**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1192-30-9 |Tetrahydrofurfuryl Bromide, Tech | 90% | 214-750-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Aspiration may lead
to pulmonary edema. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use agent most
appropriate to extinguish fire. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from sources of ignition. Keep container closed when not
in use. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1192-30-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 168 - 170 deg C @ 744.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 63 deg C ( 145.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.4520g/cm3
Molecular Formula: C5H9BrO
Molecular Weight: 165.03
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1192-30-9: LU6000000
LD50/LC50:
Not available.
Carcinogenicity:
Tetrahydrofurfuryl Bromide, Tech -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1192-30-9: No information available.
Canada
CAS# 1192-30-9 is listed on Canada's NDSL List.
CAS# 1192-30-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1192-30-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Fluorobenzene, 99%
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2-Mercaptopyridine, 99%
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DL-4-Hydroxy-3-Methoxyphenylglycol Piperazine Salt, 99%
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4'-Aminopropiophenone, 99% (Titr.)
| 70-69-9 |
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2-Nitro-5-Thiocyanatobenzoic Acid, 98% (Titr.)
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1-Eicosanol, 98%
| 629-96-9 |
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Lithium bis(trimethylsilyl)amide, 1.3M solution in THF
| 109-99-9 |
|
Methyl 4,4-Dimethyl-3-Oxovalerate, 98% (GC)
| 55107-14-7 |
|
Ruthenocene
| 1287-13-4 |
|
2,4-Dinitrobenzaldehyde, 97%
| 528-75-6 |
|
4-Nonylphenol, 99% (GC), Mixture of Isomers
| 104-40-5 |
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Cis-1,2-Dihydro-3-Methylcatechol, 20w/v % Soln. in Ethyl Acetate,
| 141-78-6 |
|
4-Hydroxy-3-Methoxybenzoic Acid, 98.5+% (HPLC)
| 121-34-6 |
|
4-Methyl-2,3,5,6-tetrafluorothiophenol 98+% (GC)
| 13634-89-4 |
|
gamma-Cyclodextrin hydrate, 99% (hplc)
| 17465-86-0 |
|
Ammonium hexachloroplatinate(IV), 99.999%
| 16919-58-7 |
|
20-(Hydroxymethyl)pregna-1,4-dien-3-one, 95%
| 35525-27-0 |
|
N,N-Dimethylguanidine sulfate
| 598-65-2 |
|
(Bromomethyl)cyclopropane, 90%
| 7051-34-5 |
|
2-Acetyl-3-methylpyrazine, 98+%
| 23787-80-6 |
|
2-Chloro-5-Nitrobenzaldehyde, 99+% (GC)
| 6361-21-3 |
|
O-Cresolphthalein, Indicator Grade, 98% (UV)
| 596-27-0 |
|
3-Nitrophenylacetic acid, 99%
| 1877-73-2 |
|
Diaza-18-Crown-6, 98%
| 23978-55-4 |
|
5-(2-Bromophenyl)-1h-tetrazole
| 73096-42-1 |
|
4-Chlorophenyl 2,3-Epoxypropyl Ether, 99%
| 2212-05-7 |
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Benzoyloxyethylchloromethylether, Tech. 85%, Balance mainly
| 0-00-1 |
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Cholesteryl Oleate, 99+% (TLC)
| 303-43-5 |
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Leuco Crystal Violet, 99%
| 603-48-5 |
|
bis(Acetato-o)(3-methoxyphenyl)iodine
| 69180-50-3 |
|
2,6-Dichloro-3-Nitropyridine, Tech., 90%
| 16013-85-7 |
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Trimethylsilyl Bromoacetate, 98%
| 18291-80-0 |
|
3-Aminocrotononitrile, 96-99%(Titr.)
| 1118-61-2 |
|
Magnesium atomic absorption standard solution, 1 mg/ml mg in 0.5n
| |
|
3-Aminoquinoline, 99+% (Titr.)
| 580-17-6 |
|
1,3-bis-(dimethylamino)-2-propanol, 95%
| 5966-51-8 |
|
(S)-(+)-Citramalic Acid, 98+%
| 6236-09-5 |
|
3-Methoxycatechol, 99%
| 934-00-9 |
|
Cyclobutanemethanol, 99%
| 4415-82-1 |
|
Tetraethylammonium Perchlorate, 98% (Titr., Dry Sub.), Conts.up to
| 2567-83-1 |
|
Poly-m-phenoxylene
| 25190-64-1 |
|
Hexachloroethane, 99%
| 67-72-1 |
|
6-Nitroindazole, 98%
| 7597-18-4 |
|
Butyl Isothiocyanate
| 592-82-5 |
|
2-Cyclopentene-1-acetic acid, 98%
| 13668-61-6 |
|
2-Methyl-2-hexanol, 97%
| 625-23-0 |
|
Tetrahydrofurfuryl Bromide, Tech, 90%
| 1192-30-9 |
|
Sulfoacetic Acid Monohydrate (Pract), 93% (Titr.)
| 6155-83-5 |
|
Dihydroxytartaric Acid, Disodium Salt Dihydrate, 98%
| 866-17-1 |
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1-(p-Tolyl)-1-cyclopentanecarboxylic acid, 98%
| 80789-75-9 |
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|