**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 17567-17-8 |Potassium tris(3,5-dimethyl-1-pyrazoly| 99 | unlisted |
| |l)borohydride | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 15 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with water liberates extremely flammable gases. Irritating
to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Reacts with water to form explosive hydrogen gas.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Remove all sources of
ignition. Provide ventilation. Do not expose spill to water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes,
skin, and clothing. Store absolutely dry. Use only with adequate
ventilation. Inform laundry personnel of contaminant's hazards.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Water free area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Exposure Limits
CAS# 17567-17-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Needles
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 287 deg C (dec)
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 287 deg C
Solubility in water: Reacts.
Specific Gravity/Density:
Molecular Formula: C15H22BKN6
Molecular Weight: 336.28
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Water contact produces hydrogen gas.
Conditions to Avoid:
Exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, oxides of boron,
dipotassium oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 17567-17-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Potassium tris(3,5-dimethyl-1-pyrazolyl)borohydride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 15 Contact with water liberates extremely
flammable gases.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 8 Keep container dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 17567-17-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 17567-17-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 17567-17-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/14/2004 Revision #1 Date: 5/14/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
TETRAPROPYLAMMONIUM HYDROXIDE (25% IN WATER)
| 4499-86-9 |
|
Decacyclene, 95%
| 191-48-0 |
|
5-Methoxy-2-methylbenzselenazole, 97%
| 2946-17-0 |
|
2-Fluorobenzaldehyde
| 446-52-6 |
|
2-Aminonaphtho[1,2]Thiazole, 98% (Titr.)
| 40172-65-4 |
|
n-Hexyllithium, 33 wt% in n-hexane
| 110-54-3 |
|
Quinazoline, 98%
| 253-82-7 |
|
N-tert-Butoxycarbonyl-1,6-hexanediamine, 95%
| 51857-17-1 |
|
Imidazole, Crystalline, 99+%
| 288-32-4 |
|
Phenyltin Trichloride, 98%
| 1124-19-2 |
|
Potassium tris(1-pyrazolyl)borohydride
| 18583-60-3 |
|
1,3,5-Benzenetrisulfonyl chloride
| 21538-06-7 |
|
Potassium tris(3,5-dimethyl-1-pyrazolyl)borohydride, 99%
| 17567-17-8 |
|
BIS(2,4,6-TRIMETHYLPYRIDINE)IODINE (I) HEXAFLUOROPHOSPHATE
| |
|
1-Hydroxy-1-Cyclopropanecarboxyllic Acid
| 17994-25-1 |
|
AGMATINE SULFATE, 85+%
| 2482-00-0 |
|
2,6-Di-Tert.-Butyl-4-Methylphenyldiazo Acetate
| 125640-92-8 |
|
3-Methylpiperidine, 99%
| 626-56-2 |
|
Aluminum atomic absorption standard solution, 1 mg/ml Al in 0.5N HNO3
| 7429-90-5 |
|
Diethyl diethylmalonate, 98% (gc)
| 77-25-8 |
|
Nicotine, pract., 95%
| 54-11-5 |
|
Deoxyribonucleic acid (d.n.a.)
| |
|
3-(Trifluoromethoxy)Benzonitrile, 97%
| 52771-22-9 |
|
Sodium Pivalate, 99% (titr., on the dry basis)
| 1184-88-9 |
|
2-Amino-4,5-dimethylthiazole hydrobromide, 99%
| 7170-76-5 |
|
Arion pigment
| |
|
Aziridino[2',3':1,2][60]fullerene
| |
|
Azur Eosin Methylene-Blue Solution According to Giemsa
| 0-00-1 |
|
n-Benzyl-4-(2-hydroxyethyl)piperidine, 97+%
| |
|
3,5-bis(chloromethyl)-2,4,6-trimethyl-phenol, 96% (gc)
| 33919-18-5 |
|
1,4-Bis(Diphenylphosphino)Butane
| 7688-25-7 |
|
Bis(phenylsulfonyl)sulfide, 96% (TLC)
| |
|
Iminodiacetic Acid, 98%
| 142-73-4 |
|
3-Bromophenylacetic acid
| 1878-67-7 |
|
p-Tert-Butylcalix (7) Arene
| |
|
p-Tert-Butyldihomooxacalix (4) Arene
| |
|
Carbopol 940
| 9003-01-4 |
|
2-(2-Chloroethoxy)ethanol
| 628-89-7 |
|
3-(4-Chlorophenyl)pyrazole
| 59843-58-2 |
|
3-Amino-1-phenyl-1-propanol hydrochloride
| |
|
1,5-Cyclooctadiene
| 111-78-4 |
|
trans-5-Decen-1-ol, 95%
| 56578-18-8 |
|
1,1-Diethoxycyclohexane
| 1670-47-9 |
|
3,4-Difluorobenzyl alcohol, 99%
| 85118-05-4 |
|
2,5-Dihydroxy-2,5-dimethyl-1,4-dithiane, 95%
| 55704-78-4 |
|
Ethyl 3-benzoylacrylate, tech. 93%, containg ca 3% cis-isomer
| 17450-56-5 |
|
Methyl 4-chloroacetoacetate,97%
| 32807-28-6 |
|
P-Isopropylcalix[4]arene
| |
|
P-Isopropylcalix[6]arene
| |
|
5-Amino-1-Pentanol
| 2508-29-4 |
|
|