**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 32085-88-4 |3,5-Difluorobenzaldehyde | 98+ | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Flammable liquid and vapor.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep away from
heat, sparks and flame. Avoid ingestion and inhalation. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 32085-88-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white - after melting, clear green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 56 deg C ( 132.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H4F2O
Molecular Weight: 142.10
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat, electrical sparks.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 32085-88-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3,5-Difluorobenzaldehyde -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALDEHYDES, N.O.S.*
Hazard Class: 3
UN Number: 1989
Packing Group: III
IMO
Shipping Name: ALDEHYDES, N.O.S.
Hazard Class: 3.3
UN Number: 1989
Packing Group: III
RID/ADR
Shipping Name: ALDEHYDES, FLAMMABLE, N.O.S.
Hazard Class: 3
UN Number: 1989
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 32085-88-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 32085-88-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 32085-88-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/17/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3,5-Difluorobenzaldehyde, 98+% (GC)
| 32085-88-4 |
|
l-Menthone, 85%
| 14073-97-3 |
|
N-Benzoyl-L-Alanine Methyl Ester, 99+%
| 7244-67-9 |
|
5-Chloro-2-nitro-benzoylchloride
| 41994-44-9 |
|
1,1-Cyclobutanedicarboxylic Acid, 99%
| 5445-51-2 |
|
cis-4-Methylcyclohexanol, 98%
| 7731-28-4 |
|
Dibenzylideneacetone, 96% (GC)
| 35225-79-7 |
|
2,6-Dichloroquinone-4-Chloroimide, 98%
| 101-38-2 |
|
Heptamethyleneimine, 98%
| 1121-92-2 |
|
1-Methyl-6,7-Diethoxy-3,4-Dihydroisoquinoline, 99+%
| 99155-80-3 |
|
Azoene Fast Red PDC Salt, 98% (UV-Vis)
| 62778-15-8 |
|
Citrinin
| 518-75-2 |
|
Ethyl oxanilate, 98%
| 1457-85-8 |
|
2-Aminobenzyl alcohol, 98%
| 5344-90-1 |
|
P-tert.-butyl-tetramercaptocalix(4)arene
| |
|
4-Chloro-3-nitrobenzoylchloride, 96%
| 38818-50-7 |
|
1-Bromo-4-(trifluoromethoxy)benzene
| 407-14-7 |
|
1,4-Piperazinedicarboxaldehyde
| 4164-39-0 |
|
[bis(Trimethylsilyl)] Selenide, 98%
| 4099-46-1 |
|
Platinum(IV) Chloride, 99%
| 13454-96-1 |
|
Ruthenium(III) Chloride, Anhydrous, 99+%
| 10049-08-8 |
|
Bcecf-am
| |
|
Sodium tartrate, dihydrate, reagent acs (crystals)
| 6106-24-7 |
|
1,3-Dichloro-4-iodobenzene, 98%
| 29898-32-6 |
|
Benzo-(c)-cinnoline, 99%
| 230-17-1 |
|
3-Chloro-4-Fluoroaniline, 98%
| 367-21-5 |
|
4-(Trifluoromethyl)benzyl alcohol, 99%
| 349-95-1 |
|
l-Tyrosine ethyl ester hydrochloride
| 4089-07-0 |
|
3-Chlorothiophenol, 97%
| 2037-31-2 |
|
2,4,5-Trimethoxybenzaldehyde, 98%
| 4460-86-0 |
|
Acethydrazide, 95%
| 1068-57-1 |
|
2-((n-ethylamino)methyl)-4-nitrophenol
| 71130-60-4 |
|
3-Fluoroiodobenzene, 99%
| 1121-86-4 |
|
Acetylenedicarboxylic acid, 99%
| 142-45-0 |
|
9-Fluorenone, 99+% (gc)
| 486-25-9 |
|
3-Amino-4-chlorobenzotrifluoride, 97%
| 121-50-6 |
|
1-Chloroadamantane, 98%
| 935-56-8 |
|
Palladium on activated carbon (1% Pd)
| |
|
Phenethylamine
| 64-04-0 |
|
Menthofuran, 95% (GC)
| 494-90-6 |
|
Fast Garnet GBC Salt, 90% (TLC)
| 101-89-3 |
|
2-Chlorobenzoyl Chloride, 98%
| 609-65-4 |
|
Thiazol Yellow G
| 1829-00-1 |
|
Calcium nitrate trihydrate, 99.999%
| 10124-37-5 |
|
Urea-d4, 98 atom % d
| 1433-11-0 |
|
Ethyl Isobutyrylacetate, 99%
| 7152-15-0 |
|
L-4-Fluorophenylalanine, 99+% e.e.
| 1132-68-9 |
|
2-Naphthalenesulfonyl chloride, 97%
| 93-11-8 |
|
Ethylcyclohexane, 99+%
| 1678-91-7 |
|
2,3,4-Trichlorophenol, 97%
| 15950-66-0 |
|
|