**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2277-19-2 |Cis-6-nonenal | 90.0 | 218-900-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire. Combustible
liquid. Can form explosive mixtures at temperatures above the
flashpoint. Use water spray to keep fire-exposed containers cool.
Vapors may be heavier than air. They can spread along the ground
and collect in low or confined areas. Containers may explode when
heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes,
skin, and clothing. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Keep container tightly closed.
Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Use only in a chemical fume hood. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Keep under a nitrogen
blanket. Store in a cool, dry, well-ventilated area away from
incompatible substances. Keep refrigerated. (Store below 4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2277-19-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 87 deg C @ 19.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 75 deg C ( 167.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: .8410g/cm3
Molecular Formula: C9H16O
Molecular Weight: 140.23
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2277-19-2: RA8509200
LD50/LC50:
CAS# 2277-19-2: Dermal, guinea pig: LD50 = >5 gm/kg; Oral, mouse:
LD50 = >5 gm/kg.
Carcinogenicity:
Cis-6-nonenal -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 2277-19-2: No information available.
Canada
CAS# 2277-19-2 is listed on Canada's DSL List.
CAS# 2277-19-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2277-19-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/19/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
l-Methionine Methylsulfonium Bromide, 99+% e.e.
| |
|
Dl-methionine methylsulfonium bromide 99% (titr.)
| |
|
Ethyl Glycidyl Ether
| 4016-11-9 |
|
ETHANETHIOL, 97%
| 75-08-1 |
|
Ethanethiol (techn) (15% in 2,2-dichloro- 1,1,1-trifluoroethane)
| 0-00-0 |
|
Potassium Chlorate, 99%
| 3811-04-9 |
|
1,3-Dioxolane, P.A. Stabilized With BHT
| 646-06-0 |
|
1,3-Dioxolane, P.A. Stabilized With 70ppm Triethylamine
| 646-06-0 |
|
L-Alpha-Hydroxyisocaproic Acid, 99%
| 13748-90-8 |
|
(1,2-Dibromoethyl)benzene, 97%
| 93-52-7 |
|
Potassium Chlorate, Reagent ACS Crystals
| 3811-04-9 |
|
1,2-Bis(tert-butylthio)ethane : diborane complex
| |
|
O-Benzotriazol-1-yl-Tetramethyluronium Hexafluorophosphate, 99%
| 94790-37-1 |
|
Yttrium(III)-Chloride Hexahydrate, 99.999%
| 10361-92-9 |
|
Germanium, Powder, 99.999%
| 7440-56-4 |
|
Dichloro Bis(Triphenylphosphine)Palladium (II)
| 13965-03-2 |
|
1-Iodooctane, 98%, stabilized over copper
| 629-27-6 |
|
Citric Acid, Monohydrate, P.A.
| 5949-29-1 |
|
Dibenzofuran, 98%
| 132-64-9 |
|
4-Methoxy-3-nitrobenzoic acid, 98%
| 89-41-8 |
|
Calix[4]-bis-2,3-naptho-crown-6
| |
|
trans-2-Hexen-1-ol, 96+%
| 928-95-0 |
|
Acetyl Methyl Carbinol, 85 Wt% Solution in Water
| 513-86-0 |
|
cis-6-Nonenal, 90%
| 2277-19-2 |
|
p-Ethylcalix[7]arene
| 0-00-0 |
|
p-tert. Butylcalix(5)arene-crown-5-complex
| |
|
P-tert.-butyl-calix[5]arene
| 81475-22-1 |
|
Selenourea, 99.9+%
| 630-10-4 |
|
Resorcinol sulfoxide, tech.
| 26948-96-9 |
|
N-BOC-3-(4-Cyanophenyl)oxaziridine
| 150884-56-3 |
|
1,3,5-tris(1,2,3-thiadiazol-4-yl)benzene 95+% (nmr)
| |
|
2-(Trimethylsilyl)thiazole, 96%
| 79265-30-8 |
|
3-(Trifluoromethoxy)benzoic acid, 99+% (titr.)
| 1014-81-9 |
|
2-(Trifluoromethoxy)aniline
| 1535-75-7 |
|
2-Pyrone-3-Carboxylic Acid-(2,2-Dimethyl-4
| 0-00-0 |
|
Nigrosine (pract)
| 80316-29-6 |
|
Nigrosin (cert)
| 80316-29-6 |
|
Samarium(II) iodide 0.1M solution in THF stabilized with samarium
| 109-99-9 |
|
Potassium hexachloroosmate(IV), min 39% Os
| 16871-60-6 |
|
2,4,6-Collidine, 99%
| 108-75-8 |
|
Ethyl 2-thiophenecarboxylate, 99+%
| 2810-04-0 |
|
2,4,6-Collidine, electron microscopy grade, 99%
| 108-75-8 |
|
Ethylenediaminetetraacetic Acid Dipotassium Salt, Dihydrate, 93%
| 2001-94-7 |
|
Ethylenediaminetetraacetic Acid, Dipotassium Salt Dihydrate, 99%
| 2001-94-7 |
|
Fluorescein disodium salt dihydrate, 90%
| 518-47-8 |
|
Potassium methoxide, 0.1n solution in tolu ene/methanol
| 865-33-8 |
|
1-Chloroanthraquinone, 98%
| 82-44-0 |
|
Citric Acid, Anhydrous, P.A.
| 77-92-9 |
|
Acetone, 99+%, Spectrophotometric Grade
| 67-64-1 |
|
Citric Acid, Anhydrous, Reagent ACS, 99.5% (Titr.)
| 77-92-9 |
|
|