**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 15681-89-7 |Sodium Borodeuteride | 98 Atom | 239-764-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 15 25 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with water liberates extremely flammable gases. Toxic if
swallowed. Causes burns.Hygroscopic (absorbs moisture from the
air).Water-reactive.
Potential Health Effects
Eye:
Causes eye burns. When substance becomes wet or comes in contact
with moisture of the mucous membranes, it will cause irritation. May
cause lacrimation (tearing), blurred vision, and photophobia. May
cause chemical conjunctivitis and corneal damage.
Skin:
Contact with skin causes irritation and possible burns, especially
if the skin is wet or moist. May cause skin rash (in milder cases),
and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause liver and kidney damage. May
cause perforation of the digestive tract. May cause cardiac
disturbances. May cause central nervous system depression. May cause
systemic effects. May cause nausea, vomiting, abdominal pain, and
increased salivation.
Inhalation:
May cause liver and kidney damage. Causes chemical burns to the
respiratory tract. Aspiration may lead to pulmonary edema. May cause
cardiac abnormalities. May cause systemic effects. Olfactory fatigue
may occur. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
May cause liver and kidney damage. Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
If water-reactive products are embedded in the skin, no water should
be applied. The embedded products should be covered with a light
oil.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Reacts violently with water giving off flammable
gas which may explode. During a fire, irritating and highly toxic
gases may be generated by thermal decomposition or combustion. Water
Reactive. Material will react with water and may release a flammable
and/or toxic gas. Dust can be an explosion hazard when exposed to
heat or flame. Flammable solid. May ignite or explode on contact
with steam or moist air. May burn rapidly with flare burning effect.
May re-ignite after fire is extinguished. Runoff from fire control
or dilution water may cause pollution.
Extinguishing Media:
Use dry sand or earth to smother fire. DO NOT USE WATER! Do NOT get
water inside containers. Contact professional fire-fighters
immediately. For small fires, use dry chemical, carbon dioxide,
sand, earth, water spray or regular foam. Cool containers with
flooding quantities of water until well after fire is out. For large
fires, use dry sand, dry chemical, soda ash or lime or withdraw from
area and let fire burn.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Scoop up with a nonsparking tool, then place into
a suitable container for disposal. Avoid generating dusty
conditions. Remove all sources of ignition. Provide ventilation. Do
not expose spill to water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not allow
water to get into the container because of violent reaction. Minimize
dust generation and accumulation. Do not breathe dust, vapor, mist,
or gas. Do not get in eyes, on skin, or on clothing. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep container tightly closed. Keep away from heat, sparks and
flame. Avoid ingestion and inhalation. Do not ingest or inhale. Do
not allow contact with water. Discard contaminated shoes. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Keep from contact with
moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Water free area.
Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 15681-89-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 300 deg C
Autoignition Temperature: 400 deg C ( 752.00 deg F)
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: BD4Na
Molecular Weight: 41.86
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Combines vigorously
or explosively with water.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, strong oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Contact with water liberates highly flammable gases., strong
oxidizing agents, acids, alcohols, moisture, water.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, oxides of boron, borane.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 15681-89-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Sodium Borodeuteride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: SODIUM BOROHYDRIDE
Hazard Class: 4.3
UN Number: 1426
Packing Group: I
IMO
Shipping Name: SODIUM BOROHYDRIDE
Hazard Class: 4.3
UN Number: 1426
Packing Group: I
RID/ADR
Shipping Name: SODIUM BOROHYDRIDE
Hazard Class: 4.3
UN Number: 1426
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 15 Contact with water liberates extremely
flammable gases.
R 25 Toxic if swallowed.
R 34 Causes burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 15681-89-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 15681-89-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 15681-89-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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2-Heptanol, 99+%
| 543-49-7 |
|
Ethyl Picolinoylacetate
| 26510-52-1 |
|
2,4-Dimethylglutaric Acid, 98+%, Mixture of DL and Meso
| 2121-67-7 |
|
Ethyl Isothiocyanate, 99+% (GC)
| 542-85-8 |
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Nonadecafluorodecanoic acid, 96%
| 335-76-2 |
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5-Bromo-4-Chloro-3-Indolyl Phosphate, Disodium Salt, Hydrate, 98%
| 0-00-1 |
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n-Methyl-o-phenylenediamine dihydro- chloride, 98% (titr.)
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O-Benzyl-L-Tyrosine, 99%
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Nickel(ii) bromide, anhydrous, 99%
| 13462-88-9 |
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3,4,5-Trimethoxyphenylacetonitrile, 97%
| 13338-63-1 |
|
Cresol, tech.
| 1319-77-3 |
|
Ethyl 2-methylphenylacetate, 96%
| 40291-39-2 |
|
4-Ethoxy-3-Methoxybenzyl Alcohol, 98%
| 61813-58-9 |
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9,10-Bis(chloromethyl)anthracene, 99% (HPLC)
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|
Phenyl sulfide, 99%
| 139-66-2 |
|
Butylated Hydroxyanisole, 96%(GC)
| 25013-16-5 |
|
Poly(hexadecyl methacrylate), 28% solution in toluene, average M.W.
| 108-88-3 |
|
(Carbethoxymethyl)-Triphenyl-Phosphonium Bromide, 98%
| 1530-45-6 |
|
2-Chloro-4-Methoxyphenol, 97%
| 18113-03-6 |
|
P-Bromobenzamide, 97%
| 698-67-9 |
|
3-Amino-4,4,4-trifluorobutyric acid
| 584-20-3 |
|
1,2-Dicyanobenzene, 98%
| 91-15-6 |
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2,6-Dimethylpiperidine, 99%, Min. 95% Cis-Isomer
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2',3',5'-Triacetylguanosine
| 6979-94-8 |
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2,6-Diisopropylphenol, Tech., 90%
| 2078-54-8 |
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D-Isoleucine
| 319-78-8 |
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Cytidine-5'-Monophosphoric Acid Mono-Hydrate, 99%
| 63-37-6 |
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| 33725-74-5 |
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Trimethylolpropane Mono Allyl Ether, 98%
| 682-11-1 |
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3,5-Dimethoxyaniline, 98%
| 10272-07-8 |
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Azure a (cert)
| 531-53-3 |
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2,3-Dichloro-5-(Trifluoromethyl)pyridine, 97%
| 69645-84-7 |
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Alpha-Chlorocinnamaldehyde, 95%
| 18365-42-9 |
|
Trans-2-Phenylcyclopropylamine Hydrochloride, 97%
| 95-62-5 |
|
3-Bromopyruvic Acid, 98% (titr.)
| 1113-59-3 |
|
1-Adamantaneethanol, 98%
| 6240-11-5 |
|
D-(-)-2,5-Dihydrophenylglycine, 97%(HPLC)
| 26774-88-9 |
|
Lissamine green B
| 3087-16-9 |
|
5-Doxyl-Stearic Acid, Free Radical
| 29545-48-0 |
|
Naphthol AS, 99%
| 92-77-3 |
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Iron pentacarbonyl
| 13463-40-6 |
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Sodium Borodeuteride, 98 Atom % D
| 15681-89-7 |
|
4-Methylsulphonylbenzyl Bromide, 85+%
| 53606-06-7 |
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| 1009-61-6 |
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Thallium (I) Chloride, 99%
| 7791-12-0 |
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IR-140, Laser Grade, 99% (UV-Vis)
| 53655-17-7 |
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Meso-2,4-Pentanediol, 99%
| 36402-52-5 |
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2,6-Dibromo-4-Nitrophenol, 99+% (TLC)
| 99-28-5 |
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3,5-Difluoroanisole, 98%
| 93343-10-3 |
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Cyclopropyl Diphenyl Carbinol, 99+%
| 5785-66-0 |
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