**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 18880-04-1 |3,4-Dichlorobenzyl Bromide | 97% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Lachrymator (substance which increases the flow of
tears).Corrosive.
Potential Health Effects
Eye:
Causes eye burns. Produces irritation, characterized by a burning
sensation, redness, tearing, inflammation, and possible corneal
injury. Lachrymator (substance which increases the flow of tears).
May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause cardiac disturbances. The toxicological properties
of this substance have not been fully investigated. May cause
central nervous system effects. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated.
Aspiration may lead to pulmonary edema. May cause cardiac
abnormalities. May cause systemic effects. May cause Central Nervous
System Effects characterized by apathy, mental confusion, blurred
vision, and tremors.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Containers
may explode in the heat of a fire. Contact with metals may evolve
flammable hydrogen gas. Non-combustible, substance itself does not
burn but may decompose upon heating to produce corrosive and/or toxic
fumes.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Do not
ingest or inhale. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 18880-04-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: colorless to yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 116 - 119 deg C @ 1mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 239.93
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, electrical
sparks, exposure to flame.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 18880-04-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3,4-Dichlorobenzyl Bromide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 18880-04-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 18880-04-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 18880-04-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/15/1998 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Aluminum Nitrate Nonahydrate, P.A.
| 7784-27-2 |
|
Acetamide
| 60-35-5 |
|
2-Methoxyethylisothiocyanate
| 38663-85-3 |
|
9-Methyladenine, 98%
| 700-00-5 |
|
Tetrahydropyran, 99%
| 142-68-7 |
|
Methyl Vanillate, 99%
| 3943-74-6 |
|
Acetanilide
| 103-84-4 |
|
3,4-Diaminothiophene dihydrochloride, 99%
| 0-01-1 |
|
Dodecylbenzenesulfonic acid, sodium salt, tech.
| 25155-30-0 |
|
(3S-cis)-(+)-3,7a-Diphenyltetrahydropyrrolo-[2,1-b]oxazol-5(6H)-one
| 161970-71-4 |
|
Hydroxylamine-O-Sulfonic Acid, 97%
| 2950-43-8 |
|
Acetic acid, >96%
| 64-19-7 |
|
6-Chloro-2-Methyl-4-Nitroaniline, 97%
| 69951-02-6 |
|
Nonidet?? P-40, 99%
| 9016-45-9 |
|
DL-2'-Methylphenylalanine Hydrochloride
| 22888-51-3 |
|
DL-5-Methyl-1,2,3,4-Tetrahydroisoquinoline-3-Carboxylic Acid
| 151637-59-1 |
|
1-Chloro-2-Methyl-2-Propanol, 98%
| 558-42-9 |
|
DL-N-FMOC-2'-Methylphenylalanine
| 135944-06-8 |
|
DL-Alpha-Aminosuberic Acid
| 3054-07-7 |
|
Acetic anhydride
| 108-24-7 |
|
Pentacyanoamine ferroate, ammonium disodium salt, pentahydrate 97%
| 80789-79-3 |
|
DL-1,2,3,4-Tetrahydroisoquinoline-1-Carboxylic Acid Hydrochloride
| 0-01-1 |
|
DL-BOC-5-Methyl-1,2,3,4-Tetrahydroisoquinoline-3-Carboxylic Acid, 98%
| 0-01-1 |
|
DL-BOC-2'-Methylphenylalanine, 98%
| 0-01-1 |
|
4-Acetamidobutyric acid, 99+ %
| 3025-96-5 |
|
1-Acetylthiosemicarbazide, 95%
| 2302-88-7 |
|
2,4-Dimethylsulfolane, 95%
| 1003-78-7 |
|
Acetone
| 67-64-1 |
|
3,4-Dichlorobenzyl Bromide, 97%
| 18880-04-1 |
|
3-Chlorobenzal Chloride, 96%
| 0-01-1 |
|
70 wt% Nickel on silica catalyst, reduced and stabilized, 30-40 M2 Ni
| 1313-99-1 |
|
2-Chloro-4,5-Difluorobenzoic Acid, 99+%
| 110877-64-0 |
|
3-Aminoquinuclidine dihydrochloride, 98%
| 6530-09-2 |
|
66 wt% Nickel on silica catalyst, reduced and stabilized, 20-30 M2 Ni
| 1313-99-1 |
|
66 wt% Nickel on silica catalyst, reduced and stabilized, 30-40 M2 Ni
| 1313-99-1 |
|
50 wt% Nickel on alumina catalyst, reduced and stabilized,15-25 M2 Ni
| 1313-99-1 |
|
3-Amino-N,N-Dimethyl-4-Nitroaniline, 97%
| 2069-71-8 |
|
4-Amino-N,N-Dimethyl-3-Nitroaniline, 97%
| 16293-12-2 |
|
4-Bromo-3-Nitroaniline, 97%
| 53324-38-2 |
|
4-Butoxy-3-Nitroaniline, 97%
| 0-01-1 |
|
Aluminum Oxide, Activated, Acidic, for Column Chromatography, 50-200
| 1344-28-1 |
|
4,4-Dimethyl-1-phenyl-3-pyrazolidone, 99%
| 2654-58-2 |
|
4-Iodo-3-Nitrophenol, 97%
| 50590-07-3 |
|
Aluminum, Powder, 200 Mesh, 99%
| 7429-90-5 |
|
3-Iodo-4-Nitrotoluene, 97%
| 52488-29-6 |
|
3-Pyridinecarboxaldehyde, 98%
| 500-22-1 |
|
Isodehydracetic acid, 99+%
| 480-65-9 |
|
2,2'-(3,6-Dithiaoctamethylene)dipyridine, 99%
| 64691-70-9 |
|
3-Iodo-4-Nitroanisole, 97%
| 0-01-1 |
|
Hecogenin acetate
| 915-35-5 |
|
|