**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 16523-54-9 |Chlorodicyclohexylphosphine | | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 14 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water. Causes burns.Moisture sensitive.Air
sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema. May
cause burning sensation, coughing, wheezing, laryngitis, shortness of
breath, headache, nausea, and vomiting.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water Reactive. Material will react with water and
may release a flammable and/or toxic gas.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood. Handle under
argon.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Store under argon.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 16523-54-9:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 165 deg C @ 12 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 109 deg C (> 228.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: 1.054
Molecular Formula: C12H22ClP
Molecular Weight: 232.74
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to air, exposure to moist air or
water.
Incompatibilities with Other Materials:
Water, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of phosphorus, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 16523-54-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Chlorodicyclohexylphosphine -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Corrosive liquid, acidic, organic, n.o.s.*
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: Corrosive liquid, acidic, organic, n.o.s.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 8 Keep container dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 16523-54-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 16523-54-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16523-54-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/16/2002 Revision #1 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Neodymium(III) isopropoxide, 98%
| 19236-15-8 |
|
Samarium(III) isopropoxide in ampoules
| 3504-40-3 |
|
Chlorodicyclohexylphosphine
| 16523-54-9 |
|
Lithium pentamethylcyclopentadienide
| 51905-34-1 |
|
Bis(cyclopentadienyl)magnesium, sublimed, 97%
| 1284-72-6 |
|
d-(-)Prolinol
| 68832-13-3 |
|
Butyltriphenyl Phosphonium Chloride, 98%
| 13371-17-0 |
|
(2,4-Dichlorobenzyl)triphenylphosphonium chloride hydrate
| 0-01-1 |
|
(2-Chlorobenzyl)triphenylphosphonium chloride hydrate, 98%
| 18583-55-6 |
|
(1-Naphthylmethyl)Triphenylphosphonium Chloride
| 23277-00-1 |
|
N-Benzyl-N-Methylethanolamine, 99%(GC)
| 101-98-4 |
|
5-Bromo-2-Chlorotoluene, 98%
| 54932-72-8 |
|
2,4,6,8-Tetramethylcyclotetrasiloxane, mixture of isomers, 95%
| 2370-88-9 |
|
Octanesulfonyl Chloride, 96%
| 7795-95-1 |
|
Ethyl 3-oxo-4-(triphenylphosphoranylidene)butyrate, 97%
| 13148-05-5 |
|
Cyanogen bromide 3M solution in dichloromethane
| 75-09-2 |
|
3,4-Dihydroxybenzophenone, 98%
| 10425-11-3 |
|
3-Methylamino-1,2-Propanediol, 98%
| 40137-22-2 |
|
Meso-2,3-Dmercaptosuccinic acid, 98%
| 304-55-2 |
|
Mono-Methyl Terephthalate, 97%
| 1679-64-7 |
|
2,5-Dimethylresorcinol, 99%
| 488-87-9 |
|
4,5-Dimethylresorcinol
| 527-55-9 |
|
2,6-Dihydroxy-4-Methylbenzoic Acid
| 480-67-1 |
|
Trimethyl(phenylethynyl)tin, 97%
| 1199-95-7 |
|
2,6-Bis(bromomethyl)pyridine
| 7703-74-4 |
|
L-(+)-2-Amino-6-(O,O'-diethylphosphono)hexanoic acid, 98%
| 184095-99-6 |
|
(R)-(-)-Tetrahydrofurfurylamine
| 7202-43-9 |
|
Phenanthridine, 98%
| 229-87-8 |
|
2,4,6-Trichlorobenzoic Acid, 97%
| 50-43-1 |
|
Methyl 2-Chlorophenylacetate, 98%
| 57486-68-7 |
|
5-Nitro-1,10-phenanthroline, 98%
| 4199-88-6 |
|
Methyl 4- Chlorophenylacetate, 99%
| 52449-43-1 |
|
Methyl 3-fluorophenylacetate, 98%
| 64123-77-9 |
|
Methyl 2 ,4-Dichlorophenylacetate, 99%
| 55954-23-9 |
|
Methyl 2,6-Dichlorophenylacetate, 99%
| 54551-83-6 |
|
Methyl 3,4-Dichlorophenylacetate, 99%
| 6725-44-6 |
|
Trans-2-Hydroxy-1-Cyclohexanecarboxamide, 99%
| 24947-95-3 |
|
2,6-Dichlorophenethylalcohol, 96%
| 30595-79-0 |
|
3,4-Dichlorophenethylalcohol, 97%
| 35364-79-5 |
|
2,4,6-Trimethylphenethylalcohol, 99%
| 6950-92-1 |
|
2,5-Dimethylphenethylalcohol, 99%
| 6972-51-6 |
|
2-Chloro-6-Fluorobenzylamine
| 15205-15-9 |
|
2-Chloro-6-Fluorophenethylamine, 99%
| 149488-93-7 |
|
Coumarin 30, Laser Grade
| 41044-12-6 |
|
3-Bromobenzyl Chloride, 98%
| 932-77-4 |
|
4,5-Dinitro-1,2-phenylenediamine
| 32690-28-1 |
|
4-Chloro-5-Nitrophenylenediamine
| 67073-39-6 |
|
Harmalol Hydrochloride Hydrate, 98%
| 6028-00-8 |
|
Bis(indenyl)dimethylzirconium
| 49596-04-5 |
|
Tris(tetramethylcyclopentdienyl)cerium, packaged in ampules on 1 gm.
| 251984-08-4 |
|
|