**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 865-34-9 |Lithium methoxide | | 212-737-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 14 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Reacts violently with water. Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water Reactive. Material will react with water and
may release a flammable and/or toxic gas. Material will burn in a
fire. Flammable liquid and vapor. Reacts violently with water.
Extinguishing Media:
Do NOT use carbon dioxide. DO NOT USE WATER OR FOAM. Smother with
dry sand, dry clay, dry ground limestone (CaCO3), or use approved
Class D extinguishers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Remove all sources of ignition. Use a spark-proof tool. Do
not expose spill to water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not allow water to get into the container because of violent
reaction. Use spark-proof tools and explosion proof equipment. Do
not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin,
or on clothing. Handle under an inert atmosphere. Do not allow
contact with water. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep away from water.
Flammables-area. Corrosives area. Store under nitrogen.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 865-34-9:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: Not available.
pH: >7
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: vigorous reaction
Specific Gravity/Density:
Molecular Formula: CH3LiO
Molecular Weight: 37.98
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
May ignite spontaneously in air by slightly elevating the
temperature or lowering the pressure. Reacts violently with water.
Moisture sensitive.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, exposure
to moist air or water.
Incompatibilities with Other Materials:
Oxidizing materials, water, acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, lithium oxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 865-34-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Lithium methoxide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE,
N.O.S.*
Hazard Class: 4.2 (8)
UN Number: 3206
Packing Group: II
IMO
Shipping Name: ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE,
N.O.S.
Hazard Class: 4.2 (8)
UN Number: 3206
Packing Group: II
RID/ADR
Shipping Name: ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE,
N.O.S.
Hazard Class: 4.2 (8)
UN Number: 3206
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 8 Keep container dry.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 43A In case of fire, use dry chemical (never use
water).
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 865-34-9: No information available.
Canada
CAS# 865-34-9 is listed on Canada's NDSL List.
CAS# 865-34-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 865-34-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/08/2004 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
6,7-Dimethoxy-1,2,3,4-tetrahydro-1-isoquinoline acetic acid
| 303094-23-7 |
|
6,7-Dimethoxy-1,2,3,4-tetrahydro-1- isoquinoline acetonitrile
| 0-00-0 |
|
6,7-Diethoxy-1,2,3,4-Tetrahydro-1- Isoquinoline Acetonitrile
| 0-00-0 |
|
6,7-Dimethoxy-3-methyl-1,2,3,4-tetrahydroi soquinoline hydrochloride
| 0-00-0 |
|
1-Isopropyl-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline
| 0-01-1 |
|
6,7-Dimethoxy-3-methyl-3,4-dihydroisoquino line hydrochloride
| 0-00-0 |
|
6,7-Dimethoxy-1,3-dimethyl-3,4-dihydroisoq uinoline hydrochloride,
| 0-00-0 |
|
6,7-Dimethoxy-1-Phenyl-1,2,3,4-Tetrahydroisoquinoline Hydrochloride
| 0-00-1 |
|
Cyclohexanone oxime, 97%
| 100-64-1 |
|
Methyl-(s)-3-(tert.-butoxycarbonyl)-2,2-di
| 108149-60-6 |
|
Phosphoric acid, 85% solution in water, c.p.
| 7664-38-2 |
|
4-Sulfonic calix[8]arene
| |
|
2-Chloroethanesulfonic Acid, Sodium Salt Monohydrate, 98%
| 15484-44-3 |
|
2,5-Bis(diethoxyphosphoryl)thiophene
| 100651-98-7 |
|
1,2-bis(dimethoxyphosphoryl)benzene, 97% ( gc)
| 15104-46-8 |
|
4-Amino-6-mercaptopyrazolo[3,4-d]pyrimidine
| 23771-52-0 |
|
Tris(acetonitrile)molybdenumtricarbonyl
| 15038-48-9 |
|
Tris(acetonitrile)chromiumtricarbonyl
| 16800-46-7 |
|
Di[(Methylcyclopentadienyl)molybdenum Tricarbonyl]
| 33056-03-0 |
|
Dipentene, mixture of limonene, 56.0-64.0% , and terpinolene,
| 138-86-3 |
|
Trans 2, trans 4-nonadienal, 90%
| 5910-28-1 |
|
4-Methyl-2-Pentenal, 95%
| 5362-56-1 |
|
L-TERT.-LEUCINE, 99%
| 20859-02-3 |
|
1-Fluorohexane, 99+% (GC)
| 373-14-8 |
|
N-BUTYL METHYLSULFIDE
| 628-29-5 |
|
alpha-Tetralone, 85%
| 529-34-0 |
|
2,2,4-Trimethylpentane, c.p.
| 540-84-1 |
|
TRIS-(2-CYANOETHYL)PHOSPHINE
| 4023-53-4 |
|
3-Bromophenylacetonitrile, 98+%
| 31938-07-5 |
|
POTASSIUM FLUOROZIRCONATE
| 16923-95-8 |
|
3,5-Dibromo-4-Hydroxybenzaldehyde, 98%
| 2973-77-5 |
|
5'-Chloro-2'-hydroxyacetophenone, 99%
| 1450-74-4 |
|
10-UNDECYNOIC ACID
| 2777-65-3 |
|
Lithium tert-butoxide
| 1907-33-1 |
|
Lithium methoxide
| 865-34-9 |
|
2-Chloroethylphosphonic Acid, Tech., 90%
| 16672-87-0 |
|
2-Phenylimidazole ,98%
| 670-96-2 |
|
SOLVENT BLUE 36
| |
|
Cyclopentadienylsodium, 0.4 M in tetrahydrofuran
| 4984-82-1 |
|
Selenium(IV) Chloride (-8 Mesh), 95%
| 10026-03-6 |
|
4-trans-Phenylcyclohexane-cis-dicarboxylic acid, 97%
| 36299-64-6 |
|
cis-2-Benzoyl-1-cyclohexanecarboxylic acid, 98%
| 6939-99-7 |
|
trans-2-Benzoyl-1-cyclohexanecarboxylic acid, 99%
| 3586-84-3 |
|
cis-2-(4-Methylbenzoyl)-1-cyclohexanecarboxylic acid, 99%
| 107147-13-7 |
|
trans-2-(4-Methylbenzoyl)-1-cyclohexanecarboxylic acid
| 151830-92-1 |
|
2-trans-Benzoyl-5-trans-phenyl-1-cyclohexanecarboxylic acid, 99%
| 35033-79-5 |
|
trans-2-(p-Chlorobenzoyl)-1-cyclohexanecarboxylic acid, 98%
| 52240-19-4 |
|
cis-2-(4-Fluorobenzoyl)-1-cyclohexane-carboxylic acid, 99%
| 154810-33-0 |
|
trans-2-(4-Fluorobenzoyl)-1-cyclohexane-carboxylic acid, 99%
| 111857-42-2 |
|
Cis-2-(4-Bromobenzoyl)-1-Cyclohexane-Carboxylic Acid
| |
|
|