**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 141-52-6 |Sodium Ethoxide | 94-97% | 205-487-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 14 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Reacts violently with water. Causes
burns.Corrosive.Water-reactive.Air sensitive.
Potential Health Effects
Eye:
Causes eye burns. May cause blindness. Causes redness and pain.
Skin:
Causes skin burns. Causes redness and pain.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal irritation with nausea, vomiting and diarrhea.
Causes gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Inhalation may be fatal as
a result of spasm, inflammation, edema of the larynx and bronchi,
chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Do NOT induce
vomiting and seek IMMEDIATE MEDICAL ADVICE.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Water Reactive. Material will react with water and may release a
flammable and/or toxic gas. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable solid. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
Use dry sand or earth to smother fire. Use water spray to cool
fire-exposed containers. DO NOT USE WATER! Use dry chemical. Do NOT
use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Use a spark-proof tool. Provide
ventilation. A vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Do not breathe dust,
vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep container tightly closed. Keep away from heat,
sparks and flame. Do not get on skin or in eyes. Use with adequate
ventilation. Do not allow contact with water. Discard contaminated
shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Do not store in direct
sunlight. Store in a tightly closed container. Keep under a nitrogen
blanket. Store in a cool, dry, well-ventilated area away from
incompatible substances. Water free area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 141-52-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear neoprene gloves, apron, and/or clothing.
Clothing:
Wear neoprene gloves, apron, and/or clothing.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. A NIOSH/MSHA
approved air purifying dust or mist respirator or
European Standard EN 149.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow-white
Odor: Not available.
pH: Not available.
Vapor Pressure: < 0.1 mm Hg @ 2
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 260 deg C
Autoignition Temperature: 50 deg C ( 122.00 deg F)
Flash Point: 30 deg C ( 86.00 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: >260 deg C
Solubility in water: reacts
Specific Gravity/Density:
Molecular Formula: C2H5ONa
Molecular Weight: 68.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, light, ignition sources, exposure to air,
excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, sodium oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 141-52-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Sodium Ethoxide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE,
N.O.S.*
Hazard Class: 4.2 (8)
UN Number: 3206
Packing Group: II
IMO
Shipping Name: ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE,
N.O.S.
Hazard Class: 4.2 (8)
UN Number: 3206
Packing Group: II
RID/ADR
Shipping Name: ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE,
N.O.S.
Hazard Class: 4.2
UN Number: 3206
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 8 Keep container dry.
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 43A In case of fire, use dry chemical (never use
water).
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 141-52-6: 1
Canada
CAS# 141-52-6 is listed on Canada's DSL List.
CAS# 141-52-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 141-52-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/12/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Chloro-4'-Fluoropropiophenone, 98%
| 347-93-3 |
|
4-Ethylaniline, 99+%
| 589-16-2 |
|
1,6-Hexanediol
| 629-11-8 |
|
6-Amino-M-Toluenesulfonic Acid, 99%
| 88-44-8 |
|
Methyl 3-mercaptopropionate, 98%
| 2935-90-2 |
|
1,4-Dihydroxyanthraquinone, 96%
| 81-64-1 |
|
Methyl 2-(chlorosulfonyl)benzoate, tech., 90%
| 26638-43-7 |
|
9,10-Dihydrobenzo(a)Pyren-7(8H)-One, 97%
| 3331-46-2 |
|
1,2,5-Trimethylpyrrole,99%
| 930-87-0 |
|
4-Acetamidothiophenol, 95%
| 1126-79-0 |
|
Praseodymium atomic absorption standard solution, 1 mg/ml Pr in 2%
| 7440-10-0 |
|
(R)-(-)-N-(3,5-Dinitrobenzoyl)-Alpha-Phenylglycine, 99%
| 74927-72-3 |
|
Phenyl Beta-D-Glucopyranoside, 98%
| 1464-44-4 |
|
DL-3,4-Dihydroxymandelic Acid, 98%
| 14883-87-5 |
|
N,N'-bis(2-aminoethyl)-1,3-propanediamine, 97% (titr.)
| 4741-99-5 |
|
L-2-Fluorophenylalanine hemihydrate, 99.5% (e.e.)
| |
|
Butyl Levulinate, 98%
| 2052-15-5 |
|
DL-3-Methylenecyclopropane-Trans-1,2-Dicarboxylic Acid, 98% (Titr.)
| 499-02-5 |
|
1,1-Diphenylacetone, 99+%
| 781-35-1 |
|
4-Pyridylcarbinol, 99%
| 586-95-8 |
|
N,N-Dimethyldodecylamine (Pract)
| 112-18-5 |
|
(r)-(+)-Bis-(1,2-Diphenylphosphino)Propane Tech., 93% (TLC)
| 67884-32-6 |
|
4-Methoxy-2(5H)-Furanone, 97%
| 69556-70-3 |
|
Fullerene c60, 99.9% (hplc)
| 99685-96-8 |
|
Butyl methacrylate, 99%, Stabilized with 25ppm Methylhydroquinone
| 97-88-1 |
|
1H-Tetrazole, 99+%
| 288-94-8 |
|
5-Bromoindoxyl Diacetate, 99%
| 33588-54-4 |
|
N,n,n',n'-tetramethylbenzidine,97.5%
| 366-29-0 |
|
Perfluorooctyl iodide, 99%
| 507-63-1 |
|
9-Fluorenemethanol,99%
| 24324-17-2 |
|
3,3-Dimethylpentane, 99%
| 562-49-2 |
|
Dipropyl Phthalate, 99+% (gc)
| 131-16-8 |
|
Sodium Ethoxide, 96+%
| 141-52-6 |
|
Fluoxymesterone, 97.0-102.0% hplc (on dry substance)
| 76-43-7 |
|
L-(-)-Carvone, 99+% (GC)
| 6485-40-1 |
|
2-(3-Bromophenyl)-1,3-dioxolane, 95%
| 17789-14-9 |
|
2-Oxooctanenitrile, tech.
| 80997-84-8 |
|
4-Hydroxypiperidine, 97%, contains varying amounts of moisture
| 5382-16-1 |
|
2-Ethyl-1-hexanol
| 104-76-7 |
|
N-(2,6-Diethylphenylcarbamoyl-Methyl)-Iminodiacetic Acid, 99%
| 0-00-1 |
|
4-Methoxy-7-Methyl-5H-Furo(3,2-g)(1)-Benzopyran-5-One, 97% (Visnagin)
| 82-57-5 |
|
N-Benzyloxycarbonyl-L-Glutamic Acid 99%
| 1155-62-0 |
|
p-Phenylenediacetonitrile, 97%
| 622-75-3 |
|
3-(Trimethoxysilyl)propyl methacrylate, 98%
| 67-56-1 |
|
Ethyl Heptafluorobutyrate, 97%
| 356-27-4 |
|
Trifluoroacetic Acid, Sodium Salt, 97%
| 2923-18-4 |
|
2,2-Dimethyl-4-methoxycarbonyl-2H-imidazole-1-oxide, 99%
| 0-00-1 |
|
Ethyl p-toluenesulfonate (pract), 85% (GC)
| 80-22-8 |
|
3,4-Difluorophenylacetonitrile, 97+% (GC)
| 658-99-1 |
|
Di-n-octyl phthalate, 95% (gc)
| 117-84-0 |
|
|