**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 12030-88-5 |Potassium Superoxide, Catalyzed Granul| ca. 100 | 234-746-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: O C
Risk Phrases: 14 35 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water. Causes severe burns. Contact with
combustible material may cause fire.Corrosive.Water-reactive.
Potential Health Effects
Eye:
Causes severe eye burns. When substance becomes wet or comes in
contact with moisture of the mucous membranes, it will cause
irritation. May cause permanent corneal opacification. May cause
chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. The toxicological properties of this substance have not been
fully investigated. May cause systemic effects. May cause nausea,
vomiting, and diarrhea, possibly with blood.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated.
Aspiration may lead to pulmonary edema. May cause systemic effects.
May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and
upper airway obstruction caused by edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
If water-reactive products are embedded in the skin, no water should
be applied. The embedded products should be covered with a light
oil.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Water
Reactive. Material will react with water and may release a flammable
and/or toxic gas. Oxidizer. Greatly increases the burning rate of
combustible materials. May ignite or explode on contact with steam
or moist air. Some oxidizers may react explosively with
hydrocarbons(fuel). May accelerate burning if involved in a fire.
Containers may explode when heated. May re-ignite after fire is
extinguished.
Extinguishing Media:
Use dry sand or earth to smother fire. DO NOT USE WATER! Do NOT get
water inside containers. Contact professional fire-fighters
immediately. Cool containers with flooding quantities of water until
well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Avoid generating dusty conditions. Remove all
sources of ignition. Provide ventilation. Do not expose spill to
water. Do not use combustible materials such as paper towels to clean
up spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not allow
water to get into the container because of violent reaction. Minimize
dust generation and accumulation. Do not breathe dust, vapor, mist,
or gas. Do not get in eyes, on skin, or on clothing. Keep container
tightly closed. Avoid contact with clothing and other combustible
materials. Do not ingest or inhale. Do not allow contact with water.
Discard contaminated shoes. Keep from contact with moist air and
steam.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a cool, dry place. Keep container
closed when not in use. Keep away from water. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use process enclosure, local exhaust
ventilation, or other engineering controls to control airborne
levels.
Exposure Limits
CAS# 12030-88-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Granules
Color: Yellow-green granules
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 400 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: KO2
Molecular Weight: 71.10
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Combines vigorously or explosively with water.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation,
combustible materials, reducing agents, exposure to moist air or
water.
Incompatibilities with Other Materials:
Reducing agents, water.
Hazardous Decomposition Products:
Oxides of potassium.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 12030-88-5: TT6053000
LD50/LC50:
Not available.
Carcinogenicity:
Potassium Superoxide, Catalyzed Granules, 3.5-5 mesh -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: POTASSIUM SUPEROXIDE
Hazard Class: 5.1
UN Number: 2466
Packing Group: I
IMO
Shipping Name: POTASSIUM SUPEROXIDE
Hazard Class: 5.1
UN Number: 2466
Packing Group: I
RID/ADR
Shipping Name: POTASSIUM SUPEROXIDE
Hazard Class: 5.1
UN Number: 2466
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C
Risk Phrases:
R 14 Reacts violently with water.
R 35 Causes severe burns.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 8 Keep container dry.
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 12030-88-5: No information available.
Canada
CAS# 12030-88-5 is listed on Canada's NDSL List.
CAS# 12030-88-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 12030-88-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/14/1998 Revision #5 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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(Methyl sulfoxide)-d6, packaged in 0.50 ml ampules, 99.9 atom % D
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Alpha, Alpha-Diphenyl-4-Piperidinomethanol 98+% (TLC)
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Acetic-D3 Acid-D, Packaged in 1ml Ampules, 99.5 Atom% D
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Acrylamide, 99+%, Electrophoresis Grade
| 79-06-1 |
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Acetonitrile-d3
| 75-05-8 |
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Trans-2-Pentenal, 97%
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|
Adipic acid, 99%
| 124-04-9 |
|
Dioctyl sulfosuccinate, sodium salt, 96%
| 577-11-7 |
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(R)-Glycidyl Butyrate, 92-94%(GC)
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Perfluoro(methylcyclohexane), 90%
| 355-02-2 |
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Rhodium(III) acetylacetonate
| 4447-60-3 |
|
2-Amino-5-Bromopyridine, 97%
| 1072-97-5 |
|
N-Benzyl-N-Methylethanolamine, 90%
| 101-98-4 |
|
1,8-Bis(Hydroxymethyl)Naphthalene, 99%
| 2026-08-6 |
|
Potassium Superoxide, Catalyzed Granules, 3.5-5 mesh
| 12030-88-5 |
|
Methylenecyclohexane, 98%
| 1192-37-6 |
|
3-Chloroanisole
| 2845-89-8 |
|
Urethane, 97%
| 51-79-6 |
|
Acetaldehyde, 99.5%
| 75-07-0 |
|
Tetramethylurea-D12, 99+ Atom % D
| 51219-89-7 |
|
Trans,Trans-2,4-Hexadien-1-ol, 99%
| 17102-64-6 |
|
4-Amino-3-Chlorobenzonitrile, 97%
| 21803-75-8 |
|
n-Methyloctylamine, 98%
| 2439-54-5 |
|
Diethyl 1,3-Acetonedicarboxylate, 95%
| 105-50-0 |
|
d-(-)-Tartaric acid(unnatural tartaric acid), 99%
| 147-71-7 |
|
2,7-Dimethylnaphthalene, 99%
| 582-16-1 |
|
Agar, Powder
| 9002-18-0 |
|
Methyl 4-Methoxycarbonylbenzoylacetate, 95%
| 0-01-1 |
|
Pent-4-enoic Anhydride
| 63521-92-6 |
|
Agarose, Pure Powder (MR = -0.13+/- 0.005)
| 9012-36-6 |
|
Methyl alcohol HPLC gradient grade
| 67-56-1 |
|
Albumin, egg (powder)
| 9006-59-1 |
|
Gibberellic Acid, 99% (Titr.)
| 77-06-5 |
|
1-Piperazinecarboxaldehyde, 98%
| 7755-92-2 |
|
Cerium(IV) sulfate, complex with sulfuric acid, Ce ca. 28%
| 17106-39-7 |
|
alpha-Chloralose, 97%
| 15879-93-3 |
|
2-Ketoglutaric acid, 98%
| 328-50-7 |
|
Ethyl 3,4-Dihydroxybenzoate, 97%
| 3943-89-3 |
|
alpha-Terpineol, mixture of isomers, 98%
| 98-55-5 |
|
Trimethylamine hydrochloride, 98%
| 593-81-7 |
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Aurintricarboxylic acid ammonium salt
| 569-58-4 |
|
2',6'-Dimethylacetanilide, 97%
| 2198-53-0 |
|
Aluminum ammonium sulfate dodecahydrate, reagent (crystals), 99%
| 7784-26-1 |
|
Propyl Benzoate, 99%
| 2315-68-6 |
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Aluminum chloride, anhydrous, powder, 98.5%
| 7446-70-0 |
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D-(-)Asparagine Monohydrate, 99%
| 2058-58-4 |
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7-Methyladenine, 98%
| 935-69-3 |
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