**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 13462-92-5 |Aluminum fluoride monohydrate | 99.999 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Ingestion of large amounts of fluoride may cause salivation, nausea,
vomiting, abdominal pain, fever, labored breathing. Exposure to
fluoride compounds can result in systemic toxic effects on the heart,
liver, and kidneys. It may also deplete calcium levels in the body
leading to hypocalcemia and death. Aluminum may be readily absorbed
from the gastrointestinal tract. The oral human LDLo for the fluoride
ion (CAS= 16984-48-8) is 50 mg/kg. Acute fluoride intoxication
produces nausea, vomiting, abdominal pain, diarrhea and tetany,
often resulting in death from cardiovascular collapse.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride
poisoning (fluorosis) characterized by weight loss, weakness,
anemia, brittle bones, and stiff joints. Chronic exposure to
fluoride compounds may cause systemic toxicity. Overexposure to
fluoride dust over prolonged periods can result in fluoride
deposition in bones and cartilage as evidenced by X-ray changes
(fluorosis) which may be accompanied by stiffness of joints. (Alcoa)
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Substance
is nonflammable.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Use with adequate ventilation.
Avoid breathing dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 7784-18-1:
United Kingdom, WEL - TWA: (listed as aluminum, soluble salts): 2
mg/m3 TWA
United Kingdom, WEL - STEL: (listed as aluminum, soluble salts):
mg/m3 STEL
United States OSHA: 2.5 mg/m3 TWA (as F) (listed under
Fluorides).2.5 mg/m3 TWA (as F) (listed under Fluorides).
Belgium - TWA: (listed as aluminum, soluble salts): 2 mg/m3 VLE (
Al)
France - VME: (listed as fluorides): 2.5 mg/m3 VME (as F)
Germany: (listed as fluorides): 2.5 mg/m3 VME (as F)
Malaysia: (listed as fluorides): 2.5 mg/m3 TWA (as F)
Netherlands: (listed as fluorides): 3.5 mg/m3 STEL (as F)
Netherlands: (listed as aluminum, soluble compounds): 2 mg/m3 MAC
Russia: 2.5 mg/m3 TWA
Russia: 0.5 mg/m3 STEL
Spain: (listed as aluminum, soluble salts): 2 mg/m3 VLA-ED (as Al
CAS# 13462-92-5:
United Kingdom, WEL - TWA: (listed as fluorides, inorganic): 2.5
mg/m3 TWA (as F)
United Kingdom, WEL - STEL: (listed as fluorides, inorganic): 6.2
mg/m3 STEL (as F)
United States OSHA: 2.5 mg/m3 TWA (as F) (listed under
Fluorides).2.5 mg/m3 TWA (as F) (listed under Fluorides).
Belgium - TWA: (listed as fluorides, inorganic): 2.5 mg/m3 VLE (a
France - VME: (listed as fluorides): 2.5 mg/m3 VME (as F)
Germany: (listed as fluorides): 2.5 mg/m3 VME (as F)
Malaysia: (listed as fluorides): 2.5 mg/m3 TWA (as F)
Netherlands: (listed as fluorides): 3.5 mg/m3 STEL (as F)
Netherlands: (listed as aluminum, soluble compounds): 2 mg/m3 MAC
Spain: (listed as fluorides, inorganic): 2.5 mg/m3 VLA-ED (except
uranium hexafluoride, as F)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 1260 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 1260C(sublimes)
Solubility in water: 0.559 g/100 ml @25C
Specific Gravity/Density: 2.17
Molecular Formula: AlF3.H2O
Molecular Weight: 101.99
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. If temperature of use for aluminum fluoride
exceeds the sublimation temperature (1260C), hydrogen fluoride gas
may be generated. In the presence of water vapor and temperature in
excess of 300C, HF gas may be generated.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
No significant incompatibilities identified with common materials and
contaminants..
Hazardous Decomposition Products:
Hydrogen fluoride gas, aluminum oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7784-18-1: BD0725000
CAS# 13462-92-5 unlisted.
LD50/LC50:
CAS# 7784-18-1: Draize test, rabbit, eye: 500 mg/24H Mild; Oral,
mouse: LD50 = 103 mg/kg; Oral, rat: LD50 = 1800 mg/kg.
CAS# 13462-92-5.
Carcinogenicity:
Aluminum fluoride -
Not listed by ACGIH, IARC, or NTP.
Aluminum fluoride monohydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 7784-18-1: No information available.
CAS# 13462-92-5: No information available.
Canada
CAS# 7784-18-1 is listed on Canada's DSL List.
CAS# 7784-18-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 13462-92-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7784-18-1 is listed on the TSCA inventory.
CAS# 13462-92-5 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #6 Date: 12/03/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tetrahydropyran-2-Methanol, 98%
| 100-72-1 |
|
Molecular sieves, 4a, 8 to 12 mesh
| 70955-01-0 |
|
1-Chloro-4-nitrobenzene, 99%
| 100-00-5 |
|
L-Strychnine, 98%
| 57-24-9 |
|
2-Nitrophenylacetic acid, 99%
| 3740-52-1 |
|
3-Chlorothiophene-2-carboxylic acid, 99+%
| 59337-89-2 |
|
4-Biphenylacetic acid, 98%
| 5728-52-9 |
|
N,N-Diethylnipecotamide, Tech.
| 3367-95-1 |
|
2-Hydroxy-5-methylbenzophenone
| 1470-57-1 |
|
2-Chloro-4-nitrobenzoic acid, 98%
| 99-60-5 |
|
3-(3-(Trifluoromethyl)Phenoxy)Benzaldehyde 97%
| 78725-46-9 |
|
Ethylenediaminetetraacetic acid, tetrasodium salt, hydrate , 99%
| 64-02-8 |
|
3,4-Dinitrobenzoic acid, 99%
| 528-45-0 |
|
Methyltrichlorosilane, 98%
| 75-79-6 |
|
2,2'-Dinitrobiphenyl, 97%
| 2436-96-6 |
|
Phosphoric acid-d3, 85 wt % solution in D2O, 99+ atom % D
| 14335-33-2 |
|
2-Amino-3-Hydroxypyridine, 98%
| 16867-03-1 |
|
1,2,3-Trichloropropane, 99+ %
| 96-18-4 |
|
2-(Ethylamino)-1,3,4-Thiadiazole
| 13275-68-8 |
|
Triethyl 2-phosphonopropionate, 98%
| 3699-66-9 |
|
1,2,3-Tribromo-5-Fluorobenzene, 99+%
| 3925-78-8 |
|
1-Methylimidazole, 99%
| 616-47-7 |
|
(r,r)-chiraphos, 97%
| 74839-84-2 |
|
1-Acetyl-1-cyclohexene, 97%
| 932-66-1 |
|
4-Nitroindole, 98%
| 4769-97-5 |
|
N,N-Dimethylacetamide Dimethyl Acetal, Tech., 85%
| 7732-18-5 |
|
Benzimidazole, 98%
| 51-17-2 |
|
DL-O-Methoxy-Alpha-Methylbenzyl Alcohol, 99%
| 13513-82-1 |
|
2,4-Dichloro-6-nitrophenol moist solid containing 20% water
| 609-89-2 |
|
3-Acetyl-n-tosylpyrrole, 99+%
| |
|
1-(Pyrrolidino)-1-cyclohexene, 97%
| 1125-99-1 |
|
4-Chlororesorcinol, 98%
| 95-88-5 |
|
P-(Methylthio)Benzyl Alcohol, 98%
| 3446-90-0 |
|
2-Hydroxy-gamma-butyrolactone, 99%
| 19444-84-9 |
|
Ethyl 4-Methoxycarbonylbenzoylacetate
| 79322-76-2 |
|
2,2,6-Trimethyl-4H-1,3-dioxin-4-one, 97% (GC)
| 67-64-1 |
|
L-(+)-Cysteine, 99+% (TLC)
| 52-90-4 |
|
2-Methoxy-1,3-Dioxolane, 99%
| 19693-75-5 |
|
Z-Alpha,Beta-Dinitrostilbene 99.5+%
| 1796-05-0 |
|
N-Acetylglycine, 99%
| 543-24-8 |
|
p-Toluenesulfonic acid sodium salt, 99% (titr.)
| 657-84-1 |
|
Acridine orange, 80% (uv-vis)
| 65-61-2 |
|
2,2-Dichlorooctadecanal, 90%
| 119450-47-4 |
|
p-Acetophenetidide, 97%
| 62-44-2 |
|
Rhodium on carbon (5% rh)
| |
|
1,2,4-Benzenetriamine Dihydrochloride (Pract), 99% (titr.)
| 615-47-4 |
|
Ammonium hexafluoroniobate(v), 99.99%
| 12062-13-4 |
|
Nylon 6/6
| 32131-17-2 |
|
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| 7784-18-1 |
|
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| 121-14-2 |
|
|