**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 138-86-3 |Dipentene | 75-80 | 205-341-0 |
|----------------|--------------------------------------|----------|-----------|
| 586-62-9 |Terpinolene | 20-25 | 209-578-0 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI N
Risk Phrases: 10 38 43 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to skin. May cause sensitization by skin
contact. Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause irritation and dermatitis. May
cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingestion of large amounts may cause CNS depression.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to
pulmonary edema. Vapors may cause dizziness or suffocation. Can
produce delayed pulmonary edema. May cause burning sensation in the
chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Use agent most appropriate to
extinguish fire. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Keep away from heat, sparks
and flame. Avoid ingestion and inhalation. Wash clothing before
reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 138-86-3:
CAS# 586-62-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: citrus-like odor
pH: Not available.
Vapor Pressure: 1.98 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 165 deg C @ 760 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 46 deg C ( 114.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: in water: < 1%
Specific Gravity/Density: .8500g/cm3
Molecular Formula: C10H16
Molecular Weight: 136.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 138-86-3: OS8100000
CAS# 586-62-9: WZ6870000
LD50/LC50:
CAS# 138-86-3: Draize test, rabbit, skin: 500 mg/24H Moderate;
Inhalation, mouse: LC50 = 67500 mg/m3; Oral, mouse: LD50 = 5550
uL/kg; Oral, rat: LD50 = 5300 mg/kg.
CAS# 586-62-9: Draize test, rabbit, skin: 10%/24H Moderate; Oral,
rat: LD50 = 4390 mg/kg.
Carcinogenicity:
Dipentene -
Not listed by ACGIH, IARC, or NTP.
Terpinolene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DIPENTENE
Hazard Class: 3
UN Number: 2052
Packing Group: III
IMO
Shipping Name: DIPENTENE
Hazard Class: 3.3
UN Number: 2052
Packing Group: III
RID/ADR
Shipping Name: DIPENTENE
Hazard Class: 3
UN Number: 2052
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI N
Risk Phrases:
R 10 Flammable.
R 38 Irritating to skin.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 138-86-3: No information available.
CAS# 586-62-9: No information available.
Canada
CAS# 138-86-3 is listed on Canada's DSL List.
CAS# 586-62-9 is listed on Canada's DSL List.
CAS# 138-86-3 is listed on Canada's Ingredient Disclosure List.
CAS# 586-62-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 138-86-3 is listed on the TSCA inventory.
CAS# 586-62-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 4/05/1997 Revision #9 Date: 8/24/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
6,7-Dimethoxy-1,2,3,4-tetrahydro-1-isoquinoline acetic acid
| 303094-23-7 |
|
6,7-Dimethoxy-1,2,3,4-tetrahydro-1- isoquinoline acetonitrile
| 0-00-0 |
|
6,7-Diethoxy-1,2,3,4-Tetrahydro-1- Isoquinoline Acetonitrile
| 0-00-0 |
|
6,7-Dimethoxy-3-methyl-1,2,3,4-tetrahydroi soquinoline hydrochloride
| 0-00-0 |
|
1-Isopropyl-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline
| 0-01-1 |
|
6,7-Dimethoxy-3-methyl-3,4-dihydroisoquino line hydrochloride
| 0-00-0 |
|
6,7-Dimethoxy-1,3-dimethyl-3,4-dihydroisoq uinoline hydrochloride,
| 0-00-0 |
|
6,7-Dimethoxy-1-Phenyl-1,2,3,4-Tetrahydroisoquinoline Hydrochloride
| 0-00-1 |
|
Cyclohexanone oxime, 97%
| 100-64-1 |
|
Methyl-(s)-3-(tert.-butoxycarbonyl)-2,2-di
| 108149-60-6 |
|
Phosphoric acid, 85% solution in water, c.p.
| 7664-38-2 |
|
4-Sulfonic calix[8]arene
| |
|
2-Chloroethanesulfonic Acid, Sodium Salt Monohydrate, 98%
| 15484-44-3 |
|
2,5-Bis(diethoxyphosphoryl)thiophene
| 100651-98-7 |
|
1,2-bis(dimethoxyphosphoryl)benzene, 97% ( gc)
| 15104-46-8 |
|
4-Amino-6-mercaptopyrazolo[3,4-d]pyrimidine
| 23771-52-0 |
|
Tris(acetonitrile)molybdenumtricarbonyl
| 15038-48-9 |
|
Tris(acetonitrile)chromiumtricarbonyl
| 16800-46-7 |
|
Di[(Methylcyclopentadienyl)molybdenum Tricarbonyl]
| 33056-03-0 |
|
Dipentene, mixture of limonene, 56.0-64.0% , and terpinolene,
| 138-86-3 |
|
Trans 2, trans 4-nonadienal, 90%
| 5910-28-1 |
|
4-Methyl-2-Pentenal, 95%
| 5362-56-1 |
|
L-TERT.-LEUCINE, 99%
| 20859-02-3 |
|
1-Fluorohexane, 99+% (GC)
| 373-14-8 |
|
N-BUTYL METHYLSULFIDE
| 628-29-5 |
|
alpha-Tetralone, 85%
| 529-34-0 |
|
2,2,4-Trimethylpentane, c.p.
| 540-84-1 |
|
TRIS-(2-CYANOETHYL)PHOSPHINE
| 4023-53-4 |
|
3-Bromophenylacetonitrile, 98+%
| 31938-07-5 |
|
POTASSIUM FLUOROZIRCONATE
| 16923-95-8 |
|
3,5-Dibromo-4-Hydroxybenzaldehyde, 98%
| 2973-77-5 |
|
5'-Chloro-2'-hydroxyacetophenone, 99%
| 1450-74-4 |
|
10-UNDECYNOIC ACID
| 2777-65-3 |
|
Lithium tert-butoxide
| 1907-33-1 |
|
Lithium methoxide
| 865-34-9 |
|
2-Chloroethylphosphonic Acid, Tech., 90%
| 16672-87-0 |
|
2-Phenylimidazole ,98%
| 670-96-2 |
|
SOLVENT BLUE 36
| |
|
Cyclopentadienylsodium, 0.4 M in tetrahydrofuran
| 4984-82-1 |
|
Selenium(IV) Chloride (-8 Mesh), 95%
| 10026-03-6 |
|
4-trans-Phenylcyclohexane-cis-dicarboxylic acid, 97%
| 36299-64-6 |
|
cis-2-Benzoyl-1-cyclohexanecarboxylic acid, 98%
| 6939-99-7 |
|
trans-2-Benzoyl-1-cyclohexanecarboxylic acid, 99%
| 3586-84-3 |
|
cis-2-(4-Methylbenzoyl)-1-cyclohexanecarboxylic acid, 99%
| 107147-13-7 |
|
trans-2-(4-Methylbenzoyl)-1-cyclohexanecarboxylic acid
| 151830-92-1 |
|
2-trans-Benzoyl-5-trans-phenyl-1-cyclohexanecarboxylic acid, 99%
| 35033-79-5 |
|
trans-2-(p-Chlorobenzoyl)-1-cyclohexanecarboxylic acid, 98%
| 52240-19-4 |
|
cis-2-(4-Fluorobenzoyl)-1-cyclohexane-carboxylic acid, 99%
| 154810-33-0 |
|
trans-2-(4-Fluorobenzoyl)-1-cyclohexane-carboxylic acid, 99%
| 111857-42-2 |
|
Cis-2-(4-Bromobenzoyl)-1-Cyclohexane-Carboxylic Acid
| |
|
|