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MSDS 
:
 4-Sulfonic calix[8]arene
CAS 
:
 
SYNONYMS 
:
 None.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Water-reactive.The toxicological properties of this material have not
been fully investigated.

Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this
material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this
material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Powder
Color: beige to gray - light green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C56H48O32S8
Molecular Weight: 1489.00

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stability unknown.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to moist air or
water.
Incompatibilities with Other Materials:
Water.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
No CAS#s in product.
LD50/LC50:
No data
Carcinogenicity:

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Other
No information available.

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
US FEDERAL
TSCA

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 2/08/1999 Revision #2 Date: 3/18/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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ALL MSDS PAGES IN THIS GROUP
NAMECAS
6,7-Dimethoxy-1,2,3,4-tetrahydro-1-isoquinoline acetic acid 303094-23-7
6,7-Dimethoxy-1,2,3,4-tetrahydro-1- isoquinoline acetonitrile 0-00-0
6,7-Diethoxy-1,2,3,4-Tetrahydro-1- Isoquinoline Acetonitrile 0-00-0
6,7-Dimethoxy-3-methyl-1,2,3,4-tetrahydroi soquinoline hydrochloride 0-00-0
1-Isopropyl-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline 0-01-1
6,7-Dimethoxy-3-methyl-3,4-dihydroisoquino line hydrochloride 0-00-0
6,7-Dimethoxy-1,3-dimethyl-3,4-dihydroisoq uinoline hydrochloride, 0-00-0
6,7-Dimethoxy-1-Phenyl-1,2,3,4-Tetrahydroisoquinoline Hydrochloride 0-00-1
Cyclohexanone oxime, 97% 100-64-1
Methyl-(s)-3-(tert.-butoxycarbonyl)-2,2-di 108149-60-6
Phosphoric acid, 85% solution in water, c.p. 7664-38-2
4-Sulfonic calix[8]arene
2-Chloroethanesulfonic Acid, Sodium Salt Monohydrate, 98% 15484-44-3
2,5-Bis(diethoxyphosphoryl)thiophene 100651-98-7
1,2-bis(dimethoxyphosphoryl)benzene, 97% ( gc) 15104-46-8
4-Amino-6-mercaptopyrazolo[3,4-d]pyrimidine 23771-52-0
Tris(acetonitrile)molybdenumtricarbonyl 15038-48-9
Tris(acetonitrile)chromiumtricarbonyl 16800-46-7
Di[(Methylcyclopentadienyl)molybdenum Tricarbonyl] 33056-03-0
Dipentene, mixture of limonene, 56.0-64.0% , and terpinolene, 138-86-3
Trans 2, trans 4-nonadienal, 90% 5910-28-1
4-Methyl-2-Pentenal, 95% 5362-56-1
L-TERT.-LEUCINE, 99% 20859-02-3
1-Fluorohexane, 99+% (GC) 373-14-8
N-BUTYL METHYLSULFIDE 628-29-5
alpha-Tetralone, 85% 529-34-0
2,2,4-Trimethylpentane, c.p. 540-84-1
TRIS-(2-CYANOETHYL)PHOSPHINE 4023-53-4
3-Bromophenylacetonitrile, 98+% 31938-07-5
POTASSIUM FLUOROZIRCONATE 16923-95-8
3,5-Dibromo-4-Hydroxybenzaldehyde, 98% 2973-77-5
5'-Chloro-2'-hydroxyacetophenone, 99% 1450-74-4
10-UNDECYNOIC ACID 2777-65-3
Lithium tert-butoxide 1907-33-1
Lithium methoxide 865-34-9
2-Chloroethylphosphonic Acid, Tech., 90% 16672-87-0
2-Phenylimidazole ,98% 670-96-2
SOLVENT BLUE 36
Cyclopentadienylsodium, 0.4 M in tetrahydrofuran 4984-82-1
Selenium(IV) Chloride (-8 Mesh), 95% 10026-03-6
4-trans-Phenylcyclohexane-cis-dicarboxylic acid, 97% 36299-64-6
cis-2-Benzoyl-1-cyclohexanecarboxylic acid, 98% 6939-99-7
trans-2-Benzoyl-1-cyclohexanecarboxylic acid, 99% 3586-84-3
cis-2-(4-Methylbenzoyl)-1-cyclohexanecarboxylic acid, 99% 107147-13-7
trans-2-(4-Methylbenzoyl)-1-cyclohexanecarboxylic acid 151830-92-1
2-trans-Benzoyl-5-trans-phenyl-1-cyclohexanecarboxylic acid, 99% 35033-79-5
trans-2-(p-Chlorobenzoyl)-1-cyclohexanecarboxylic acid, 98% 52240-19-4
cis-2-(4-Fluorobenzoyl)-1-cyclohexane-carboxylic acid, 99% 154810-33-0
trans-2-(4-Fluorobenzoyl)-1-cyclohexane-carboxylic acid, 99% 111857-42-2
Cis-2-(4-Bromobenzoyl)-1-Cyclohexane-Carboxylic Acid

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