**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 115-19-5 |2-Methyl-3-Butyn-2-Ol | 98 | 204-070-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Vapors may cause dizziness
or suffocation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire. Use water spray to keep
fire-exposed containers cool. Containers may explode in the heat of
a fire. Flammable liquid and vapor. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. Vapors may form an explosive mixture with air.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. In case of fire, use water, dry chemical,
chemical foam, or alcohol-resistant foam. Use water spray to cool
fire-exposed containers. Water may be ineffective. Use agent most
appropriate to extinguish fire. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep away from heat,
sparks and flame. Avoid ingestion and inhalation. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 115-19-5:
Germany: 0.9 ppm TWA; 3 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to pale straw colored
Odor: None reported.
pH: Not available.
Vapor Pressure: 14 mbar @ 20 C
Viscosity: 3.8 cP 20.00 deg C
Boiling Point: 104 deg C @ 760.00mmHg
Freezing/Melting Point: 2.6 deg C
Autoignition Temperature: Not available.
Flash Point: 25 deg C ( 77.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density: .8680g/cm3
Molecular Formula: C5H8O
Molecular Weight: 84.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 115-19-5: ES0810000
LD50/LC50:
CAS# 115-19-5: Inhalation, mouse: LC50 = 2 gm/m3; Inhalation, mouse:
LC50 = 2000 mg/m3; Oral, mouse: LD50 = 500 mg/kg; Oral, mouse: LD50 =
500 mg/kg; Oral, rat: LD50 = 1950 mg/kg.
Carcinogenicity:
2-Methyl-3-Butyn-2-Ol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: LC50= 3290 mg 1-1
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALCOHOLS, N.O.S.*
Hazard Class: 3
UN Number: 1987
Packing Group: III
IMO
Shipping Name: ALCOHOLS, N.O.S.
Hazard Class: 3.3
UN Number: 1987
Packing Group: III
RID/ADR
Shipping Name: ALCOHOLS, FLAMMABLE, N.O.S.
Hazard Class: 3
UN Number: 1987
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 115-19-5: 1
Canada
CAS# 115-19-5 is listed on Canada's DSL List.
CAS# 115-19-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 115-19-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/04/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Niobocene dichloride
| 12793-14-5 |
|
4,4-Diethoxy-2-butyn-1-al, 97+% (GC)
| 74149-25-0 |
|
Beta-(1,4)-2-Amino-2-Deoxy-D-Glucose
| 9012-76-4 |
|
9,10-Anthracenedicarbonitrile, 99% (UV-Vis)
| 1217-45-4 |
|
alpha-Hydroxyacetophenone, 97%
| 582-24-1 |
|
Cyclopentyl chloride, 99+%
| 930-28-9 |
|
5'-O-Dimethoxytrityl-N-Benzoyl-Desoxycyti-Dine
| 67219-55-0 |
|
4,4,4-Trifluoro-1-phenyl-1,3-butanedione
| 326-06-7 |
|
6-Ethyl-O-Toluidine, 98+%
| 24549-06-2 |
|
2-Phenylindolizine, 99+%
| 25379-20-8 |
|
2-Methyl-3-Buten-2-Ol, 97%
| 115-18-4 |
|
1,3,5-Triacetylbenzene, 98%
| 779-90-8 |
|
Propylamine Hydrochloride, 99+%
| 556-53-6 |
|
3,5-Dinitrosalicylic Acid, 98%
| 609-99-4 |
|
2-Methyl-3-Butyn-2-Ol, 98%
| 115-19-5 |
|
Coumarin 307, laser grade, 98% (uv-vis)
| 55804-70-1 |
|
Calcium Fluoride, 99.99%
| 7789-75-5 |
|
1,3-Dichloro-2-propanol, 99%
| 96-23-1 |
|
1,2:3,5-Di-O-Isopropylidene-Alpha-D-Xylofuranose, 98%
| 20881-04-3 |
|
3,5-Dimethoxybenzoyl chloride, ca. 92%, balance is corresponding acid
| 17213-57-9 |
|
(-)-alpha-Pinene, 98%
| 7785-26-4 |
|
2-Methyl-3-pentanol, 99+%
| 565-62-8 |
|
Mem Chloride, 94-98%(GC)
| 3970-21-6 |
|
Ethyl Crotonate, 96%
| 623-70-1 |
|
2,4-Dinitrophenol, moistened with up to 35% water
| 51-28-5 |
|
2-(Phenylthio)Ethanol, 99%
| 699-12-7 |
|
1-Anthraquinonesulfonic Acid Sodium Salt (Pract), Containing up to
| 128-56-3 |
|
4-(4-Biphenylyl)-2-Methylthiazole, 97%
| 24864-19-5 |
|
4,4'-Dithiodipyridine, 98%
| 2645-22-9 |
|
1-Pentanethiol, 98%
| 110-66-7 |
|
3-Methylsulphonylbenzoic Acid, 95+%
| 5345-27-7 |
|
Hexyl sodium sulfate, pract., 98%
| 2207-98-9 |
|
3-Benzyloxybenzaldehyde,98%
| 1700-37-4 |
|
(s)-3-Butene-1,2-diol, 99% (gc)
| 62214-39-5 |
|
N,N-Dibenzylhydroxylamine, 98%
| 621-07-8 |
|
5-Iodosalicylic acid, 97%
| 119-30-2 |
|
1-Adamantyl methyl ketone, 99%
| 1660-04-4 |
|
6-Bromo-2-Naphthol, 97%
| 15231-91-1 |
|
Furoin, 98%
| 552-86-3 |
|
Iminostilbene, 97%
| 256-96-2 |
|
(+/-)-Citronellic Acid
| 502-47-6 |
|
1-Ethylpyridinium Bromide, 98%
| 1906-79-2 |
|
5-Norbornene-2-carbonitrile, 98% mixture of endo and exo
| 95-11-4 |
|
Isosorbide-5-Mononitrate, CHR
| 16051-77-7 |
|
2,2,4,5,5-Pentamethyl-3-Imidazoline-3-Oxide-1-Oxyl, Free Radical
| 18796-04-8 |
|
Undecylenic aldehyde, 97%
| 112-45-8 |
|
Lumazine, 98%
| 487-21-8 |
|
3-Fluorobenzoic Acid, 99%
| 455-38-9 |
|
2-(Bromomethyl)-Naphthalene, 96%
| 939-26-4 |
|
2,4-Dihydroxy-5,6-Dimethylpyrimidine 97%
| 26305-13-5 |
|
|