**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1499-21-4 |Diphenylphosphinyl Chloride | 98 | 216-107-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 10 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Causes burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
May cause severe irritation and possible burns.
Ingestion:
Causes gastrointestinal tract burns. May cause severe
gastrointestinal tract irritation with nausea, vomiting and possible
burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Vapors may cause dizziness
or suffocation.
Chronic:
None
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Will burn if involved in a fire.
Use water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Do NOT use water directly on fire. Use water
spray to cool fire-exposed containers. Water may be ineffective. Do
NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep container tightly closed. Keep away from heat, sparks and
flame. Do not get on skin or in eyes. Do not ingest or inhale. Use
with adequate ventilation. Discard contaminated shoes. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1499-21-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 222 deg C @ 16.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 26 deg C ( 78.80 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density: 1.2400g/cm3
Molecular Formula: C12H10ClOP
Molecular Weight: 236.64
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, phosphine, carbon monoxide, oxides of phosphorus,
carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1499-21-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Diphenylphosphinyl Chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.*
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8
UN Number: 2920
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 34 Causes burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 1499-21-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1499-21-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1499-21-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/16/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
L-Carnosine, 98%
| 305-84-0 |
|
Ethylbenzene-d10, 98+ atom % d
| 25837-05-2 |
|
Molybdenyl acetylacetonate, 99%
| 17524-05-9 |
|
3,7-Dimethyl-7-Hydroxyoctanal, 98%
| 107-75-5 |
|
D-L-5-Fluorotryptophan, 99+%
| 154-08-5 |
|
6-Chloronicotinic Acid, 99%
| 5326-23-8 |
|
Methyl 3,3-Dimethoxypropionate, 99%
| 7424-54-6 |
|
1-Acetamidoadamantane, 99+%
| 880-52-4 |
|
2-Nitroimidazole, 98%
| 527-73-1 |
|
Tetraphenylmethane, 97%
| 630-76-2 |
|
8-Nitroquinoline, 98%
| 607-35-2 |
|
3-Octylthiophene, 94%, remainder mainly tetradecane
| 65016-62-8 |
|
4-Nitrobenzophenone, 99+%
| 1144-74-7 |
|
9-Chloroacridine
| 1207-69-8 |
|
4-Epichlortetracycline hydrochloride 'can be used as secondary
| 101342-45-4 |
|
Sarcosine Hydrochloride, 99%
| 637-96-7 |
|
5-alpha-Cholestan-3-one, 97%
| 15600-08-5 |
|
n-Glycyl-l-isoleucine, 99%
| 19462-38-2 |
|
2,4-Dinitrophenylacetic Acid, Tech., 90%(GC)
| 643-43-6 |
|
2-Chloroethanesulfonyl Chloride, 95% (gc)
| 1622-32-8 |
|
Heptyl Isothiocyanate
| 4426-83-9 |
|
Alpha-Bromo-Meta-Tolunitrile, 95%
| 28188-41-2 |
|
Phenylpropiolic acid, 97%
| 637-44-5 |
|
2,3,5-Trimethylphenol, 98+%
| 697-82-5 |
|
2,4-Dinitrophenyl Acetate
| 4232-27-3 |
|
(1r,2r)-(+)-n,n'-dimethyl-1,2-diphenyl-1,2 -ethane diamine, 99%
| 118628-68-5 |
|
Isobutyric anhydride, 97%
| 97-72-3 |
|
Diethyl Ketomalonate, 95% (GC)
| 609-09-6 |
|
3-Aminopyrazine-2-Carboxylic Acid, 99+%
| 5424-01-1 |
|
2,3' -diethyl-9-methylthiacarbocyanine iodide
| 3065-79-0 |
|
6-Chloro-2-Pyridinol, 98%
| 16879-02-0 |
|
9-Aminofluorene hydrochloride, 99%
| 5978-75-6 |
|
1-Methoxy-3-(Trimethylsilyloxy)-1,3-Butadiene, 90%
| 59414-23-2 |
|
Aminoacetonitrile Hydrochloride, 99%
| 6011-14-9 |
|
Diphenylphosphinyl Chloride, 98%
| 1499-21-4 |
|
2-(2-Tritylaminothiazole-4-Yl)-2-Methoxyiminoacetic Acid
| 64485-90-1 |
|
Antimony (III) Sulfide, 98%
| 1345-04-6 |
|
Magnesiumhydrogenphosphate trihydrate, c.p
| 7782-75-4 |
|
1-Hydroxyethylethoxypiperazine, 95%
| 13349-82-1 |
|
4'-Chloroacetoacetanilide, 98%
| 101-92-8 |
|
Cycloheximide
| 66-81-9 |
|
??2,4??-Dibenzo-18-Crown-6, 99+%
| 14187-32-7 |
|
Cyanuric Chloride, 99% (Titr.)
| 108-77-0 |
|
Alpha-Toluenesulfonamide
| 4563-33-1 |
|
Ethyl 2-Mercaptoacetate, 99% (GC)
| 623-51-8 |
|
N-Carbethoxy-4-Tropinone, 98%
| 32499-64-2 |
|
2,3-Dimethylquinoxaline, 97%
| 2379-55-7 |
|
Potassium perchlorate
| 7778-74-7 |
|
Benzylamine
| 100-46-9 |
|
N-Omega-Acetylhistamine, 98%
| 673-49-4 |
|
|