
| 7745-91-7 |
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2-Amino-3,5-Diiodobenzoic Acid, 98%
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3-Chloro-2-methylpropene tech., 90%
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4-Cyclohexylacetophenone, 98%
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2,4,6-Trihydroxybenzaldehyde, 97%
| 487-70-7 |
|
2-Dodecanone, 95%
| 6175-49-1 |
|
1-(4-Cyanophenyl)-piperazine hydrochloride
| 0-01-1 |
|
9-BBN crystalline dimer, 98%
| 21205-91-4 |
|
2,3-Pyridinedicarboxylic Anhydride,97%
| 699-98-9 |
|
N-tert-Butoxycarbonyl-L-Prolinol
| 69610-40-8 |
|
Toluene, P.A.
| 108-88-3 |
|
Tri-N-Butyl Phosphate
| 126-73-8 |
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Tributylamine, P.A
| 102-82-9 |
|
Chloral hydrate, 98.5%
| 302-17-0 |
|
N-tert-Butoxycarbonyl-D-Prolinol
| 83435-58-9 |
|
3,5-Dimethyl-1-phenylpyrazole, 97%
| 1131-16-4 |
|
(4S)-4-Bromomethyl-2-Phenyl-1,3-Dioxane, 95%
| 201743-52-4 |
|
1,3,5-Trimethylpyrazole, 99%
| 1072-91-9 |
|
Trichloroethylene, reagent ACS, stabilized with 0.5% ethanol
| 64-17-5 |
|
Triethylene glycol, 99%
| 112-27-6 |
|
Triethylenetetramine, 95%
| 112-24-3 |
|
Hexyl Acetate, 99%
| 142-92-7 |
|
3,5-Diacetoxyacetophenone, 98+%
| 35086-59-0 |
|
2,4,5-Trihydroxybenzaldehyde
| 35094-87-2 |
|
Tetrahydroxy-1,4-quinone hydrate
| 123334-16-7 |
|
Trifluoroacetic acid, biochemical grade
| 76-05-1 |
|
Trifluoroacetic anhydride, 99+%
| 407-25-0 |
|
tert-Butanol-d10, 98%
| 53001-22-2 |
|
3-Methyl-2,4-pentanedione, mixture of tautomers, tech. 85%
| 815-57-6 |
|
1-(4-Methylphenyl)-2-methylpiperazine, 1:1 mixture of conformers, 97%
| 35947-11-6 |
|
Tris-(Hydroxymethyl)-Aminomethane, P.A.; Biochemical grade
| 77-86-1 |
|
Sodium phosphate, tribasic dodecahydrate, reagent ACS, powder
| 7601-54-9 |
|
Tungsten(vi) oxide 99+%
| 1314-35-8 |
|
Fluoranthene, 93%
| 206-44-0 |
|
4-Chloro-3-nitrobenzoyl chloride, 98%
| 38818-50-7 |
|
TMIO, 98%
| 0-01-1 |
|
4-Amino-2-chloro-6,7-dimethoxyquinazoline, 97%
| 23680-84-4 |
|
5-Chloro-3-pyridinol, 99%
| 74115-12-1 |
|
2-Chloro-5-chloromethylpyridine, tech. 90%
| 70258-18-3 |
|
7-Acetoxy-4-methylcoumarin, 98%
| 2747-05-9 |
|
3-Amino-2,5-dichlorobenzoic acid, 97%
| 133-90-4 |
|
6,11-Dihydrodibenzo[b,e]Thiepin-11-one, 97%
| 1531-77-7 |
|
Methylcyclopentane, 95%
| 96-37-7 |
|
3-Methylfuran, 98%
| 930-27-8 |
|
2-Amino-6-chloro-4-methoxypyrimidine, 98%
| 5734-64-5 |
|
Urea, 98%, Pearls
| 57-13-6 |
|
Vanillin, 99%
| 121-33-5 |
|
Vinyl acetate monomer, stabilized
| 108-05-4 |
|
N-Methylmaleimide
| 930-88-1 |
|
2-Acetyl-1-tetralone
| 17216-08-9 |
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|