**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13463-40-6 |Iron pentacarbonyl | 100 | 236-670-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+ F
Risk Phrases: 11 24 26/28
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Toxic in contact with skin. Very toxic by
inhalation and if swallowed.Light sensitive.Air sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May be fatal if absorbed through the skin.
Ingestion:
May be fatal if swallowed.
Inhalation:
May be fatal if inhaled. Vapors may cause dizziness or suffocation.
Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
POISON material. In case of contact, get medical aid immediately.
Immediately flush eyes or skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash
clothing before reuse. Destroy contaminated shoes.
Ingestion:
POISON material. If swallowed, get medical aid immediately. Only
induce vomiting if directed to do so by medical personnel. Never give
anything by mouth to an unconscious person.
Inhalation:
POISON material. If inhaled, get medical aid immediately. Remove
victim to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Notes to Physician:
Effects may be delayed. Persons with liver, kidney, or central
nervous system diseases may be at increased risk from exposure to
this product.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Use water spray to keep
fire-exposed containers cool. Flammable liquid and vapor. Vapors are
heavier than air and may travel to a source of ignition and flash
back. Vapors can spread along the ground and collect in low or
confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Wear a
self contained breathing apparatus and appropriate personal
protection. (See Exposure Controls, Personal Protection section).
Remove all sources of ignition. Use a spark-proof tool. Provide
ventilation. A vapor suppressing foam may be used to reduce vapors.
Evacuate unnecessary personnel.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Do not
get in eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Use and store under nitrogen. Discard contaminated
shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames. Do not
breathe vapor. Keep away from heat, sparks and flame. Inform laundry
personnel of contaminant's hazards. Use only with adequate
ventilation or respiratory protection.
Storage:
Keep away from heat, sparks, and flame. Dark room.
Refrigerator/flammables. Store under nitrogen. Store in air tight
containers. Store in a cool, dry area away from incompatible
substances. Separate from oxidizing materials.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits. Ventilation fans and other electrical
service must be non-sparking and have an explosion-proof design.
Exposure Limits
CAS# 13463-40-6:
United Kingdom, WEL - TWA: 0.01 ppm TWA (as Fe); 0.08 mg/m3 TWA (
Fe)
United Kingdom, WEL - STEL: 0.03 ppm STEL (as Fe); 0.24 mg/m3 STE
(as Fe)
Belgium - TWA: 0.1 ppm VLE (as Fe); 0.23 mg/m3 VLE (as Fe)
Belgium - STEL: 0.2 ppm VLE (as Fe); 0.46 mg/m3 VLE (as Fe)
France - VME: 0.1 ppm VME (as Fe); 0.8 mg/m3 VME (as Fe)
Germany: 0.1 ppm TWA; 0.81 mg/m3 TWA
Malaysia: 0.1 ppm TWA (as Fe); 0.23 mg/m3 TWA (as Fe)
Netherlands: 0.01 ppm MAC; 0.08 mg/m3 MAC (as Fe)
Russia: 0.1 mg/m3 TWA
Spain: 0.1 ppm VLA-ED (as Fe); 0.8 mg/m3 VLA-ED (as Fe)
Spain: 0.2 ppm VLA-EC (as Fe); 1.6 mg/m3 VLA-EC (as Fe)
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: oily, colorless to light yellow - light yellow to da
Odor: none reported
pH: Not available.
Vapor Pressure: 40 mm Hg @ 30.3 deg C
Viscosity: Viscous.
Boiling Point: 103 deg C @ 760 mm Hg
Freezing/Melting Point: -20 deg C
Autoignition Temperature: 49 deg C ( 120.20 deg F)
Flash Point: -15 deg C ( 5.00 deg F)
Explosion Limits, lower: 3.7
Explosion Limits, upper: 12.5
Decomposition Temperature: 200 deg C
Solubility in water: Insoluble.
Specific Gravity/Density: 1.4900 g/cm3
Molecular Formula: C5FeO5
Molecular Weight: 195.90
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Decomposes on exposure to air and light.
Conditions to Avoid:
Light, ignition sources, exposure to air, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, amines, halogens.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, oxides of iron.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13463-40-6: NO4900000
LD50/LC50:
CAS# 13463-40-6: Inhalation, mouse: LC50 = 2190 mg/m3/30M;
Inhalation, rat: LC50 = 10 ppm/4H; Oral, mouse: LD50 = 62 mg/kg;
Oral, rabbit: LD50 = 12 mg/kg; Oral, rat: LD50 = 25 mg/kg; Skin,
rabbit: LD50 = 56 mg/kg.
Carcinogenicity:
Iron pentacarbonyl -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: IRON PENTACARBONYL
Hazard Class: 6.1 (3)
UN Number: 1994
Packing Group: I
IMO
Shipping Name: IRON PENTACARBONYL
Hazard Class: 6.1 (3)
UN Number: 1994
Packing Group: I
RID/ADR
Shipping Name: IRON PENTACARBONYL
Hazard Class: 6.1
UN Number: 1994
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ F
Risk Phrases:
R 11 Highly flammable.
R 24 Toxic in contact with skin.
R 26/28 Very toxic by inhalation and if swallowed.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13463-40-6: No information available.
Canada
CAS# 13463-40-6 is listed on Canada's DSL List.
CAS# 13463-40-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13463-40-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/06/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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Ethyl Picolinoylacetate
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2,4-Dimethylglutaric Acid, 98+%, Mixture of DL and Meso
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Ethyl Isothiocyanate, 99+% (GC)
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Nonadecafluorodecanoic acid, 96%
| 335-76-2 |
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5-Bromo-4-Chloro-3-Indolyl Phosphate, Disodium Salt, Hydrate, 98%
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n-Methyl-o-phenylenediamine dihydro- chloride, 98% (titr.)
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O-Benzyl-L-Tyrosine, 99%
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Nickel(ii) bromide, anhydrous, 99%
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3,4,5-Trimethoxyphenylacetonitrile, 97%
| 13338-63-1 |
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Cresol, tech.
| 1319-77-3 |
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Ethyl 2-methylphenylacetate, 96%
| 40291-39-2 |
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4-Ethoxy-3-Methoxybenzyl Alcohol, 98%
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9,10-Bis(chloromethyl)anthracene, 99% (HPLC)
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Butylated Hydroxyanisole, 96%(GC)
| 25013-16-5 |
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Poly(hexadecyl methacrylate), 28% solution in toluene, average M.W.
| 108-88-3 |
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(Carbethoxymethyl)-Triphenyl-Phosphonium Bromide, 98%
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|
2-Chloro-4-Methoxyphenol, 97%
| 18113-03-6 |
|
P-Bromobenzamide, 97%
| 698-67-9 |
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3-Amino-4,4,4-trifluorobutyric acid
| 584-20-3 |
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1,2-Dicyanobenzene, 98%
| 91-15-6 |
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| 2078-54-8 |
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| 319-78-8 |
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Cytidine-5'-Monophosphoric Acid Mono-Hydrate, 99%
| 63-37-6 |
|
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| 33725-74-5 |
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Trimethylolpropane Mono Allyl Ether, 98%
| 682-11-1 |
|
3,5-Dimethoxyaniline, 98%
| 10272-07-8 |
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Azure a (cert)
| 531-53-3 |
|
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| 69645-84-7 |
|
Alpha-Chlorocinnamaldehyde, 95%
| 18365-42-9 |
|
Trans-2-Phenylcyclopropylamine Hydrochloride, 97%
| 95-62-5 |
|
3-Bromopyruvic Acid, 98% (titr.)
| 1113-59-3 |
|
1-Adamantaneethanol, 98%
| 6240-11-5 |
|
D-(-)-2,5-Dihydrophenylglycine, 97%(HPLC)
| 26774-88-9 |
|
Lissamine green B
| 3087-16-9 |
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5-Doxyl-Stearic Acid, Free Radical
| 29545-48-0 |
|
Naphthol AS, 99%
| 92-77-3 |
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Iron pentacarbonyl
| 13463-40-6 |
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Sodium Borodeuteride, 98 Atom % D
| 15681-89-7 |
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| 7791-12-0 |
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| 36402-52-5 |
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| 99-28-5 |
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| 93343-10-3 |
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