**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 147460-41-1 |2-Bromo-5-Fluorophenol | 99 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause irritation and dermatitis. May
cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Can produce delayed
pulmonary edema. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. May polymerize explosively when
involved in a fire. Contact with metals may evolve flammable hydrogen
gas. Containers may explode when heated.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Absorb spill using
an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust. Use a
spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Wash clothing before reuse. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 147460-41-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: phenol-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 87 deg C ( 188.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.717
Molecular Formula: C6H4BrFO
Molecular Weight: 191.00
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen fluoride gas, hydrogen bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 147460-41-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Bromo-5-Fluorophenol -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 147460-41-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 147460-41-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 147460-41-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tin (II) Bromide
| 10031-24-0 |
|
Erbium(III) nitrate pentahydrate, 99.9%
| 10031-51-3 |
|
Aurintricarboxylic Acid
| 4431-00-9 |
|
Terbium(III) carbonate hydrate, 99.9%
| 100587-96-0 |
|
Cerium (IV) Fluoride, 99%
| 10060-10-3 |
|
Diammonium Tetrachlorocuprate(II) Dihydrate, 98%
| 10060-13-6 |
|
Lanthanum Chloride, 99.9%
| 10099-58-8 |
|
Dysprosium(III) Sulfate Octahydrate, 99.99+%
| 10031-50-2 |
|
Vincristine sulfate, 95% (hplc)
| 2068-78-2 |
|
Lead(II)Nitrate, 99.999%
| 10099-74-8 |
|
Strontium Nitrate, Reagent ACS, 99+%
| 10042-76-9 |
|
Boric Acid, 99.99%
| 10043-35-3 |
|
Chromium (II) Chloride, 99.9%
| 10049-05-5 |
|
Calcium sulfate dihydrate, reagent ACS
| 7778-18-9 |
|
Cadmium chloride, reagent ACS, 99+%
| 10108-64-2 |
|
Copper (II) Chloride Dihydrate, Reagent ACS, 99+%
| 10125-13-0 |
|
Bismuth(III) Nitrate Pentahydrate, 99.999%
| 10035-06-0 |
|
Barium Carbonate, 99.999%
| 513-77-9 |
|
Ethoxymethylenemalononitrile, 98%
| 123-06-8 |
|
Erbium(III) Chloride, 99.9%
| 10138-41-7 |
|
Holmium(III) chloride, 99.9%
| 10138-62-2 |
|
Diphenyl(p-tolyl)phosphine, 96%
| 1031-93-2 |
|
Samarium(III) chloride, -20 mesh, 97%
| 10361-82-7 |
|
Scandium trichloride, anhydrous, 99.99%
| 10361-84-9 |
|
Barium bromide, anhydrous, 99.999%
| 10553-31-8 |
|
Sodium acetylide, 18 wt% slurry in xylene/light mineral oil, 95%
| 1066-26-8 |
|
(2-Naphthoxy)-acetic acid, 98%
| 120-23-0 |
|
Europium(III) Acetate Hydrate, 99.9%
| 62667-64-5 |
|
Niobium (IV) Oxide, -200 Mesh, 99+%
| 12034-59-2 |
|
Rhenium(IV)oxide dihydrate, 99.9%
| 12036-09-8 |
|
Titanium boride, powder, ca. 10 micron
| 12045-63-5 |
|
Scandium (III) Oxide, 99.9%
| 12060-08-1 |
|
Lutetium oxide, 99.9%
| 12032-20-1 |
|
2-Bromo-5-Fluorophenol, 99%
| 147460-41-1 |
|
Terbium(III,IV) oxide, 99.9%
| 12037-01-3 |
|
3-(1,1,2,2-Tetrafluoroethoxy)aniline, 97%
| 831-75-4 |
|
3-(1,1,2,2-Tetrafluoroethoxy)benzaldehyde, 95%
| 35295-35-3 |
|
Tetrafluoroisophthalic acid, 98%
| 1551-39-9 |
|
Tetrafluoroisophthalonitrile, 98%
| 2377-81-3 |
|
2,3,4,5-Tetrafluoronitrobenzene, 99%
| 5580-79-0 |
|
2,6,10-Trimethyl-5,9-undecadien-1-ol, 98% mixture of isomers
| 24048-14-4 |
|
Tetrafluorophthalonitrile, 95%
| 1835-65-0 |
|
2,2,3,3-Tetrafluoropropyl methacrylate, 99%
| 45102-52-1 |
|
1-(4-Chlorophenyl)-2-Methylpiperazine
| 55117-80-1 |
|
Tetrafluoroterephthalic Acid, 97%
| 652-36-8 |
|
2,3,5,6-Tetrafluorotoluene, 98%
| 5230-78-4 |
|
Triethylsilyl trifluoromethanesulfonate, 99%
| 79271-56-0 |
|
2,3,6-Trifluorobenzoic acid, 99%
| 2358-29-4 |
|
2,4,6-Trifluorobenzoic Acid, 98%
| 28314-80-9 |
|
Trans-1,2-Dibenzoylethylene, 97%
| 959-28-4 |
|
|