**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 96-23-1 |1,3-Dichloro-2-propanol | 99 | 202-491-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 21 25 45
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin. Toxic if swallowed. May cause cancer.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes mild skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. May cause narcotic effects in
high concentration.
Chronic:
Animal studies indicate that the product may affect the liver and
kidneys.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Combustible liquid and vapor. Vapors are heavier
than air and may travel to a source of ignition and flash back.
Vapors can spread along the ground and collect in low or confined
areas.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide or alcohol type foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion
and inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Keep away from heat and flame.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 96-23-1:
Russia: 5 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: Ethereal odor
pH: Not available.
Vapor Pressure: 0.75 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 172-176 deg C @ 760 mm Hg
Freezing/Melting Point: -4 deg C
Autoignition Temperature: Not available.
Flash Point: 85 deg C ( 185.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.3510g/cm3
Molecular Formula: C3H6Cl2O
Molecular Weight: 128.99
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Unstable.
Conditions to Avoid:
Ignition sources.
Incompatibilities with Other Materials:
Strong acids, acid anhydrides, acid chlorides, strong oxidizing
agents, strong reducing agents.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 96-23-1: UB1400000
LD50/LC50:
CAS# 96-23-1: Oral, mouse: LD50 = 25 mg/kg; Oral, mouse: LD50 = 93
mg/kg; Oral, rat: LD50 = 81 mg/kg; Oral, rat: LD50 = 81 mg/kg; Skin,
rabbit: LD50 = 800 uL/kg; Skin, rabbit: LD50 = 590 mg/kg.
Carcinogenicity:
1,3-Dichloro-2-propanol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 1,3-DICHLOROPROPANOL-2
Hazard Class: 6.1
UN Number: 2750
Packing Group: II
IMO
Shipping Name: 1,3-DICHLOROPROPANOL-2
Hazard Class: 6.1
UN Number: 2750
Packing Group: II
RID/ADR
Shipping Name: 1,3-DICHLOROPROPANOL-2
Hazard Class: 6.1
UN Number: 2750
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 21 Harmful in contact with skin.
R 25 Toxic if swallowed.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 96-23-1: 2
Canada
CAS# 96-23-1 is listed on Canada's DSL List.
CAS# 96-23-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 96-23-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/23/1998 Revision #3 Date: 9/07/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Niobocene dichloride
| 12793-14-5 |
|
4,4-Diethoxy-2-butyn-1-al, 97+% (GC)
| 74149-25-0 |
|
Beta-(1,4)-2-Amino-2-Deoxy-D-Glucose
| 9012-76-4 |
|
9,10-Anthracenedicarbonitrile, 99% (UV-Vis)
| 1217-45-4 |
|
alpha-Hydroxyacetophenone, 97%
| 582-24-1 |
|
Cyclopentyl chloride, 99+%
| 930-28-9 |
|
5'-O-Dimethoxytrityl-N-Benzoyl-Desoxycyti-Dine
| 67219-55-0 |
|
4,4,4-Trifluoro-1-phenyl-1,3-butanedione
| 326-06-7 |
|
6-Ethyl-O-Toluidine, 98+%
| 24549-06-2 |
|
2-Phenylindolizine, 99+%
| 25379-20-8 |
|
2-Methyl-3-Buten-2-Ol, 97%
| 115-18-4 |
|
1,3,5-Triacetylbenzene, 98%
| 779-90-8 |
|
Propylamine Hydrochloride, 99+%
| 556-53-6 |
|
3,5-Dinitrosalicylic Acid, 98%
| 609-99-4 |
|
2-Methyl-3-Butyn-2-Ol, 98%
| 115-19-5 |
|
Coumarin 307, laser grade, 98% (uv-vis)
| 55804-70-1 |
|
Calcium Fluoride, 99.99%
| 7789-75-5 |
|
1,3-Dichloro-2-propanol, 99%
| 96-23-1 |
|
1,2:3,5-Di-O-Isopropylidene-Alpha-D-Xylofuranose, 98%
| 20881-04-3 |
|
3,5-Dimethoxybenzoyl chloride, ca. 92%, balance is corresponding acid
| 17213-57-9 |
|
(-)-alpha-Pinene, 98%
| 7785-26-4 |
|
2-Methyl-3-pentanol, 99+%
| 565-62-8 |
|
Mem Chloride, 94-98%(GC)
| 3970-21-6 |
|
Ethyl Crotonate, 96%
| 623-70-1 |
|
2,4-Dinitrophenol, moistened with up to 35% water
| 51-28-5 |
|
2-(Phenylthio)Ethanol, 99%
| 699-12-7 |
|
1-Anthraquinonesulfonic Acid Sodium Salt (Pract), Containing up to
| 128-56-3 |
|
4-(4-Biphenylyl)-2-Methylthiazole, 97%
| 24864-19-5 |
|
4,4'-Dithiodipyridine, 98%
| 2645-22-9 |
|
1-Pentanethiol, 98%
| 110-66-7 |
|
3-Methylsulphonylbenzoic Acid, 95+%
| 5345-27-7 |
|
Hexyl sodium sulfate, pract., 98%
| 2207-98-9 |
|
3-Benzyloxybenzaldehyde,98%
| 1700-37-4 |
|
(s)-3-Butene-1,2-diol, 99% (gc)
| 62214-39-5 |
|
N,N-Dibenzylhydroxylamine, 98%
| 621-07-8 |
|
5-Iodosalicylic acid, 97%
| 119-30-2 |
|
1-Adamantyl methyl ketone, 99%
| 1660-04-4 |
|
6-Bromo-2-Naphthol, 97%
| 15231-91-1 |
|
Furoin, 98%
| 552-86-3 |
|
Iminostilbene, 97%
| 256-96-2 |
|
(+/-)-Citronellic Acid
| 502-47-6 |
|
1-Ethylpyridinium Bromide, 98%
| 1906-79-2 |
|
5-Norbornene-2-carbonitrile, 98% mixture of endo and exo
| 95-11-4 |
|
Isosorbide-5-Mononitrate, CHR
| 16051-77-7 |
|
2,2,4,5,5-Pentamethyl-3-Imidazoline-3-Oxide-1-Oxyl, Free Radical
| 18796-04-8 |
|
Undecylenic aldehyde, 97%
| 112-45-8 |
|
Lumazine, 98%
| 487-21-8 |
|
3-Fluorobenzoic Acid, 99%
| 455-38-9 |
|
2-(Bromomethyl)-Naphthalene, 96%
| 939-26-4 |
|
2,4-Dihydroxy-5,6-Dimethylpyrimidine 97%
| 26305-13-5 |
|
|