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MSDS 
:
 Bromophenol Blue (0.1% in Water)
CAS 
:
 115-39-9
SYNONYMS 
:
 Tetrabromophenoltetrabromosulfonenephthalein; BPB
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 115-39-9 |Bromphenol Blue | 0.1 | 204-086-2 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Not available.

Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Low hazard for usual industrial handling.
Inhalation:
May cause respiratory tract irritation. Low hazard for usual
industrial handling.
Chronic:
Allergic reactions have occured with similar compounds.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Wash clothing before reuse. Flush skin with plenty
of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode in
the heat of a fire.
Extinguishing Media:
Use alcohol foam, carbon dioxide, or water spray when fighting fires
involving this material. Cool containers with flooding quantities of
water until well after fire is out.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Provide
ventilation.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Keep container
tightly closed.
Storage:
Store in a cool, dry place. Keep containers tightly closed.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 115-39-9:

CAS# 7732-18-5:


Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid
Color: blue-black
Odor: Odorless.
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: 279 deg C
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C19H10Br4O5S
Molecular Weight: 669.96

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong acids, strong
bases.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 115-39-9: SJ7453000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Bromphenol Blue -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 115-39-9: No information available.
CAS# 7732-18-5: No information available.
Canada
CAS# 115-39-9 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 115-39-9 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 115-39-9 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

Text for R-phrases from Section 2
MSDS Creation Date: 5/11/1998 Revision #2 Date: 3/18/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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ALL MSDS PAGES IN THIS GROUP
NAMECAS
Bromophenol Blue (0.1% in Water) 115-39-9
Diethylene glycol dibutyl ether, 99+% 112-73-2
Bromophenol Blue, Water Soluble Indicator 62625-28-9
Bromocresol green, indicator 76-60-8
Cresyl Violet Acetate, High Purity Biological Stain 10510-54-0
Congo Red, Indicator Grade 573-58-0
Congo Red (Cert) 573-58-0
2,6-Dichloroindophenol Sodium Salt Hydrate P.A. 620-45-1
Eosin Y High Purity Biological Stain 17372-87-1
Eosin Y (cert) 17372-87-1
Giemsa Stain, High Purity Biological Stain 51811-82-6
Hematoxylin (Cert), 90% (UV-Vis) 517-28-2
Indigo carmine, high purity biological stain 860-22-0
Methyl red, sodium salt, indicator 845-10-3
Methyl Orange, Indicator 547-58-0
Methyl Orange (Cert) 547-58-0
Methyl Orange, Reagent ACS 547-58-0
Neutral red, high purity biological stain 553-24-2
Orange G, High Purity Biological Stain 1936-15-8
Orcein, natural 1400-62-0
Basic Fuchsin, high purity biological stain 569-61-9
Pararosaniline Chloride (0.2% in .1M Hydrochloric Acid) 569-61-9
1,10-Phenanthroline monohydrate, 99+% 66-71-7
m-Toluic acid, 99% 99-04-7
Phenol Red, Water Soluble, Indicator 34487-61-1
Phloxine b, high purity biological stain 18472-87-2
Safranine O, high purity biological stain, 95% 477-73-6
Sudan iii, high purity biological stain 98% (tlc) 85-86-9
Sudan IV, High Purity Biological Stain 85-83-6
Sudan Black B, High Purity Biological Stain 4197-25-5
Palmitoyl chloride,tech. 92%(gc) 112-67-4
Pyronin Y, High Purity Biological Stain 92-32-0
Nitro Blue Tetrazolium Chloride Mono- Hydrate 298-83-9
Oil Red O, biological stain 1320-06-5
Dithioerythritol, 99+% 6892-68-8
MES hydrate 0-00-1
2,2-Bis(Hydroxymethyl)-2,2',2"- Nitrilotriethanol, 98% 6976-37-0
ACES, 99% 7365-82-4
Benzamidine hydrochloride hydrate, 98% 1670-14-0
Dimethyl 1,4-Cyclohexanedicarboxylate, 99%, Mixture of Cis and Trans 94-60-0
Iodoacetic acid 64-69-7
Calcium Pantothenate, 97.5% 137-08-6
1-BROMOPYRENE 1714-29-0
Yttrium(iii)-oxide, 99.999% 1314-36-9
2-Hydroxy-p-naphthoquinone 83-72-7
Crocein Orange G 1934-20-9
5-Nitroindazole, 98% (titr.) 5401-94-5
4-Chloro-1-Naphthol, 99% 604-44-4
Dextran (High Fraction), average m.w. 250000 9004-54-0
2,2-Dimethyl-1,3-propanediol, 97% 126-30-7

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