**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-56-1 |Methyl alcohol | 1 | 200-659-6 |
|----------------|--------------------------------------|----------|-----------|
| 2530-85-0 |3-(Trimethoxysilyl)propyl methacrylate| 98 | 219-785-8 |
| | | | |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. Inhalation, ingestion or skin absorption of
methanol can cause significant disturbances in vision, including
blindness.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause blindness.
Inhalation:
Causes respiratory tract irritation. High vapor concentrations may
cause drowsiness.
Chronic:
Methanol is only very slowly eliminated from the body. Because of
this slow elimination, methanol should be regarded as a cumulative
poison. Though a single exposure may cause no effect, daily exposures
may result in the accumulation of a harmful amount.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat same as methyl alcohol poisoning.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid and
vapor.
Extinguishing Media:
Do NOT get water inside containers. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Do not allow contact with water. Keep from contact with moist
air and steam. Keep away from heat and flame. Do not breathe vapor or
mist. Pure vapor will be uninhibited and may polymerize in vents or
other confined spaces. Do not take internally. Product evolves
flammable methyl alcohol when exposed to water or humid air.
Storage:
Keep away from sources of ignition. Keep container closed when not
in use. Store in a cool, dry, well-ventilated area away from
incompatible substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 67-56-1:
United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA
United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL
United States OSHA: 200 ppm TWA; 260 mg/m3 TWA
Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE
Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE
France - VME: 200 ppm VME; 260 mg/m3 VME
France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE
Germany: 200 ppm TWA; 270 mg/m3 TWA
Germany: Skin absorber
Japan: 200 ppm OEL; 260 mg/m3 OEL
Malaysia: 200 ppm TWA; 262 mg/m3 TWA
Netherlands: 200 ppm MAC; 260 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED
Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC
CAS# 2530-85-0:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 10 mm Hg @ 130 deg C
Viscosity: 2.5 cSt 25.00 deg C
Boiling Point: 190 deg C @ 760 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: 265 deg C ( 509.00 deg F)
Flash Point: 92 deg C ( 197.60 deg F)
Explosion Limits, lower: 0.80 vol %
Explosion Limits, upper: 16.3 vol %
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.040 g/cm3
Molecular Formula: C10H20O5Si
Molecular Weight: 248.35
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Water, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, silicon dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-56-1: PC1400000
CAS# 2530-85-0: UC0230000
LD50/LC50:
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test,
rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20
mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H;
Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300
mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600
mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 2530-85-0: Draize test, rabbit, eye: 500 mg/24H Mild; Draize
test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 22600 uL/kg.
Dow Corning says methacryloxypropyl trimethoxysilane is a possible
skin sensitizer.
Carcinogenicity:
Methyl alcohol -
Not listed by ACGIH, IARC, or NTP.
3-(Trimethoxysilyl)propyl methacrylate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 67-56-1: 1
CAS# 2530-85-0: 1
Canada
CAS# 67-56-1 is listed on Canada's DSL List.
CAS# 2530-85-0 is listed on Canada's DSL List.
CAS# 67-56-1 is listed on Canada's Ingredient Disclosure List.
CAS# 2530-85-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 2530-85-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin and
if swallowed.
R 39/23/24/25 Toxic : danger of very serious irreversible
effects through inhalation, in contact with skin and if swallowed.
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/17/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Chloro-4'-Fluoropropiophenone, 98%
| 347-93-3 |
|
4-Ethylaniline, 99+%
| 589-16-2 |
|
1,6-Hexanediol
| 629-11-8 |
|
6-Amino-M-Toluenesulfonic Acid, 99%
| 88-44-8 |
|
Methyl 3-mercaptopropionate, 98%
| 2935-90-2 |
|
1,4-Dihydroxyanthraquinone, 96%
| 81-64-1 |
|
Methyl 2-(chlorosulfonyl)benzoate, tech., 90%
| 26638-43-7 |
|
9,10-Dihydrobenzo(a)Pyren-7(8H)-One, 97%
| 3331-46-2 |
|
1,2,5-Trimethylpyrrole,99%
| 930-87-0 |
|
4-Acetamidothiophenol, 95%
| 1126-79-0 |
|
Praseodymium atomic absorption standard solution, 1 mg/ml Pr in 2%
| 7440-10-0 |
|
(R)-(-)-N-(3,5-Dinitrobenzoyl)-Alpha-Phenylglycine, 99%
| 74927-72-3 |
|
Phenyl Beta-D-Glucopyranoside, 98%
| 1464-44-4 |
|
DL-3,4-Dihydroxymandelic Acid, 98%
| 14883-87-5 |
|
N,N'-bis(2-aminoethyl)-1,3-propanediamine, 97% (titr.)
| 4741-99-5 |
|
L-2-Fluorophenylalanine hemihydrate, 99.5% (e.e.)
| |
|
Butyl Levulinate, 98%
| 2052-15-5 |
|
DL-3-Methylenecyclopropane-Trans-1,2-Dicarboxylic Acid, 98% (Titr.)
| 499-02-5 |
|
1,1-Diphenylacetone, 99+%
| 781-35-1 |
|
4-Pyridylcarbinol, 99%
| 586-95-8 |
|
N,N-Dimethyldodecylamine (Pract)
| 112-18-5 |
|
(r)-(+)-Bis-(1,2-Diphenylphosphino)Propane Tech., 93% (TLC)
| 67884-32-6 |
|
4-Methoxy-2(5H)-Furanone, 97%
| 69556-70-3 |
|
Fullerene c60, 99.9% (hplc)
| 99685-96-8 |
|
Butyl methacrylate, 99%, Stabilized with 25ppm Methylhydroquinone
| 97-88-1 |
|
1H-Tetrazole, 99+%
| 288-94-8 |
|
5-Bromoindoxyl Diacetate, 99%
| 33588-54-4 |
|
N,n,n',n'-tetramethylbenzidine,97.5%
| 366-29-0 |
|
Perfluorooctyl iodide, 99%
| 507-63-1 |
|
9-Fluorenemethanol,99%
| 24324-17-2 |
|
3,3-Dimethylpentane, 99%
| 562-49-2 |
|
Dipropyl Phthalate, 99+% (gc)
| 131-16-8 |
|
Sodium Ethoxide, 96+%
| 141-52-6 |
|
Fluoxymesterone, 97.0-102.0% hplc (on dry substance)
| 76-43-7 |
|
L-(-)-Carvone, 99+% (GC)
| 6485-40-1 |
|
2-(3-Bromophenyl)-1,3-dioxolane, 95%
| 17789-14-9 |
|
2-Oxooctanenitrile, tech.
| 80997-84-8 |
|
4-Hydroxypiperidine, 97%, contains varying amounts of moisture
| 5382-16-1 |
|
2-Ethyl-1-hexanol
| 104-76-7 |
|
N-(2,6-Diethylphenylcarbamoyl-Methyl)-Iminodiacetic Acid, 99%
| 0-00-1 |
|
4-Methoxy-7-Methyl-5H-Furo(3,2-g)(1)-Benzopyran-5-One, 97% (Visnagin)
| 82-57-5 |
|
N-Benzyloxycarbonyl-L-Glutamic Acid 99%
| 1155-62-0 |
|
p-Phenylenediacetonitrile, 97%
| 622-75-3 |
|
3-(Trimethoxysilyl)propyl methacrylate, 98%
| 67-56-1 |
|
Ethyl Heptafluorobutyrate, 97%
| 356-27-4 |
|
Trifluoroacetic Acid, Sodium Salt, 97%
| 2923-18-4 |
|
2,2-Dimethyl-4-methoxycarbonyl-2H-imidazole-1-oxide, 99%
| 0-00-1 |
|
Ethyl p-toluenesulfonate (pract), 85% (GC)
| 80-22-8 |
|
3,4-Difluorophenylacetonitrile, 97+% (GC)
| 658-99-1 |
|
Di-n-octyl phthalate, 95% (gc)
| 117-84-0 |
|
|