**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 68832-13-3 |(R)-(-)-2-(Hydroxymethyl)pyrrolidine | | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Air sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause dermatitis. May cause cyanosis of
the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with sand, dry lime or soda ash and place in
a closed container for disposal. Provide ventilation. Place under an
inert atmosphere.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Use with
adequate ventilation. Handle under an inert atmosphere. Store
protected from air.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.) Do not expose to air. Store
under an inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 68832-13-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear colorless
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: viscous
Boiling Point: 75 deg C @ 2.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water:
Specific Gravity/Density: 1.0250g/cm3
Molecular Formula: C5H11NO
Molecular Weight: 101.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. May discolor on exposure to air.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to air, excess
heat, strong oxidants.
Incompatibilities with Other Materials:
Air, acid anhydrides, acid chlorides, strong acids, strong oxidizing
agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 68832-13-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(R)-(-)-2-(Hydroxymethyl)pyrrolidine -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 68832-13-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 68832-13-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 68832-13-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Neodymium(III) isopropoxide, 98%
| 19236-15-8 |
|
Samarium(III) isopropoxide in ampoules
| 3504-40-3 |
|
Chlorodicyclohexylphosphine
| 16523-54-9 |
|
Lithium pentamethylcyclopentadienide
| 51905-34-1 |
|
Bis(cyclopentadienyl)magnesium, sublimed, 97%
| 1284-72-6 |
|
d-(-)Prolinol
| 68832-13-3 |
|
Butyltriphenyl Phosphonium Chloride, 98%
| 13371-17-0 |
|
(2,4-Dichlorobenzyl)triphenylphosphonium chloride hydrate
| 0-01-1 |
|
(2-Chlorobenzyl)triphenylphosphonium chloride hydrate, 98%
| 18583-55-6 |
|
(1-Naphthylmethyl)Triphenylphosphonium Chloride
| 23277-00-1 |
|
N-Benzyl-N-Methylethanolamine, 99%(GC)
| 101-98-4 |
|
5-Bromo-2-Chlorotoluene, 98%
| 54932-72-8 |
|
2,4,6,8-Tetramethylcyclotetrasiloxane, mixture of isomers, 95%
| 2370-88-9 |
|
Octanesulfonyl Chloride, 96%
| 7795-95-1 |
|
Ethyl 3-oxo-4-(triphenylphosphoranylidene)butyrate, 97%
| 13148-05-5 |
|
Cyanogen bromide 3M solution in dichloromethane
| 75-09-2 |
|
3,4-Dihydroxybenzophenone, 98%
| 10425-11-3 |
|
3-Methylamino-1,2-Propanediol, 98%
| 40137-22-2 |
|
Meso-2,3-Dmercaptosuccinic acid, 98%
| 304-55-2 |
|
Mono-Methyl Terephthalate, 97%
| 1679-64-7 |
|
2,5-Dimethylresorcinol, 99%
| 488-87-9 |
|
4,5-Dimethylresorcinol
| 527-55-9 |
|
2,6-Dihydroxy-4-Methylbenzoic Acid
| 480-67-1 |
|
Trimethyl(phenylethynyl)tin, 97%
| 1199-95-7 |
|
2,6-Bis(bromomethyl)pyridine
| 7703-74-4 |
|
L-(+)-2-Amino-6-(O,O'-diethylphosphono)hexanoic acid, 98%
| 184095-99-6 |
|
(R)-(-)-Tetrahydrofurfurylamine
| 7202-43-9 |
|
Phenanthridine, 98%
| 229-87-8 |
|
2,4,6-Trichlorobenzoic Acid, 97%
| 50-43-1 |
|
Methyl 2-Chlorophenylacetate, 98%
| 57486-68-7 |
|
5-Nitro-1,10-phenanthroline, 98%
| 4199-88-6 |
|
Methyl 4- Chlorophenylacetate, 99%
| 52449-43-1 |
|
Methyl 3-fluorophenylacetate, 98%
| 64123-77-9 |
|
Methyl 2 ,4-Dichlorophenylacetate, 99%
| 55954-23-9 |
|
Methyl 2,6-Dichlorophenylacetate, 99%
| 54551-83-6 |
|
Methyl 3,4-Dichlorophenylacetate, 99%
| 6725-44-6 |
|
Trans-2-Hydroxy-1-Cyclohexanecarboxamide, 99%
| 24947-95-3 |
|
2,6-Dichlorophenethylalcohol, 96%
| 30595-79-0 |
|
3,4-Dichlorophenethylalcohol, 97%
| 35364-79-5 |
|
2,4,6-Trimethylphenethylalcohol, 99%
| 6950-92-1 |
|
2,5-Dimethylphenethylalcohol, 99%
| 6972-51-6 |
|
2-Chloro-6-Fluorobenzylamine
| 15205-15-9 |
|
2-Chloro-6-Fluorophenethylamine, 99%
| 149488-93-7 |
|
Coumarin 30, Laser Grade
| 41044-12-6 |
|
3-Bromobenzyl Chloride, 98%
| 932-77-4 |
|
4,5-Dinitro-1,2-phenylenediamine
| 32690-28-1 |
|
4-Chloro-5-Nitrophenylenediamine
| 67073-39-6 |
|
Harmalol Hydrochloride Hydrate, 98%
| 6028-00-8 |
|
Bis(indenyl)dimethylzirconium
| 49596-04-5 |
|
Tris(tetramethylcyclopentdienyl)cerium, packaged in ampules on 1 gm.
| 251984-08-4 |
|
|