**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 121-50-6 |3-Amino-4-chlorobenzotrifluoride | 97% | 204-475-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 20/21/22 36/37/38 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin. Toxic to aquatic
organisms, may cause long-term adverse effects in the aquatic
environment.Dangerous for the environment.Combustible liquid.Light
sensitive.Air sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be absorbed through the skin in harmful
amounts.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood). Causes respiratory tract irritation.
Chronic:
Prolonged exposure may produce a narcotic effect. Prolonged or
repeated exposure may cause nausea, dizziness, and headache.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use with adequate
ventilation. Do not get in eyes, on skin, or on clothing. Do not
ingest or inhale.
Storage:
Keep away from sources of ignition. Store in a cool, dry place. Do
not store in direct sunlight. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Exposure Limits
CAS# 121-50-6:
United States OSHA: 2.5 mg/m3 TWA (as F) (listed under Fluorides
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear faint yellow to yellow
Odor: Penetrating odor.
pH: Not available.
Vapor Pressure: 0.15 mbar
Viscosity: Not available.
Boiling Point: 82 - 83 deg C @ 9.00mm Hg
Freezing/Melting Point: 10 deg C
Autoignition Temperature: > 560 deg C (> 1,040.00 deg F)
Flash Point: 75 deg C ( 167.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 11G/L (60C)
Specific Gravity/Density: 1.4280g/cm3
Molecular Formula: H2NC6H3(Cl)CF3
Molecular Weight: 195.57
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, ignition sources, exposure to air,
temperatures above 75C (167F).
Incompatibilities with Other Materials:
Acids and oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 121-50-6: XU5775000
LD50/LC50:
Not available.
Carcinogenicity:
3-Amino-4-chlorobenzotrifluoride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
log Pow: 3.19 Fish toxicity: Zebrafish LC50:7.1 mg/l/48h Zebrafish
LC50:7.1 mg/l/96h Bacteria EC50:62 mg/l/3h - Methode OESO 209
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S
.*
Hazard Class: 9
UN Number: 3082
Packing Group: III
IMO
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S
.
Hazard Class: 9
UN Number: 3082
Packing Group: III
RID/ADR
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S
.
Hazard Class: 9
UN Number: 3082
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 57 Use appropriate containment to avoid
environmental contamination.
S 60 This material and its container must be
disposed of as hazardous waste.
WGK (Water Danger/Protection)
CAS# 121-50-6: No information available.
Canada
CAS# 121-50-6 is listed on Canada's NDSL List.
CAS# 121-50-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 121-50-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3,5-Difluorobenzaldehyde, 98+% (GC)
| 32085-88-4 |
|
l-Menthone, 85%
| 14073-97-3 |
|
N-Benzoyl-L-Alanine Methyl Ester, 99+%
| 7244-67-9 |
|
5-Chloro-2-nitro-benzoylchloride
| 41994-44-9 |
|
1,1-Cyclobutanedicarboxylic Acid, 99%
| 5445-51-2 |
|
cis-4-Methylcyclohexanol, 98%
| 7731-28-4 |
|
Dibenzylideneacetone, 96% (GC)
| 35225-79-7 |
|
2,6-Dichloroquinone-4-Chloroimide, 98%
| 101-38-2 |
|
Heptamethyleneimine, 98%
| 1121-92-2 |
|
1-Methyl-6,7-Diethoxy-3,4-Dihydroisoquinoline, 99+%
| 99155-80-3 |
|
Azoene Fast Red PDC Salt, 98% (UV-Vis)
| 62778-15-8 |
|
Citrinin
| 518-75-2 |
|
Ethyl oxanilate, 98%
| 1457-85-8 |
|
2-Aminobenzyl alcohol, 98%
| 5344-90-1 |
|
P-tert.-butyl-tetramercaptocalix(4)arene
| |
|
4-Chloro-3-nitrobenzoylchloride, 96%
| 38818-50-7 |
|
1-Bromo-4-(trifluoromethoxy)benzene
| 407-14-7 |
|
1,4-Piperazinedicarboxaldehyde
| 4164-39-0 |
|
[bis(Trimethylsilyl)] Selenide, 98%
| 4099-46-1 |
|
Platinum(IV) Chloride, 99%
| 13454-96-1 |
|
Ruthenium(III) Chloride, Anhydrous, 99+%
| 10049-08-8 |
|
Bcecf-am
| |
|
Sodium tartrate, dihydrate, reagent acs (crystals)
| 6106-24-7 |
|
1,3-Dichloro-4-iodobenzene, 98%
| 29898-32-6 |
|
Benzo-(c)-cinnoline, 99%
| 230-17-1 |
|
3-Chloro-4-Fluoroaniline, 98%
| 367-21-5 |
|
4-(Trifluoromethyl)benzyl alcohol, 99%
| 349-95-1 |
|
l-Tyrosine ethyl ester hydrochloride
| 4089-07-0 |
|
3-Chlorothiophenol, 97%
| 2037-31-2 |
|
2,4,5-Trimethoxybenzaldehyde, 98%
| 4460-86-0 |
|
Acethydrazide, 95%
| 1068-57-1 |
|
2-((n-ethylamino)methyl)-4-nitrophenol
| 71130-60-4 |
|
3-Fluoroiodobenzene, 99%
| 1121-86-4 |
|
Acetylenedicarboxylic acid, 99%
| 142-45-0 |
|
9-Fluorenone, 99+% (gc)
| 486-25-9 |
|
3-Amino-4-chlorobenzotrifluoride, 97%
| 121-50-6 |
|
1-Chloroadamantane, 98%
| 935-56-8 |
|
Palladium on activated carbon (1% Pd)
| |
|
Phenethylamine
| 64-04-0 |
|
Menthofuran, 95% (GC)
| 494-90-6 |
|
Fast Garnet GBC Salt, 90% (TLC)
| 101-89-3 |
|
2-Chlorobenzoyl Chloride, 98%
| 609-65-4 |
|
Thiazol Yellow G
| 1829-00-1 |
|
Calcium nitrate trihydrate, 99.999%
| 10124-37-5 |
|
Urea-d4, 98 atom % d
| 1433-11-0 |
|
Ethyl Isobutyrylacetate, 99%
| 7152-15-0 |
|
L-4-Fluorophenylalanine, 99+% e.e.
| 1132-68-9 |
|
2-Naphthalenesulfonyl chloride, 97%
| 93-11-8 |
|
Ethylcyclohexane, 99+%
| 1678-91-7 |
|
2,3,4-Trichlorophenol, 97%
| 15950-66-0 |
|
|