**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1576-87-0 |Trans-2-Pentenal | 97% | 216-414-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and
skin.Light sensitive.Highly flammable.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause cardiac disturbances. Ingestion of large amounts
may cause CNS depression.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to
pulmonary edema. Vapors may cause dizziness or suffocation. May
cause cardiac abnormalities. Inhalation at high concentrations may
cause CNS depression and asphixiation. May cause burning sensation in
the chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. Will be easily ignited by heat, sparks or
flame. Containers may explode if exposed to fire. Runoff from fire
control or dilution water may cause pollution.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Water may be ineffective. Water may spread
fire. If water is the only media available, use in flooding amounts.
For large fires, use water spray, fog or alcohol-resistant foam. Do
NOT use straight streams of water. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation.
Use with adequate ventilation. Wash clothing before reuse. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1576-87-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to slight yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 115 - 125 deg C @ 760mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 19 deg C ( 66.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: .8600g/cm3
Molecular Formula: CHOHC=CHC2H5
Molecular Weight: 84.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1576-87-0: SB1560000
LD50/LC50:
Not available.
Carcinogenicity:
Trans-2-Pentenal -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 1576-87-0: No information available.
Canada
CAS# 1576-87-0 is listed on Canada's DSL List.
CAS# 1576-87-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1576-87-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/21/1998 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
5-Amino-4-carbethoxy-1-phenylpyrazole, 98%
| 16078-71-0 |
|
1,1,2,2-Tetrabromoethane, 98%
| 79-27-6 |
|
(Methyl sulfoxide)-d6, packaged in 0.50 ml ampules, 99.9 atom % D
| 2206-27-1 |
|
Cyclohexane-D12, Packaged in 1ml Ampules, 99.5 Atom % D
| 1735-17-7 |
|
Alpha, Alpha-Diphenyl-4-Piperidinomethanol 98+% (TLC)
| 115-46-8 |
|
Acetic-D3 Acid-D, Packaged in 1ml Ampules, 99.5 Atom% D
| 1186-52-3 |
|
Acrylamide, 99+%, Electrophoresis Grade
| 79-06-1 |
|
Acetonitrile-d3
| 75-05-8 |
|
Trans-2-Pentenal, 97%
| 1576-87-0 |
|
Adipic acid, 99%
| 124-04-9 |
|
Dioctyl sulfosuccinate, sodium salt, 96%
| 577-11-7 |
|
(R)-Glycidyl Butyrate, 92-94%(GC)
| 60456-23-7 |
|
Perfluoro(methylcyclohexane), 90%
| 355-02-2 |
|
Rhodium(III) acetylacetonate
| 4447-60-3 |
|
2-Amino-5-Bromopyridine, 97%
| 1072-97-5 |
|
N-Benzyl-N-Methylethanolamine, 90%
| 101-98-4 |
|
1,8-Bis(Hydroxymethyl)Naphthalene, 99%
| 2026-08-6 |
|
Potassium Superoxide, Catalyzed Granules, 3.5-5 mesh
| 12030-88-5 |
|
Methylenecyclohexane, 98%
| 1192-37-6 |
|
3-Chloroanisole
| 2845-89-8 |
|
Urethane, 97%
| 51-79-6 |
|
Acetaldehyde, 99.5%
| 75-07-0 |
|
Tetramethylurea-D12, 99+ Atom % D
| 51219-89-7 |
|
Trans,Trans-2,4-Hexadien-1-ol, 99%
| 17102-64-6 |
|
4-Amino-3-Chlorobenzonitrile, 97%
| 21803-75-8 |
|
n-Methyloctylamine, 98%
| 2439-54-5 |
|
Diethyl 1,3-Acetonedicarboxylate, 95%
| 105-50-0 |
|
d-(-)-Tartaric acid(unnatural tartaric acid), 99%
| 147-71-7 |
|
2,7-Dimethylnaphthalene, 99%
| 582-16-1 |
|
Agar, Powder
| 9002-18-0 |
|
Methyl 4-Methoxycarbonylbenzoylacetate, 95%
| 0-01-1 |
|
Pent-4-enoic Anhydride
| 63521-92-6 |
|
Agarose, Pure Powder (MR = -0.13+/- 0.005)
| 9012-36-6 |
|
Methyl alcohol HPLC gradient grade
| 67-56-1 |
|
Albumin, egg (powder)
| 9006-59-1 |
|
Gibberellic Acid, 99% (Titr.)
| 77-06-5 |
|
1-Piperazinecarboxaldehyde, 98%
| 7755-92-2 |
|
Cerium(IV) sulfate, complex with sulfuric acid, Ce ca. 28%
| 17106-39-7 |
|
alpha-Chloralose, 97%
| 15879-93-3 |
|
2-Ketoglutaric acid, 98%
| 328-50-7 |
|
Ethyl 3,4-Dihydroxybenzoate, 97%
| 3943-89-3 |
|
alpha-Terpineol, mixture of isomers, 98%
| 98-55-5 |
|
Trimethylamine hydrochloride, 98%
| 593-81-7 |
|
Aurintricarboxylic acid ammonium salt
| 569-58-4 |
|
2',6'-Dimethylacetanilide, 97%
| 2198-53-0 |
|
Aluminum ammonium sulfate dodecahydrate, reagent (crystals), 99%
| 7784-26-1 |
|
Propyl Benzoate, 99%
| 2315-68-6 |
|
Aluminum chloride, anhydrous, powder, 98.5%
| 7446-70-0 |
|
D-(-)Asparagine Monohydrate, 99%
| 2058-58-4 |
|
7-Methyladenine, 98%
| 935-69-3 |
|
|