**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 528-29-0 |1,2-Dinitrobenzene | 99 | 208-431-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+ N
Risk Phrases: 26/27/28 33 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed.
Danger of cumulative effects. Very toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be fatal if absorbed through the
skin.
Ingestion:
May be fatal if swallowed. May cause irritation of the digestive
tract. Methemoglobinemia is characterized by dizziness, drowsiness,
headache, shortness of breath, cyanosis (bluish discoloration of skin
due to deficient oxygenation of the blood), rapid heart rate and
chocolate-brown colored blood. Effects may be delayed. May form
methemoglobin which in sufficient concentration causes cyanosis
(bluish discoloration of skin due to deficient oxygenation of the
blood).
Inhalation:
May be fatal if inhaled. May cause respiratory tract irritation.
Chronic:
There is a danger of cumulative effects. May cause adverse
reproductive effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
POISON material. If swallowed, get medical aid immediately. Only
induce vomiting if directed to do so by medical personnel. Never give
anything by mouth to an unconscious person.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 528-29-0:
United States OSHA: 1 mg/m3 TWA
Japan: 0.15 ppm OEL; 1 mg/m3 OEL
Malaysia: 0.15 ppm TWA; 1.0 mg/m3 TWA
Spain: 0.15 ppm VLA-ED; 1 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: light yellow - brown
Odor: Not available.
pH: Not available.
Vapor Pressure: 1 hPa @100 deg C
Viscosity: Not available.
Boiling Point: 319 deg C @ 773 mm Hg
Freezing/Melting Point: 116 - 119 deg C
Autoignition Temperature: Not available.
Flash Point: 150 deg C ( 302.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 150 mg/l water (20C)
Specific Gravity/Density:
Molecular Formula: C6H4N2O4
Molecular Weight: 168.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, exposure
to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 528-29-0: CZ7450000
LD50/LC50:
Not available.
Carcinogenicity:
1,2-Dinitrobenzene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DINITROBENZENES, SOLID
Hazard Class: 6.1
UN Number: 1597
Packing Group: II
IMO
Shipping Name: DINITROBENZENES, SOLID
Hazard Class: 6.1
UN Number: 1597
Packing Group: II
RID/ADR
Shipping Name: DINITROBENZENES, SOLID
Hazard Class: 6.1
UN Number: 1597
Packing group: II
USA RQ: CAS# 528-29-0: 100 lb final RQ (Listed under Dinitrobenzene, mixed); 45.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ N
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 33 Danger of cumulative effects.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 528-29-0: 3
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 528-29-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 528-29-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/16/2002 Revision #1 Date: 10/08/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Chlorophenethylacohol, 98%
| 5182-44-5 |
|
4-Chlorophenethylalcohol, 99%
| 1875-88-3 |
|
2,4-Dichlorophenethylalcohol
| 81156-68-5 |
|
3,5-Dimethyl-4-Hydroxybenzonitrile
| 4198-90-7 |
|
1,2-Dinitrobenzene, 99%
| 528-29-0 |
|
2,6-Dimethylnaphthalene
| 581-42-0 |
|
Ethyl Phenyl Sulfone, 98%
| 599-70-2 |
|
Isobutyl Benzoate, 98%
| 120-50-3 |
|
Diethyl benzylmalonate, 97%
| 607-81-8 |
|
Pentaethylene glycol, 98%
| 4792-15-8 |
|
4',4"(5")-Di-tert. butyldicyclohexano-18-crown-6, mixture of isomers
| 28801-57-2 |
|
4-Bromo-2,6-dimethylaniline, 98%
| 24596-19-8 |
|
1,1,1-Trichloro-2-methyl-2-propanol hemihydrate, 98%
| 6001-64-5 |
|
L-Lysine
| 56-87-1 |
|
Grubb's catalyst, 97%
| 172222-30-9 |
|
4-Methoxybiphenyl, 98%
| 613-37-6 |
|
2-Naphthalenemethanol, 98%
| 1592-38-7 |
|
2-Amino-4,6-dimethylpyridine, 99%
| 5407-87-4 |
|
1-Naphthyl Propionate
| 3121-71-9 |
|
N,N'-Diacetylhydrazine, 98%
| 3148-73-0 |
|
2,4,6-Trimethylphenylacetic Acid
| 4408-60-0 |
|
2,4,6-Trimethylbenzylcyanide
| 34688-71-6 |
|
Triethylgermanium hydride, 98%
| 1188-14-3 |
|
Trimethylgermanium Bromide, 98%
| 1066-37-1 |
|
Triphenylgermanium Chloride
| 1626-24-0 |
|
Diphenylgermanium Dichloride, 95%
| 1613-66-7 |
|
Chlorotriethylgermane, 96%
| 994-28-5 |
|
Triphenylgermanium bromide, 95%
| 3005-32-1 |
|
Germanium(IV) methoxide, 97%
| 992-91-6 |
|
Trimethylgermanium iodide
| 1066-38-2 |
|
(2-Methoxyphenyl)acetonitrile, 98%
| 7035-03-2 |
|
Tris(cyclopentadienyl)praseodymium
| 11077-59-1 |
|
Trimethoxy(pentamethylcyclopentadienyl) titanium(IV)
| 123927-75-3 |
|
Diphenylzinc, 95%
| 1078-58-6 |
|
Trimethyl(pentafluorophenyl)silane, 98%
| 1206-46-8 |
|
Pentamethylcyclopentadienyl Hafnium Trichloride
| 75181-08-7 |
|
Tantalum(V) Butoxide
| 51094-78-1 |
|
Bis(pentamethylcylcopentadienyl)hafnium dichloride
| 85959-83-7 |
|
Benzyltrichlorosilane
| 770-10-5 |
|
Tetrakis(dimethylamino)titanium
| 3275-24-9 |
|
Bis(pentamethylcyclopentadienyl)manganese
| 67506-86-9 |
|
alpha-Methylferrocenemethanol, 97%
| 1277-49-2 |
|
Tris(pentafluorophenyl)borane, 95%
| 1109-15-5 |
|
3,5-Dimethylpiperidine, 96%
| 35794-11-7 |
|
Tin(II) acetate
| 638-39-1 |
|
Diphenyltin oxide, 97%
| 2273-51-0 |
|
Tricarbonyl(cycloheptatriene)molybdenum
| 12125-77-8 |
|
Tetraphenylantimony bromide
| 16894-69-2 |
|
4,4,6-Trimethyl-2-vinyl-1,3,2- dioxaborinane
| 4627-10-5 |
|
Hexylphosphonic Dichloride, 95%
| 928-64-3 |
|
|