**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1199-95-7 |Trimethyl(phenylethynyl)tin | 97 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+ N
Risk Phrases: 26/27/28 36/37/38 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin. Very toxic to
aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Toxic in contact with skin.
Ingestion:
May cause irritation of the digestive tract. Poison by ingestion.
Inhalation:
Causes respiratory tract irritation. Toxic if inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1199-95-7:
United Kingdom, WEL - TWA: (listed as tin organic compounds): 0.1
mg/m3 TWA (except cyhexatin, as Sn)
United Kingdom, WEL - STEL: (listed as tin organic compounds): 0.
mg/m3 STEL (except cyhexatin, as Sn)
United States OSHA: 0.1 mg/m3 TWA (as Sn) (listed under Tin orga
compounds).
Belgium - TWA: (listed as tin organic compounds): 0.1 mg/m3 VLE (
Sn)
Belgium - STEL: (listed as tin organic compounds): 0.2 mg/m3 VLE
Sn)
France - VME: (listed as tin organic compounds): 0.1 mg/m3 VME (a
Sn)
France - VLE: (listed as tin organic compounds): 0.2 mg/m3 VLE (a
Sn)
Germany: (listed as tin organic compounds): 0.1 mg/m3 VME (as Sn)
Germany: (listed as tin organic compounds): Skin absorber
Malaysia: (listed as tin organic compounds): 0.1 mg/m3 TWA (as Sn
Netherlands: (listed as tin organic compounds): 0.2 mg/m3 STEL (a
Sn)
Netherlands: (listed as tin organic compounds): 0.1 mg/m3 MAC (as
Spain: (listed as tin organic compounds): 0.1 mg/m3 VLA-ED (as Sn
Spain: (listed as tin organic compounds): 0.2 mg/m3 VLA-EC (as Sn
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white to light beige
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C11H14Sn
Molecular Weight: 264.92
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, tin/tin oxides.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1199-95-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Trimethyl(phenylethynyl)tin -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Organotin compound, solid, n.o.s.*
Hazard Class: 6.1
UN Number: 3146
Packing Group: II
IMO
Shipping Name: Organotin compound, solid, n.o.s.
Hazard Class: 6.1
UN Number: 3146
Packing Group: II
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ N
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 1199-95-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1199-95-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1199-95-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/16/2002 Revision #1 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Neodymium(III) isopropoxide, 98%
| 19236-15-8 |
|
Samarium(III) isopropoxide in ampoules
| 3504-40-3 |
|
Chlorodicyclohexylphosphine
| 16523-54-9 |
|
Lithium pentamethylcyclopentadienide
| 51905-34-1 |
|
Bis(cyclopentadienyl)magnesium, sublimed, 97%
| 1284-72-6 |
|
d-(-)Prolinol
| 68832-13-3 |
|
Butyltriphenyl Phosphonium Chloride, 98%
| 13371-17-0 |
|
(2,4-Dichlorobenzyl)triphenylphosphonium chloride hydrate
| 0-01-1 |
|
(2-Chlorobenzyl)triphenylphosphonium chloride hydrate, 98%
| 18583-55-6 |
|
(1-Naphthylmethyl)Triphenylphosphonium Chloride
| 23277-00-1 |
|
N-Benzyl-N-Methylethanolamine, 99%(GC)
| 101-98-4 |
|
5-Bromo-2-Chlorotoluene, 98%
| 54932-72-8 |
|
2,4,6,8-Tetramethylcyclotetrasiloxane, mixture of isomers, 95%
| 2370-88-9 |
|
Octanesulfonyl Chloride, 96%
| 7795-95-1 |
|
Ethyl 3-oxo-4-(triphenylphosphoranylidene)butyrate, 97%
| 13148-05-5 |
|
Cyanogen bromide 3M solution in dichloromethane
| 75-09-2 |
|
3,4-Dihydroxybenzophenone, 98%
| 10425-11-3 |
|
3-Methylamino-1,2-Propanediol, 98%
| 40137-22-2 |
|
Meso-2,3-Dmercaptosuccinic acid, 98%
| 304-55-2 |
|
Mono-Methyl Terephthalate, 97%
| 1679-64-7 |
|
2,5-Dimethylresorcinol, 99%
| 488-87-9 |
|
4,5-Dimethylresorcinol
| 527-55-9 |
|
2,6-Dihydroxy-4-Methylbenzoic Acid
| 480-67-1 |
|
Trimethyl(phenylethynyl)tin, 97%
| 1199-95-7 |
|
2,6-Bis(bromomethyl)pyridine
| 7703-74-4 |
|
L-(+)-2-Amino-6-(O,O'-diethylphosphono)hexanoic acid, 98%
| 184095-99-6 |
|
(R)-(-)-Tetrahydrofurfurylamine
| 7202-43-9 |
|
Phenanthridine, 98%
| 229-87-8 |
|
2,4,6-Trichlorobenzoic Acid, 97%
| 50-43-1 |
|
Methyl 2-Chlorophenylacetate, 98%
| 57486-68-7 |
|
5-Nitro-1,10-phenanthroline, 98%
| 4199-88-6 |
|
Methyl 4- Chlorophenylacetate, 99%
| 52449-43-1 |
|
Methyl 3-fluorophenylacetate, 98%
| 64123-77-9 |
|
Methyl 2 ,4-Dichlorophenylacetate, 99%
| 55954-23-9 |
|
Methyl 2,6-Dichlorophenylacetate, 99%
| 54551-83-6 |
|
Methyl 3,4-Dichlorophenylacetate, 99%
| 6725-44-6 |
|
Trans-2-Hydroxy-1-Cyclohexanecarboxamide, 99%
| 24947-95-3 |
|
2,6-Dichlorophenethylalcohol, 96%
| 30595-79-0 |
|
3,4-Dichlorophenethylalcohol, 97%
| 35364-79-5 |
|
2,4,6-Trimethylphenethylalcohol, 99%
| 6950-92-1 |
|
2,5-Dimethylphenethylalcohol, 99%
| 6972-51-6 |
|
2-Chloro-6-Fluorobenzylamine
| 15205-15-9 |
|
2-Chloro-6-Fluorophenethylamine, 99%
| 149488-93-7 |
|
Coumarin 30, Laser Grade
| 41044-12-6 |
|
3-Bromobenzyl Chloride, 98%
| 932-77-4 |
|
4,5-Dinitro-1,2-phenylenediamine
| 32690-28-1 |
|
4-Chloro-5-Nitrophenylenediamine
| 67073-39-6 |
|
Harmalol Hydrochloride Hydrate, 98%
| 6028-00-8 |
|
Bis(indenyl)dimethylzirconium
| 49596-04-5 |
|
Tris(tetramethylcyclopentdienyl)cerium, packaged in ampules on 1 gm.
| 251984-08-4 |
|
|