**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 462-06-6 |Fluorobenzene | 99 | 207-321-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may
cause defatting of the skin and dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation. Vapors may cause dizziness
or suffocation.
Chronic:
Chronic exposure may cause lung damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Immediately
flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before reuse.
Remove contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water
spray to keep fire-exposed containers cool. Extremely flammable
liquid and vapor. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Will be easily ignited by heat, sparks or flame.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Use agent most appropriate to
extinguish fire. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 462-06-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: benzene-like
pH: Not available.
Vapor Pressure: 400 mbar @ 50 C
Viscosity: Not available.
Boiling Point: 85 deg C @ 760.00mmHg
Freezing/Melting Point: -40 deg C
Autoignition Temperature: Not available.
Flash Point: -15 deg C ( 5.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 1.0240g/cm3
Molecular Formula: C6H5F
Molecular Weight: 96.10
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, electrical sparks, exposure to flame.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 462-06-6: DA0800000
LD50/LC50:
CAS# 462-06-6: Inhalation, mouse: LC50 = 45 gm/m3/2H; Inhalation,
mouse: LC50 = 45000 mg/m3/2H; Inhalation, rat: LC50 = 26908 mg/m3;
Oral, rat: LD50 = 4399 mg/kg.
Carcinogenicity:
Fluorobenzene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLUOROBENZENE
Hazard Class: 3
UN Number: 2387
Packing Group: II
IMO
Shipping Name: FLUOROBENZENE
Hazard Class: 3.2
UN Number: 2387
Packing Group: II
RID/ADR
Shipping Name: FLUOROBENZENE
Hazard Class: 3
UN Number: 2387
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 7 Keep container tightly closed.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 462-06-6: 2
Canada
CAS# 462-06-6 is listed on Canada's DSL List.
CAS# 462-06-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 462-06-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/12/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Fluorobenzene, 99%
| 462-06-6 |
|
2-Mercaptopyridine, 99%
| 2637-34-5 |
|
DL-4-Hydroxy-3-Methoxyphenylglycol Piperazine Salt, 99%
| 67423-45-4 |
|
4'-Aminopropiophenone, 99% (Titr.)
| 70-69-9 |
|
2-Nitro-5-Thiocyanatobenzoic Acid, 98% (Titr.)
| 30211-77-9 |
|
1-Eicosanol, 98%
| 629-96-9 |
|
Lithium bis(trimethylsilyl)amide, 1.3M solution in THF
| 109-99-9 |
|
Methyl 4,4-Dimethyl-3-Oxovalerate, 98% (GC)
| 55107-14-7 |
|
Ruthenocene
| 1287-13-4 |
|
2,4-Dinitrobenzaldehyde, 97%
| 528-75-6 |
|
4-Nonylphenol, 99% (GC), Mixture of Isomers
| 104-40-5 |
|
Cis-1,2-Dihydro-3-Methylcatechol, 20w/v % Soln. in Ethyl Acetate,
| 141-78-6 |
|
4-Hydroxy-3-Methoxybenzoic Acid, 98.5+% (HPLC)
| 121-34-6 |
|
4-Methyl-2,3,5,6-tetrafluorothiophenol 98+% (GC)
| 13634-89-4 |
|
gamma-Cyclodextrin hydrate, 99% (hplc)
| 17465-86-0 |
|
Ammonium hexachloroplatinate(IV), 99.999%
| 16919-58-7 |
|
20-(Hydroxymethyl)pregna-1,4-dien-3-one, 95%
| 35525-27-0 |
|
N,N-Dimethylguanidine sulfate
| 598-65-2 |
|
(Bromomethyl)cyclopropane, 90%
| 7051-34-5 |
|
2-Acetyl-3-methylpyrazine, 98+%
| 23787-80-6 |
|
2-Chloro-5-Nitrobenzaldehyde, 99+% (GC)
| 6361-21-3 |
|
O-Cresolphthalein, Indicator Grade, 98% (UV)
| 596-27-0 |
|
3-Nitrophenylacetic acid, 99%
| 1877-73-2 |
|
Diaza-18-Crown-6, 98%
| 23978-55-4 |
|
5-(2-Bromophenyl)-1h-tetrazole
| 73096-42-1 |
|
4-Chlorophenyl 2,3-Epoxypropyl Ether, 99%
| 2212-05-7 |
|
Benzoyloxyethylchloromethylether, Tech. 85%, Balance mainly
| 0-00-1 |
|
Cholesteryl Oleate, 99+% (TLC)
| 303-43-5 |
|
Leuco Crystal Violet, 99%
| 603-48-5 |
|
bis(Acetato-o)(3-methoxyphenyl)iodine
| 69180-50-3 |
|
2,6-Dichloro-3-Nitropyridine, Tech., 90%
| 16013-85-7 |
|
Trimethylsilyl Bromoacetate, 98%
| 18291-80-0 |
|
3-Aminocrotononitrile, 96-99%(Titr.)
| 1118-61-2 |
|
Magnesium atomic absorption standard solution, 1 mg/ml mg in 0.5n
| |
|
3-Aminoquinoline, 99+% (Titr.)
| 580-17-6 |
|
1,3-bis-(dimethylamino)-2-propanol, 95%
| 5966-51-8 |
|
(S)-(+)-Citramalic Acid, 98+%
| 6236-09-5 |
|
3-Methoxycatechol, 99%
| 934-00-9 |
|
Cyclobutanemethanol, 99%
| 4415-82-1 |
|
Tetraethylammonium Perchlorate, 98% (Titr., Dry Sub.), Conts.up to
| 2567-83-1 |
|
Poly-m-phenoxylene
| 25190-64-1 |
|
Hexachloroethane, 99%
| 67-72-1 |
|
6-Nitroindazole, 98%
| 7597-18-4 |
|
Butyl Isothiocyanate
| 592-82-5 |
|
2-Cyclopentene-1-acetic acid, 98%
| 13668-61-6 |
|
2-Methyl-2-hexanol, 97%
| 625-23-0 |
|
Tetrahydrofurfuryl Bromide, Tech, 90%
| 1192-30-9 |
|
Sulfoacetic Acid Monohydrate (Pract), 93% (Titr.)
| 6155-83-5 |
|
Dihydroxytartaric Acid, Disodium Salt Dihydrate, 98%
| 866-17-1 |
|
1-(p-Tolyl)-1-cyclopentanecarboxylic acid, 98%
| 80789-75-9 |
|
|