**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-64-9 |tert-Butylamine | 99 | 200-888-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F+
Risk Phrases: 11 25 34 20
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Toxic if swallowed. Causes burns. Harmful by
inhalation.Air sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye irritation and possible burns.
Skin:
Causes severe skin irritation and possible burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns. May cause
perforation of the digestive tract.
Inhalation:
Causes chemical burns to the respiratory tract. May cause pulmonary
edema and severe respiratory disturbances. Inhalation may be fatal
as a result of spasm, inflammation, edema of the larynx and bronchi,
chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Extremely
flammable liquid and vapor. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Contact professional fire-fighters
immediately.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Take precautionary measures against static discharges.
Keep away from heat, sparks and flame. Do not get on skin or in
eyes. Do not ingest or inhale. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 75-64-9:
Germany: 5 ppm TWA; 15 mg/m3 TWA
Germany: Skin absorber
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: amine-like
pH: Not available.
Vapor Pressure: 362 mm Hg @ 25 C
Viscosity: Not available.
Boiling Point: 46 deg C @ 760.00mm Hg
Freezing/Melting Point: -67 deg C
Autoignition Temperature: 380 deg C ( 716.00 deg F)
Flash Point: -9 deg C ( 15.80 deg F)
Explosion Limits, lower: 1.70 vol %
Explosion Limits, upper: 8.90 vol %
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density: .6960g/cm3
Molecular Formula: C4H11N
Molecular Weight: 73.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, mechanical shock, ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, organic acids, isocyanates, alcohols
and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene
glycol), phenols and cresols (e.g. carbolic acid, creosote, cresol,
phenol, resorcinol).
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-64-9: EO3330000
LD50/LC50:
CAS# 75-64-9: Inhalation, rat: LC50 = 3800 mg/m3/4H; Oral, rat: LD50
= 44 mg/kg.
Carcinogenicity:
tert-Butylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S.*
Hazard Class: 3 (8)
UN Number: 2733
Packing Group: II
IMO
Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S.
Hazard Class: 3.2 (8)
UN Number: 2733
Packing Group: II
RID/ADR
Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S.
Hazard Class: 3
UN Number: 2733
Packing group: II
USA RQ: CAS# 75-64-9: 1000 lb final RQ (Listed under Butylamine); 454 kg final R
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F+
Risk Phrases:
R 11 Highly flammable.
R 20 Harmful by inhalation.
R 25 Toxic if swallowed.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 29 Do not empty into drains.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 75-64-9: 1
Canada
CAS# 75-64-9 is listed on Canada's DSL List.
CAS# 75-64-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-64-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/12/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|