**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1125-99-1 |1-(Pyrrolidino)-1-cyclohexene | 97 | 214-414-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: 10
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable.The toxicological properties of this material have not
been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. Ingestion of large amounts may cause CNS
depression.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Aspiration may lead
to pulmonary edema. Vapors may cause dizziness or suffocation. May
cause burning sensation in the chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Do NOT use straight streams of water. Use water spray,
dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Cover with sand, dry lime or soda ash and place in a closed
container for disposal. Remove all sources of ignition. Use a
spark-proof tool. Provide ventilation. A vapor suppressing foam may
be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Avoid contact with heat,
sparks and flame. Avoid ingestion and inhalation. Wash clothing
before reuse. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Personal Protective Equipment
Eyes:
Wear chemical goggles. Wear safety glasses and
chemical goggles if splashing is possible. Wear
appropriate protective eyeglasses or chemical safety
goggles as described by OSHA's eye and face protection
regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR ??1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Appearance: clear yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 114.0 - 115.0 deg C @ 15.00mm
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 39 deg C ( 102.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: .9400g/cm3
Molecular Formula: C10H17N
Molecular Weight: 151.25
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1125-99-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-(Pyrrolidino)-1-cyclohexene -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Dangerous Goods Code: 3(31C)
UN Number: 1993
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 1125-99-1: No information available.
United Kingdom Occupational Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1125-99-1 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 1125-99-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 8/02/2000
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tetrahydropyran-2-Methanol, 98%
| 100-72-1 |
|
Molecular sieves, 4a, 8 to 12 mesh
| 70955-01-0 |
|
1-Chloro-4-nitrobenzene, 99%
| 100-00-5 |
|
L-Strychnine, 98%
| 57-24-9 |
|
2-Nitrophenylacetic acid, 99%
| 3740-52-1 |
|
3-Chlorothiophene-2-carboxylic acid, 99+%
| 59337-89-2 |
|
4-Biphenylacetic acid, 98%
| 5728-52-9 |
|
N,N-Diethylnipecotamide, Tech.
| 3367-95-1 |
|
2-Hydroxy-5-methylbenzophenone
| 1470-57-1 |
|
2-Chloro-4-nitrobenzoic acid, 98%
| 99-60-5 |
|
3-(3-(Trifluoromethyl)Phenoxy)Benzaldehyde 97%
| 78725-46-9 |
|
Ethylenediaminetetraacetic acid, tetrasodium salt, hydrate , 99%
| 64-02-8 |
|
3,4-Dinitrobenzoic acid, 99%
| 528-45-0 |
|
Methyltrichlorosilane, 98%
| 75-79-6 |
|
2,2'-Dinitrobiphenyl, 97%
| 2436-96-6 |
|
Phosphoric acid-d3, 85 wt % solution in D2O, 99+ atom % D
| 14335-33-2 |
|
2-Amino-3-Hydroxypyridine, 98%
| 16867-03-1 |
|
1,2,3-Trichloropropane, 99+ %
| 96-18-4 |
|
2-(Ethylamino)-1,3,4-Thiadiazole
| 13275-68-8 |
|
Triethyl 2-phosphonopropionate, 98%
| 3699-66-9 |
|
1,2,3-Tribromo-5-Fluorobenzene, 99+%
| 3925-78-8 |
|
1-Methylimidazole, 99%
| 616-47-7 |
|
(r,r)-chiraphos, 97%
| 74839-84-2 |
|
1-Acetyl-1-cyclohexene, 97%
| 932-66-1 |
|
4-Nitroindole, 98%
| 4769-97-5 |
|
N,N-Dimethylacetamide Dimethyl Acetal, Tech., 85%
| 7732-18-5 |
|
Benzimidazole, 98%
| 51-17-2 |
|
DL-O-Methoxy-Alpha-Methylbenzyl Alcohol, 99%
| 13513-82-1 |
|
2,4-Dichloro-6-nitrophenol moist solid containing 20% water
| 609-89-2 |
|
3-Acetyl-n-tosylpyrrole, 99+%
| |
|
1-(Pyrrolidino)-1-cyclohexene, 97%
| 1125-99-1 |
|
4-Chlororesorcinol, 98%
| 95-88-5 |
|
P-(Methylthio)Benzyl Alcohol, 98%
| 3446-90-0 |
|
2-Hydroxy-gamma-butyrolactone, 99%
| 19444-84-9 |
|
Ethyl 4-Methoxycarbonylbenzoylacetate
| 79322-76-2 |
|
2,2,6-Trimethyl-4H-1,3-dioxin-4-one, 97% (GC)
| 67-64-1 |
|
L-(+)-Cysteine, 99+% (TLC)
| 52-90-4 |
|
2-Methoxy-1,3-Dioxolane, 99%
| 19693-75-5 |
|
Z-Alpha,Beta-Dinitrostilbene 99.5+%
| 1796-05-0 |
|
N-Acetylglycine, 99%
| 543-24-8 |
|
p-Toluenesulfonic acid sodium salt, 99% (titr.)
| 657-84-1 |
|
Acridine orange, 80% (uv-vis)
| 65-61-2 |
|
2,2-Dichlorooctadecanal, 90%
| 119450-47-4 |
|
p-Acetophenetidide, 97%
| 62-44-2 |
|
Rhodium on carbon (5% rh)
| |
|
1,2,4-Benzenetriamine Dihydrochloride (Pract), 99% (titr.)
| 615-47-4 |
|
Ammonium hexafluoroniobate(v), 99.99%
| 12062-13-4 |
|
Nylon 6/6
| 32131-17-2 |
|
Aluminum fluoride monohydrate, 99.999%,
| 7784-18-1 |
|
2,4-Dinitrotoluene, 95%, remainder 2,6-dinitrotoluene
| 121-14-2 |
|
|