**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 139-66-2 |Phenyl sulfide | 99 | 205-371-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to skin.Stench.
Potential Health Effects
Eye:
May cause severe eye irritation.
Skin:
May cause severe skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed. Contact with stomach acid may
liberate toxic hydrogen sulfide gas. Hydrogen sulfide affects the
nervous system producing headache, dizziness, excitement, staggering
gait, diarrhea, and painful or difficult urination. H2S doesn't
combine with hemoglobin; its asphyxiant action is due to paralysis of
the respiratory center.
Inhalation:
Causes irritation of the mucous membrane and upper respiratory
tract.
Chronic:
Rats fed large doses of phenyl sulfide for 13 weeks displayed
changes in liver weight and bladder weight.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Get medical aid. Wash
clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Keep container tightly closed. Use only in a
chemical fume hood. Avoid breathing vapor or mist.
Storage:
Keep containers tightly closed. Store in a cool, dry area away from
incompatible substances. Separate from oxidizing materials.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 139-66-2:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: stench
pH: Not available.
Vapor Pressure: 7.54E-003 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 296 deg C @ 760 mmHg
Freezing/Melting Point: -40 deg C
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: insoluble
Specific Gravity/Density: 1.11 g/cm3
Molecular Formula: C12H10S
Molecular Weight: 186.27
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, diazonium salts.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen sulfide, sulfur oxides
(SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 139-66-2: SX2275000
LD50/LC50:
CAS# 139-66-2: Oral, rat: LD50 = 490 uL/kg; Skin, rabbit: LD50 =
11300 uL/kg.
490 uL/kg = 544 mg/kg.
Carcinogenicity:
Phenyl sulfide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 38 Irritating to skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 139-66-2: No information available.
Canada
CAS# 139-66-2 is listed on Canada's DSL List.
CAS# 139-66-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 139-66-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/16/1999 Revision #4 Date: 6/12/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Heptanol, 99+%
| 543-49-7 |
|
Ethyl Picolinoylacetate
| 26510-52-1 |
|
2,4-Dimethylglutaric Acid, 98+%, Mixture of DL and Meso
| 2121-67-7 |
|
Ethyl Isothiocyanate, 99+% (GC)
| 542-85-8 |
|
Nonadecafluorodecanoic acid, 96%
| 335-76-2 |
|
5-Bromo-4-Chloro-3-Indolyl Phosphate, Disodium Salt, Hydrate, 98%
| 0-00-1 |
|
n-Methyl-o-phenylenediamine dihydro- chloride, 98% (titr.)
| 25148-68-9 |
|
O-Benzyl-L-Tyrosine, 99%
| 16652-64-5 |
|
Nickel(ii) bromide, anhydrous, 99%
| 13462-88-9 |
|
3,4,5-Trimethoxyphenylacetonitrile, 97%
| 13338-63-1 |
|
Cresol, tech.
| 1319-77-3 |
|
Ethyl 2-methylphenylacetate, 96%
| 40291-39-2 |
|
4-Ethoxy-3-Methoxybenzyl Alcohol, 98%
| 61813-58-9 |
|
9,10-Bis(chloromethyl)anthracene, 99% (HPLC)
| 10387-13-0 |
|
Phenyl sulfide, 99%
| 139-66-2 |
|
Butylated Hydroxyanisole, 96%(GC)
| 25013-16-5 |
|
Poly(hexadecyl methacrylate), 28% solution in toluene, average M.W.
| 108-88-3 |
|
(Carbethoxymethyl)-Triphenyl-Phosphonium Bromide, 98%
| 1530-45-6 |
|
2-Chloro-4-Methoxyphenol, 97%
| 18113-03-6 |
|
P-Bromobenzamide, 97%
| 698-67-9 |
|
3-Amino-4,4,4-trifluorobutyric acid
| 584-20-3 |
|
1,2-Dicyanobenzene, 98%
| 91-15-6 |
|
2,6-Dimethylpiperidine, 99%, Min. 95% Cis-Isomer
| 766-17-6 |
|
2',3',5'-Triacetylguanosine
| 6979-94-8 |
|
2,6-Diisopropylphenol, Tech., 90%
| 2078-54-8 |
|
D-Isoleucine
| 319-78-8 |
|
Cytidine-5'-Monophosphoric Acid Mono-Hydrate, 99%
| 63-37-6 |
|
Tetrabutylammonium borohydride, 98%
| 33725-74-5 |
|
Trimethylolpropane Mono Allyl Ether, 98%
| 682-11-1 |
|
3,5-Dimethoxyaniline, 98%
| 10272-07-8 |
|
Azure a (cert)
| 531-53-3 |
|
2,3-Dichloro-5-(Trifluoromethyl)pyridine, 97%
| 69645-84-7 |
|
Alpha-Chlorocinnamaldehyde, 95%
| 18365-42-9 |
|
Trans-2-Phenylcyclopropylamine Hydrochloride, 97%
| 95-62-5 |
|
3-Bromopyruvic Acid, 98% (titr.)
| 1113-59-3 |
|
1-Adamantaneethanol, 98%
| 6240-11-5 |
|
D-(-)-2,5-Dihydrophenylglycine, 97%(HPLC)
| 26774-88-9 |
|
Lissamine green B
| 3087-16-9 |
|
5-Doxyl-Stearic Acid, Free Radical
| 29545-48-0 |
|
Naphthol AS, 99%
| 92-77-3 |
|
Iron pentacarbonyl
| 13463-40-6 |
|
Sodium Borodeuteride, 98 Atom % D
| 15681-89-7 |
|
4-Methylsulphonylbenzyl Bromide, 85+%
| 53606-06-7 |
|
1,4-Diacetylbenzene, 98%
| 1009-61-6 |
|
Thallium (I) Chloride, 99%
| 7791-12-0 |
|
IR-140, Laser Grade, 99% (UV-Vis)
| 53655-17-7 |
|
Meso-2,4-Pentanediol, 99%
| 36402-52-5 |
|
2,6-Dibromo-4-Nitrophenol, 99+% (TLC)
| 99-28-5 |
|
3,5-Difluoroanisole, 98%
| 93343-10-3 |
|
Cyclopropyl Diphenyl Carbinol, 99+%
| 5785-66-0 |
|
|