**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1188-14-3 |Triethylgermanium hydride | 98% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation, in contact with skin and if
swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire. Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Isolate area and deny entry.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with skin and eyes. Handle
under an inert atmosphere.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1188-14-3:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 121 - 122 deg C @ 20 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 8 deg C ( 46.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 0.994
Molecular Formula: C6H16Ge
Molecular Weight: 160.78
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, oxides of germanium.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1188-14-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Triethylgermanium hydride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Flammable liquid, n.o.s.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: Flammable liquid, n.o.s.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 1188-14-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1188-14-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1188-14-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/16/2002 Revision #1 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Chlorophenethylacohol, 98%
| 5182-44-5 |
|
4-Chlorophenethylalcohol, 99%
| 1875-88-3 |
|
2,4-Dichlorophenethylalcohol
| 81156-68-5 |
|
3,5-Dimethyl-4-Hydroxybenzonitrile
| 4198-90-7 |
|
1,2-Dinitrobenzene, 99%
| 528-29-0 |
|
2,6-Dimethylnaphthalene
| 581-42-0 |
|
Ethyl Phenyl Sulfone, 98%
| 599-70-2 |
|
Isobutyl Benzoate, 98%
| 120-50-3 |
|
Diethyl benzylmalonate, 97%
| 607-81-8 |
|
Pentaethylene glycol, 98%
| 4792-15-8 |
|
4',4"(5")-Di-tert. butyldicyclohexano-18-crown-6, mixture of isomers
| 28801-57-2 |
|
4-Bromo-2,6-dimethylaniline, 98%
| 24596-19-8 |
|
1,1,1-Trichloro-2-methyl-2-propanol hemihydrate, 98%
| 6001-64-5 |
|
L-Lysine
| 56-87-1 |
|
Grubb's catalyst, 97%
| 172222-30-9 |
|
4-Methoxybiphenyl, 98%
| 613-37-6 |
|
2-Naphthalenemethanol, 98%
| 1592-38-7 |
|
2-Amino-4,6-dimethylpyridine, 99%
| 5407-87-4 |
|
1-Naphthyl Propionate
| 3121-71-9 |
|
N,N'-Diacetylhydrazine, 98%
| 3148-73-0 |
|
2,4,6-Trimethylphenylacetic Acid
| 4408-60-0 |
|
2,4,6-Trimethylbenzylcyanide
| 34688-71-6 |
|
Triethylgermanium hydride, 98%
| 1188-14-3 |
|
Trimethylgermanium Bromide, 98%
| 1066-37-1 |
|
Triphenylgermanium Chloride
| 1626-24-0 |
|
Diphenylgermanium Dichloride, 95%
| 1613-66-7 |
|
Chlorotriethylgermane, 96%
| 994-28-5 |
|
Triphenylgermanium bromide, 95%
| 3005-32-1 |
|
Germanium(IV) methoxide, 97%
| 992-91-6 |
|
Trimethylgermanium iodide
| 1066-38-2 |
|
(2-Methoxyphenyl)acetonitrile, 98%
| 7035-03-2 |
|
Tris(cyclopentadienyl)praseodymium
| 11077-59-1 |
|
Trimethoxy(pentamethylcyclopentadienyl) titanium(IV)
| 123927-75-3 |
|
Diphenylzinc, 95%
| 1078-58-6 |
|
Trimethyl(pentafluorophenyl)silane, 98%
| 1206-46-8 |
|
Pentamethylcyclopentadienyl Hafnium Trichloride
| 75181-08-7 |
|
Tantalum(V) Butoxide
| 51094-78-1 |
|
Bis(pentamethylcylcopentadienyl)hafnium dichloride
| 85959-83-7 |
|
Benzyltrichlorosilane
| 770-10-5 |
|
Tetrakis(dimethylamino)titanium
| 3275-24-9 |
|
Bis(pentamethylcyclopentadienyl)manganese
| 67506-86-9 |
|
alpha-Methylferrocenemethanol, 97%
| 1277-49-2 |
|
Tris(pentafluorophenyl)borane, 95%
| 1109-15-5 |
|
3,5-Dimethylpiperidine, 96%
| 35794-11-7 |
|
Tin(II) acetate
| 638-39-1 |
|
Diphenyltin oxide, 97%
| 2273-51-0 |
|
Tricarbonyl(cycloheptatriene)molybdenum
| 12125-77-8 |
|
Tetraphenylantimony bromide
| 16894-69-2 |
|
4,4,6-Trimethyl-2-vinyl-1,3,2- dioxaborinane
| 4627-10-5 |
|
Hexylphosphonic Dichloride, 95%
| 928-64-3 |
|
|