**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 5144-89-8 |1,10-Phenanthroline monohydrate | > 99 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T N
Risk Phrases: 25 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed. Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
The toxicological properties of this material have not been fully
investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. The anhydrous form of this substance is
harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. May be harmful if
inhaled.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 66-71-7:
CAS# 5144-89-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: off-white
Odor: weak odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: > 98 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: C12H8N2.H2O
Molecular Weight: 198.23
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 66-71-7: SF8300000
CAS# 5144-89-8: SF8437000
LD50/LC50:
Not available.
Not available.
Oral LD50 (rat) = 132 mg/kg for the anhydrous material.
Carcinogenicity:
1,10-phenanthroline, anhydrous -
Not listed by ACGIH, IARC, or NTP.
1,10-Phenanthroline monohydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 25 Toxic if swallowed.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 66-71-7: 2
CAS# 5144-89-8: No information available.
Canada
CAS# 66-71-7 is listed on Canada's DSL List.
CAS# 66-71-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 5144-89-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 66-71-7 is listed on the TSCA inventory.
CAS# 5144-89-8 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 8/14/1998 Revision #7 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Bromophenol Blue (0.1% in Water)
| 115-39-9 |
|
Diethylene glycol dibutyl ether, 99+%
| 112-73-2 |
|
Bromophenol Blue, Water Soluble Indicator
| 62625-28-9 |
|
Bromocresol green, indicator
| 76-60-8 |
|
Cresyl Violet Acetate, High Purity Biological Stain
| 10510-54-0 |
|
Congo Red, Indicator Grade
| 573-58-0 |
|
Congo Red (Cert)
| 573-58-0 |
|
2,6-Dichloroindophenol Sodium Salt Hydrate P.A.
| 620-45-1 |
|
Eosin Y High Purity Biological Stain
| 17372-87-1 |
|
Eosin Y (cert)
| 17372-87-1 |
|
Giemsa Stain, High Purity Biological Stain
| 51811-82-6 |
|
Hematoxylin (Cert), 90% (UV-Vis)
| 517-28-2 |
|
Indigo carmine, high purity biological stain
| 860-22-0 |
|
Methyl red, sodium salt, indicator
| 845-10-3 |
|
Methyl Orange, Indicator
| 547-58-0 |
|
Methyl Orange (Cert)
| 547-58-0 |
|
Methyl Orange, Reagent ACS
| 547-58-0 |
|
Neutral red, high purity biological stain
| 553-24-2 |
|
Orange G, High Purity Biological Stain
| 1936-15-8 |
|
Orcein, natural
| 1400-62-0 |
|
Basic Fuchsin, high purity biological stain
| 569-61-9 |
|
Pararosaniline Chloride (0.2% in .1M Hydrochloric Acid)
| 569-61-9 |
|
1,10-Phenanthroline monohydrate, 99+%
| 66-71-7 |
|
m-Toluic acid, 99%
| 99-04-7 |
|
Phenol Red, Water Soluble, Indicator
| 34487-61-1 |
|
Phloxine b, high purity biological stain
| 18472-87-2 |
|
Safranine O, high purity biological stain, 95%
| 477-73-6 |
|
Sudan iii, high purity biological stain 98% (tlc)
| 85-86-9 |
|
Sudan IV, High Purity Biological Stain
| 85-83-6 |
|
Sudan Black B, High Purity Biological Stain
| 4197-25-5 |
|
Palmitoyl chloride,tech. 92%(gc)
| 112-67-4 |
|
Pyronin Y, High Purity Biological Stain
| 92-32-0 |
|
Nitro Blue Tetrazolium Chloride Mono- Hydrate
| 298-83-9 |
|
Oil Red O, biological stain
| 1320-06-5 |
|
Dithioerythritol, 99+%
| 6892-68-8 |
|
MES hydrate
| 0-00-1 |
|
2,2-Bis(Hydroxymethyl)-2,2',2"- Nitrilotriethanol, 98%
| 6976-37-0 |
|
ACES, 99%
| 7365-82-4 |
|
Benzamidine hydrochloride hydrate, 98%
| 1670-14-0 |
|
Dimethyl 1,4-Cyclohexanedicarboxylate, 99%, Mixture of Cis and Trans
| 94-60-0 |
|
Iodoacetic acid
| 64-69-7 |
|
Calcium Pantothenate, 97.5%
| 137-08-6 |
|
1-BROMOPYRENE
| 1714-29-0 |
|
Yttrium(iii)-oxide, 99.999%
| 1314-36-9 |
|
2-Hydroxy-p-naphthoquinone
| 83-72-7 |
|
Crocein Orange G
| 1934-20-9 |
|
5-Nitroindazole, 98% (titr.)
| 5401-94-5 |
|
4-Chloro-1-Naphthol, 99%
| 604-44-4 |
|
Dextran (High Fraction), average m.w. 250000
| 9004-54-0 |
|
2,2-Dimethyl-1,3-propanediol, 97%
| 126-30-7 |
|
|