**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 407-25-0 |Trifluoroacetic anhydride | 100 | 206-982-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T C
Risk Phrases: 25 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed. Causes severe burns.Corrosive.Moisture
sensitive.
Potential Health Effects
Eye:
Causes severe eye burns. Contact may cause ulceration of the
conjunctiva and cornea.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
May cause hemorrhaging of the digestive tract. May cause corrosion
and permanent tissue destruction of the esophagus and digestive
tract.
Inhalation:
May cause ulceration and perforation of the nasal septum if inhaled
in excessive quantities. May cause burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Do not ingest or inhale. Discard
contaminated shoes.
Storage:
Store in a cool, dry place. Corrosives area. Keep containers tightly
closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 407-25-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Pungent odor.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 39.4 - 40.0 deg C @ 760.00mmHg
Freezing/Melting Point: - 65.00 - - 0.00 deg
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes in water
Specific Gravity/Density: 1.4870g/cm3
Molecular Formula: C4F6O3
Molecular Weight: 210.03
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, alcohols, water.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 407-25-0: AJ9800000
LD50/LC50:
CAS# 407-25-0: Draize test, rabbit, eye: 5 mg/24H Severe; Draize
test, rabbit, skin: 750 ug/24H Severe.
Carcinogenicity:
Trifluoroacetic anhydride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S.*
Hazard Class: 8 (6.1)
UN Number: 2922
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S.
Hazard Class: 8 (6.1)
UN Number: 2922
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S.
Hazard Class: 8
UN Number: 2922
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T C
Risk Phrases:
R 25 Toxic if swallowed.
R 35 Causes severe burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 407-25-0: 1
Canada
CAS# 407-25-0 is listed on Canada's DSL List.
CAS# 407-25-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 407-25-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Bromo-4-methylaniline, 97%
| 7745-91-7 |
|
2-Amino-3,5-Diiodobenzoic Acid, 98%
| 609-86-9 |
|
3-Chloro-2-methylpropene tech., 90%
| 563-47-3 |
|
4-Cyclohexylacetophenone, 98%
| 18594-05-3 |
|
2,4,6-Trihydroxybenzaldehyde, 97%
| 487-70-7 |
|
2-Dodecanone, 95%
| 6175-49-1 |
|
1-(4-Cyanophenyl)-piperazine hydrochloride
| 0-01-1 |
|
9-BBN crystalline dimer, 98%
| 21205-91-4 |
|
2,3-Pyridinedicarboxylic Anhydride,97%
| 699-98-9 |
|
N-tert-Butoxycarbonyl-L-Prolinol
| 69610-40-8 |
|
Toluene, P.A.
| 108-88-3 |
|
Tri-N-Butyl Phosphate
| 126-73-8 |
|
Tributylamine, P.A
| 102-82-9 |
|
Chloral hydrate, 98.5%
| 302-17-0 |
|
N-tert-Butoxycarbonyl-D-Prolinol
| 83435-58-9 |
|
3,5-Dimethyl-1-phenylpyrazole, 97%
| 1131-16-4 |
|
(4S)-4-Bromomethyl-2-Phenyl-1,3-Dioxane, 95%
| 201743-52-4 |
|
1,3,5-Trimethylpyrazole, 99%
| 1072-91-9 |
|
Trichloroethylene, reagent ACS, stabilized with 0.5% ethanol
| 64-17-5 |
|
Triethylene glycol, 99%
| 112-27-6 |
|
Triethylenetetramine, 95%
| 112-24-3 |
|
Hexyl Acetate, 99%
| 142-92-7 |
|
3,5-Diacetoxyacetophenone, 98+%
| 35086-59-0 |
|
2,4,5-Trihydroxybenzaldehyde
| 35094-87-2 |
|
Tetrahydroxy-1,4-quinone hydrate
| 123334-16-7 |
|
Trifluoroacetic acid, biochemical grade
| 76-05-1 |
|
Trifluoroacetic anhydride, 99+%
| 407-25-0 |
|
tert-Butanol-d10, 98%
| 53001-22-2 |
|
3-Methyl-2,4-pentanedione, mixture of tautomers, tech. 85%
| 815-57-6 |
|
1-(4-Methylphenyl)-2-methylpiperazine, 1:1 mixture of conformers, 97%
| 35947-11-6 |
|
Tris-(Hydroxymethyl)-Aminomethane, P.A.; Biochemical grade
| 77-86-1 |
|
Sodium phosphate, tribasic dodecahydrate, reagent ACS, powder
| 7601-54-9 |
|
Tungsten(vi) oxide 99+%
| 1314-35-8 |
|
Fluoranthene, 93%
| 206-44-0 |
|
4-Chloro-3-nitrobenzoyl chloride, 98%
| 38818-50-7 |
|
TMIO, 98%
| 0-01-1 |
|
4-Amino-2-chloro-6,7-dimethoxyquinazoline, 97%
| 23680-84-4 |
|
5-Chloro-3-pyridinol, 99%
| 74115-12-1 |
|
2-Chloro-5-chloromethylpyridine, tech. 90%
| 70258-18-3 |
|
7-Acetoxy-4-methylcoumarin, 98%
| 2747-05-9 |
|
3-Amino-2,5-dichlorobenzoic acid, 97%
| 133-90-4 |
|
6,11-Dihydrodibenzo[b,e]Thiepin-11-one, 97%
| 1531-77-7 |
|
Methylcyclopentane, 95%
| 96-37-7 |
|
3-Methylfuran, 98%
| 930-27-8 |
|
2-Amino-6-chloro-4-methoxypyrimidine, 98%
| 5734-64-5 |
|
Urea, 98%, Pearls
| 57-13-6 |
|
Vanillin, 99%
| 121-33-5 |
|
Vinyl acetate monomer, stabilized
| 108-05-4 |
|
N-Methylmaleimide
| 930-88-1 |
|
2-Acetyl-1-tetralone
| 17216-08-9 |
|
|