**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13031-32-8 |Nitromethane-d3, packaged in 1.00 ml a| | 235-892-2 |
| |mpules | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 22 5
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Heating may cause an
explosion.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation. Vapors may cause eye irritation. Causes
redness and pain.
Skin:
Exposure may cause irritation characterized by redness, dryness, and
inflammation. Causes redness and pain.
Ingestion:
Harmful if swallowed. May cause central nervous system depression,
kidney damage, and liver damage. May cause gastrointestinal
irritation with nausea, vomiting and diarrhea.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to
those described for ingestion. May cause pulmonary edema and severe
respiratory disturbances.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Absorption
into the body leads to the formation of methemoglobin which in
sufficient concentrations causes cyanosis (bluish discoloration of
skin due to deficient oxygenation of the blood).
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Possible aspiration hazard. Get medical aid
immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. Vapors may form an explosive
mixture with air. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire. Flammable liquid and vapor.
Extinguishing Media:
For large fires, use water spray, fog, or alcohol-resistant foam.
Use water spray to cool fire-exposed containers. Do NOT use dry
chemical.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take
precautionary measures against static discharges.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep under a nitrogen blanket.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 13031-32-8:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 100 deg C @ 760.00m
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 35 deg C ( 95.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.1830g/cm3
Molecular Formula: CD3NO2
Molecular Weight: 64.06
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Substance is shock
sensitive and thermally unstable. Substance forms an explosive sodium
salt which bursts into flame on contact with water.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition
sources.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, strong acids, bases, amines,
copper, copper alloys, formaldehyde, nitric acid, sodium hydroxide,
sulfuric acid, acids (organic, e.g. acetic acid, benzoic acid, formic
acid, methanoic acid, oxalic acid), ketones (e.g. acetone,
acetophenone, MEK, MIBK), calcium hypochlorite, lead, acetone,
potassium hydroxide, silver nitrate, 1,2-diaminoethane, metal
halides, aniline, calcium hydroxide.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13031-32-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Nitromethane-d3, packaged in 1.00 ml ampules -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
see Dictionary of Substances and their Effects.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 5 Heating may cause an explosion.
Safety Phrases:
S 41 In case of fire and/or explosion do not breathe
fumes.
WGK (Water Danger/Protection)
CAS# 13031-32-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13031-32-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13031-32-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/14/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Acetophenone, 99%
| 98-86-2 |
|
N-Ethyl-N-Hydroxyethylaniline, 96%
| 92-50-2 |
|
2-Amino-2-ethyl-1,3-propanediol, 97%
| 115-70-8 |
|
Acetyl chloride, p.a.
| 75-36-5 |
|
o-Benzylhydroxylamine hydrochloride,99%
| 2687-43-6 |
|
Bromocresol Purple, Water Soluble, Indicator Grade
| 62625-30-3 |
|
2-Bromoethylbenzene, 98%
| 1973-22-4 |
|
Ethyl (Z)-3-Bromo-2-Propenoate, 99%
| 31930-34-4 |
|
Calix[8]Arene, 97% (Elemental Analysis)
| 82452-93-5 |
|
D(+)-Camphoric acid, 99%
| 124-83-4 |
|
1,1'-Carbonyldiimidazole, 97%
| 530-62-1 |
|
Celatom FW-14
| 60676-86-0 |
|
Chalkone, 97%
| 94-41-7 |
|
4-Cyanophenol, 99%
| 767-00-0 |
|
Tetranitro Blue Tetrazolium Chloride Contains Ethanol of
| 1184-43-6 |
|
Cyclohexyl isocyanide, 99%
| 931-53-3 |
|
2,4-Dichlorobenzoic acid, 98%
| 50-84-0 |
|
2,4-Dichlorophenylacetic Acid, 99%
| 19719-28-9 |
|
3,4-Dimethoxyacetophenone, 98% (GC)
| 1131-62-0 |
|
2,3-Dimethoxybenzoic Acid, 99%
| 1521-38-6 |
|
Dimethyl isophthalate (Pract)
| 1459-93-4 |
|
1,2-Diphenylhydrazine 97%
| 122-66-7 |
|
Dl-Norleucine, 98%
| 616-06-8 |
|
1-(4-Methoxyphenyl)Piperazine, 96% (GC)
| 38212-30-5 |
|
Ethyl 2-Amino-4-Thiazoleacetate, 99%
| 53266-94-7 |
|
4-Fluoro-alpha-cyclopropyl-alpha--
| 427-53-2 |
|
2,4-Pentanedione, 99+%
| 123-54-6 |
|
Itaconic Acid, 99+%
| 97-65-4 |
|
N-Benzyl-N-Ethylaniline, 99+%
| 92-59-1 |
|
2,3-Dibromosuccinic acid, 95% (titr.)
| 526-78-3 |
|
Methyl 4-hydroxybenzoate, sodium salt, 99.0-102.0%
| 5026-62-0 |
|
Methyl 4-tert-butylbenzoate, 99%
| 26537-19-9 |
|
Trifluoroacetic Acid-D, 99.5 Atom % D
| 599-00-8 |
|
3-Nitrobenzaldehyde, 99%
| 99-61-6 |
|
2-Nitro-2-methyl-1,3-propanediol, 99%
| 77-49-6 |
|
l-2-Octanol, 99+%
| 5978-70-1 |
|
o-Nitrocinnamic acid, 97%, predominantly trans
| 612-41-9 |
|
Acetone-d6, 99.8 atom % D
| 666-52-4 |
|
3-Picolyl chloride hydrochloride, 99%
| 6959-48-4 |
|
Acacia
| 9000-01-5 |
|
Potassium Hydride, 20-25% wt.% Dispersion in Mineral Oil
| 7693-26-7 |
|
Propionaldehyde, 99+%
| 123-38-6 |
|
Trifluoroacetic Acid-D, Packaged in 1ml Ampules, 99.5 Atom % D
| 599-00-8 |
|
Nitromethane-d3, packaged in 1.00 ml ampules, 99 atom % D
| 13031-32-8 |
|
Sudan ii
| 3118-97-6 |
|
3Tert.-Butylamine, 99%
| 75-64-9 |
|
Tetrabutylammonium fluoride, 1M solution in THF, containing less than
| 109-99-9 |
|
Tetraphenylphosphonium Bromide, 99%
| 2751-90-8 |
|
Tosylmethyl Isocyanide, 98%
| 36615-45-9 |
|
9-Vinylanthracene
| 2444-68-0 |
|
|