**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 16871-60-6 |Potassium hexachloroosmate(IV) | ca. 100 | 240-893-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Hygroscopic (absorbs moisture from the air).Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Inhalation may be fatal as
a result of spasm, inflammation, edema of the larynx and bronchi,
chemical pneumonitis and pulmonary edema. May cause systemic
effects. May cause burning sensation, coughing, wheezing, laryngitis,
shortness of breath, headache, nausea, and vomiting.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid
generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Do not breathe dust, vapor, mist, or
gas. Do not get in eyes, on skin, or on clothing. Do not ingest or
inhale. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Corrosives area. Store
protected from moisture. Store in a cool, dry area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 16871-60-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: purple
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 600 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 600 deg C
Solubility in water: soluble
Specific Gravity/Density: 3.4200g/cm3
Molecular Formula: Cl6K2Os
Molecular Weight: 481.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Hygroscopic: absorbs
moisture or water from the air.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to moist air or
water.
Incompatibilities with Other Materials:
Moisture, water, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases, oxides of
potassium.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 16871-60-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Potassium hexachloroosmate(IV) -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 16871-60-6: 2
Canada
CAS# 16871-60-6 is listed on Canada's NDSL List.
CAS# 16871-60-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16871-60-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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| ALL MSDS PAGES IN THIS GROUP
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l-Methionine Methylsulfonium Bromide, 99+% e.e.
| |
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Dl-methionine methylsulfonium bromide 99% (titr.)
| |
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Ethyl Glycidyl Ether
| 4016-11-9 |
|
ETHANETHIOL, 97%
| 75-08-1 |
|
Ethanethiol (techn) (15% in 2,2-dichloro- 1,1,1-trifluoroethane)
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|
Potassium Chlorate, 99%
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1,3-Dioxolane, P.A. Stabilized With BHT
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|
1,3-Dioxolane, P.A. Stabilized With 70ppm Triethylamine
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|
L-Alpha-Hydroxyisocaproic Acid, 99%
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(1,2-Dibromoethyl)benzene, 97%
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Potassium Chlorate, Reagent ACS Crystals
| 3811-04-9 |
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1,2-Bis(tert-butylthio)ethane : diborane complex
| |
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O-Benzotriazol-1-yl-Tetramethyluronium Hexafluorophosphate, 99%
| 94790-37-1 |
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Yttrium(III)-Chloride Hexahydrate, 99.999%
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|
Germanium, Powder, 99.999%
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|
Dichloro Bis(Triphenylphosphine)Palladium (II)
| 13965-03-2 |
|
1-Iodooctane, 98%, stabilized over copper
| 629-27-6 |
|
Citric Acid, Monohydrate, P.A.
| 5949-29-1 |
|
Dibenzofuran, 98%
| 132-64-9 |
|
4-Methoxy-3-nitrobenzoic acid, 98%
| 89-41-8 |
|
Calix[4]-bis-2,3-naptho-crown-6
| |
|
trans-2-Hexen-1-ol, 96+%
| 928-95-0 |
|
Acetyl Methyl Carbinol, 85 Wt% Solution in Water
| 513-86-0 |
|
cis-6-Nonenal, 90%
| 2277-19-2 |
|
p-Ethylcalix[7]arene
| 0-00-0 |
|
p-tert. Butylcalix(5)arene-crown-5-complex
| |
|
P-tert.-butyl-calix[5]arene
| 81475-22-1 |
|
Selenourea, 99.9+%
| 630-10-4 |
|
Resorcinol sulfoxide, tech.
| 26948-96-9 |
|
N-BOC-3-(4-Cyanophenyl)oxaziridine
| 150884-56-3 |
|
1,3,5-tris(1,2,3-thiadiazol-4-yl)benzene 95+% (nmr)
| |
|
2-(Trimethylsilyl)thiazole, 96%
| 79265-30-8 |
|
3-(Trifluoromethoxy)benzoic acid, 99+% (titr.)
| 1014-81-9 |
|
2-(Trifluoromethoxy)aniline
| 1535-75-7 |
|
2-Pyrone-3-Carboxylic Acid-(2,2-Dimethyl-4
| 0-00-0 |
|
Nigrosine (pract)
| 80316-29-6 |
|
Nigrosin (cert)
| 80316-29-6 |
|
Samarium(II) iodide 0.1M solution in THF stabilized with samarium
| 109-99-9 |
|
Potassium hexachloroosmate(IV), min 39% Os
| 16871-60-6 |
|
2,4,6-Collidine, 99%
| 108-75-8 |
|
Ethyl 2-thiophenecarboxylate, 99+%
| 2810-04-0 |
|
2,4,6-Collidine, electron microscopy grade, 99%
| 108-75-8 |
|
Ethylenediaminetetraacetic Acid Dipotassium Salt, Dihydrate, 93%
| 2001-94-7 |
|
Ethylenediaminetetraacetic Acid, Dipotassium Salt Dihydrate, 99%
| 2001-94-7 |
|
Fluorescein disodium salt dihydrate, 90%
| 518-47-8 |
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Potassium methoxide, 0.1n solution in tolu ene/methanol
| 865-33-8 |
|
1-Chloroanthraquinone, 98%
| 82-44-0 |
|
Citric Acid, Anhydrous, P.A.
| 77-92-9 |
|
Acetone, 99+%, Spectrophotometric Grade
| 67-64-1 |
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Citric Acid, Anhydrous, Reagent ACS, 99.5% (Titr.)
| 77-92-9 |
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