**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 407-14-7 |1-Bromo-4-(trifluoromethoxy)benzene | ca. 100 | 206-979-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire. Use water spray to
keep fire-exposed containers cool. Combustible liquid. Containers may
explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes,
skin, and clothing. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Keep container tightly closed.
Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 407-14-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 153 - 155 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 67 deg C ( 152.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.6220g/cm3
Molecular Formula: C7H4BrF3O
Molecular Weight: 241.01
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stability unknown.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas, hydrogen
bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 407-14-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Bromo-4-(trifluoromethoxy)benzene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 407-14-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 407-14-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 407-14-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/26/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3,5-Difluorobenzaldehyde, 98+% (GC)
| 32085-88-4 |
|
l-Menthone, 85%
| 14073-97-3 |
|
N-Benzoyl-L-Alanine Methyl Ester, 99+%
| 7244-67-9 |
|
5-Chloro-2-nitro-benzoylchloride
| 41994-44-9 |
|
1,1-Cyclobutanedicarboxylic Acid, 99%
| 5445-51-2 |
|
cis-4-Methylcyclohexanol, 98%
| 7731-28-4 |
|
Dibenzylideneacetone, 96% (GC)
| 35225-79-7 |
|
2,6-Dichloroquinone-4-Chloroimide, 98%
| 101-38-2 |
|
Heptamethyleneimine, 98%
| 1121-92-2 |
|
1-Methyl-6,7-Diethoxy-3,4-Dihydroisoquinoline, 99+%
| 99155-80-3 |
|
Azoene Fast Red PDC Salt, 98% (UV-Vis)
| 62778-15-8 |
|
Citrinin
| 518-75-2 |
|
Ethyl oxanilate, 98%
| 1457-85-8 |
|
2-Aminobenzyl alcohol, 98%
| 5344-90-1 |
|
P-tert.-butyl-tetramercaptocalix(4)arene
| |
|
4-Chloro-3-nitrobenzoylchloride, 96%
| 38818-50-7 |
|
1-Bromo-4-(trifluoromethoxy)benzene
| 407-14-7 |
|
1,4-Piperazinedicarboxaldehyde
| 4164-39-0 |
|
[bis(Trimethylsilyl)] Selenide, 98%
| 4099-46-1 |
|
Platinum(IV) Chloride, 99%
| 13454-96-1 |
|
Ruthenium(III) Chloride, Anhydrous, 99+%
| 10049-08-8 |
|
Bcecf-am
| |
|
Sodium tartrate, dihydrate, reagent acs (crystals)
| 6106-24-7 |
|
1,3-Dichloro-4-iodobenzene, 98%
| 29898-32-6 |
|
Benzo-(c)-cinnoline, 99%
| 230-17-1 |
|
3-Chloro-4-Fluoroaniline, 98%
| 367-21-5 |
|
4-(Trifluoromethyl)benzyl alcohol, 99%
| 349-95-1 |
|
l-Tyrosine ethyl ester hydrochloride
| 4089-07-0 |
|
3-Chlorothiophenol, 97%
| 2037-31-2 |
|
2,4,5-Trimethoxybenzaldehyde, 98%
| 4460-86-0 |
|
Acethydrazide, 95%
| 1068-57-1 |
|
2-((n-ethylamino)methyl)-4-nitrophenol
| 71130-60-4 |
|
3-Fluoroiodobenzene, 99%
| 1121-86-4 |
|
Acetylenedicarboxylic acid, 99%
| 142-45-0 |
|
9-Fluorenone, 99+% (gc)
| 486-25-9 |
|
3-Amino-4-chlorobenzotrifluoride, 97%
| 121-50-6 |
|
1-Chloroadamantane, 98%
| 935-56-8 |
|
Palladium on activated carbon (1% Pd)
| |
|
Phenethylamine
| 64-04-0 |
|
Menthofuran, 95% (GC)
| 494-90-6 |
|
Fast Garnet GBC Salt, 90% (TLC)
| 101-89-3 |
|
2-Chlorobenzoyl Chloride, 98%
| 609-65-4 |
|
Thiazol Yellow G
| 1829-00-1 |
|
Calcium nitrate trihydrate, 99.999%
| 10124-37-5 |
|
Urea-d4, 98 atom % d
| 1433-11-0 |
|
Ethyl Isobutyrylacetate, 99%
| 7152-15-0 |
|
L-4-Fluorophenylalanine, 99+% e.e.
| 1132-68-9 |
|
2-Naphthalenesulfonyl chloride, 97%
| 93-11-8 |
|
Ethylcyclohexane, 99+%
| 1678-91-7 |
|
2,3,4-Trichlorophenol, 97%
| 15950-66-0 |
|
|