**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2855-13-2 |Isophorondiamine | 99+% | 220-666-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 21/22 34 43 52/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Causes burns. May
cause sensitization by skin contact. Harmful to aquatic organisms,
may cause long-term adverse effects in the aquatic
environment.Dangerous for the environment.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. May cause sensitization by skin contact.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. May cause burning
sensation, coughing, wheezing, laryngitis, shortness of breath,
headache, nausea, and vomiting.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas. Runoff
from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Do not ingest or
inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2855-13-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: APHA: 15 max
Odor: amine-like
pH: 11.6 @ 9 g/l (20C)
Vapor Pressure: 0.02 hPa @ 20 deg C
Viscosity: 18 mPa.s @ 20 deg C
Boiling Point: 247 deg C
Freezing/Melting Point: 10 deg C
Autoignition Temperature: 380 deg C ( 716.00 deg F)
Flash Point: 117 deg C ( 242.60 deg F)
Explosion Limits, lower: 1.2 Vol%
Explosion Limits, upper: Not available.
Decomposition Temperature: > 260 deg C
Solubility in water: Miscible.
Specific Gravity/Density: 0.920
Molecular Formula: C10H22N2
Molecular Weight: 170.3
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. Amines absorb carbon dioxide from the air to form carbamate
salts.
Conditions to Avoid:
Excess heat, Avoid temperatures of 112C/233F and above..
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, halogens, halogenated organics (e.g.
dibromoethane, hexachlorobenzene, methyl chloride,
trichloroethylene), nitromethane, hypochlorite.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, ammonia.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2855-13-2: GV5020833
LD50/LC50:
Not available.
LD50 (Oral, rat) : 1030 mg/kg.
Carcinogenicity:
Isophorondiamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Isophoronediamine
Hazard Class: 8
UN Number: 2289
Packing Group: III
IMO
Shipping Name: Isophoronediamine
Hazard Class: 8
UN Number: 2289
Packing Group: III
RID/ADR
Shipping Name: Isophoronediamine
Hazard Class: 8
UN Number: 2289
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 34 Causes burns.
R 43 May cause sensitization by skin contact.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 2855-13-2: 1
Canada
CAS# 2855-13-2 is listed on Canada's DSL List.
CAS# 2855-13-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2855-13-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/16/2002 Revision #1 Date: 7/01/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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ALL MSDS PAGES IN THIS GROUP
| NAME | CAS |
Bis(cyclopentadienyl)tungsten dichloride, 98%
| 12184-26-8 |
Bis(isopropylcyclopentadienyl)zirconium dichloride, 98%
| 58628-40-3 |
Tetrakis(diethylamino)zirconium
| 13801-49-5 |
Cyclopentadienyltungsten tricarbonyl dimer
| 12566-66-4 |
Triisopropoxyvanadium(V) oxide
| 5588-84-1 |
Bis(cyclopentadienyl)vanadium
| 1277-47-0 |
Bis(cyclopentadienyl)vanadium dichloride
| 12083-48-6 |
Cellulose Ester: UV Curable (25% in n-Propyl Acetate)
| 0-00-1 |
Bis(pentamethylcyclopentadienyl)zirconium dichloride
| 54039-38-2 |
Dichlorobis(indenyl)zirconium(IV)
| 12148-49-1 |
2,4,6-Trimethylbenzylamine
| 40393-99-5 |
2,5-Dimethylbenzylamine, 99%
| 93-48-1 |
2-Methylphenethylamine, 97%
| 55755-16-3 |
3-Methylphenethylamine, 98%
| 55755-17-4 |
2,5-Dimethylphenethylamine
| 23068-44-2 |
2,4,6-Trimethylphenethylamine
| 76935-65-4 |
2-Bromobenzylamine
| 3959-05-5 |
3-Bromobenzylamine
| 10269-01-9 |
4-Bromobenzylamine, 99%
| 3959-07-7 |
2-Bromophenethylamine, 99%
| 65185-58-2 |
3-Bromophenethylamine, 99%
| 58971-11-2 |
2-Chloroethylamine Hydrochloride, 98%
| 870-24-6 |
2,6-Dichlorophenethylamine, 99%
| 14573-23-0 |
3,4-Dichlorophenethylamine, 99%
| 21581-45-3 |
Isophorondiamine, 99+%
| 2855-13-2 |
3-Methoxyacrylonitrile, mixture of cis and trans, 96%
| 60838-50-8 |
4-Methoxyphenethyl alcohol, 96%
| 702-23-8 |
2-Methylbutyraldehyde, tech. 90%
| 96-17-3 |
2,6-Dichlorobenzylamine
| 6575-27-5 |
2-Methylphenylacetone, 97%
| 51052-00-7 |
3-Methylphenylacetone, 99%
| 18826-61-4 |
4-Methylphenylacetone, 98%
| 2096-86-8 |
2,5-Dimethylphenylacetone
| 53291-89-7 |
3,4,5-Trimethylphenylacetone
| 0-01-1 |
2-Chloro-6-Fluorophenylacetone, 99%
| 93839-16-8 |
2-Bromophenylacetone, 99%
| 21906-31-0 |
Bismuth
| 7440-69-9 |
3-Bromophenylacetone, 99%
| 21906-32-1 |
4-Bromophenylacetone, 99%
| 6186-22-7 |
2-Chlorophenylacetone, 97%
| 6305-95-9 |
3-Chlorophenylacetone, 94%
| 14123-60-5 |
Diethyl acetylsuccinate, 99%
| 1115-30-6 |
4-Chlorophenylacetone, 98%
| 5586-88-9 |
2,4-Dichlorophenylacetone, 98%
| 93457-07-9 |
2,6-Dichlorophenylacetone, 98%
| 93457-06-8 |
2,6-Dichlorophenylacetone, 99%
| 6097-32-1 |
Bismuth nitrate pentahydrate
| 10035-06-0 |
3-Fluorophenylacetone, 98%
| 1737-19-5 |
5-Amino-4,6-dihydroxypyrimidine
| 69340-97-2 |
Cetyldimethylethylammonium Bromide, 99%
| 124-03-8 |
|
|