**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7440-69-9 |Bismuth | | 231-177-4
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause mild skin irritation. Low hazard for usual industrial
handling. Repeated or prolonged exposure may cause a bismuth line or
black spots on the gums, foul breath and salivation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause headache.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Repeated or prolonged exposure may cause a bismuth line or black
spots on the gums, foul breath and salivation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. Get medical aid if
cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable when exposed to flame.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Remove all sources of ignition.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash hands before eating. Use with adequate ventilation. Minimize
dust generation and accumulation. Avoid contact with skin and eyes.
Avoid contact with heat, sparks and flame. Avoid ingestion and
inhalation.
Storage:
Keep away from heat and flame. Keep away from sources of ignition.
Keep from contact with oxidizing materials. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from acids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: silver- white or red
Odor: odorless
pH: Not available.
Vapor Pressure: 1 mm Hg @1870F
Viscosity: Not available.
Boiling Point: 2588 deg F
Freezing/Melting Point: 520.3 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 9.80
Molecular Formula: Bi
Molecular Weight: 208.984
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, strong
oxidants.
Incompatibilities with Other Materials:
Incompatible with aluminum and air, ammonium nitrate, chloric acid,
chlorine, iodine pentafluoride, nitric acid, perchloric acid,
nitrosyl fluoride, iodine pentafluoride and oxidizing agents.
Hazardous Decomposition Products:
Bismuth oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7440-69-9: EB2600000
LD50/LC50:
CAS# 7440-69-9: Oral, mouse: LD50 = 10 gm/kg; Oral, rat: LD50 = 5
gm/kg.
Carcinogenicity:
Bismuth -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7440-69-9: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7440-69-9 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7440-69-9: OEL-RUSSIA:STEL 0.5 mg/m3
US FEDERAL
TSCA
CAS# 7440-69-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Bis(cyclopentadienyl)tungsten dichloride, 98%
| 12184-26-8 |
|
Bis(isopropylcyclopentadienyl)zirconium dichloride, 98%
| 58628-40-3 |
|
Tetrakis(diethylamino)zirconium
| 13801-49-5 |
|
Cyclopentadienyltungsten tricarbonyl dimer
| 12566-66-4 |
|
Triisopropoxyvanadium(V) oxide
| 5588-84-1 |
|
Bis(cyclopentadienyl)vanadium
| 1277-47-0 |
|
Bis(cyclopentadienyl)vanadium dichloride
| 12083-48-6 |
|
Cellulose Ester: UV Curable (25% in n-Propyl Acetate)
| 0-00-1 |
|
Bis(pentamethylcyclopentadienyl)zirconium dichloride
| 54039-38-2 |
|
Dichlorobis(indenyl)zirconium(IV)
| 12148-49-1 |
|
2,4,6-Trimethylbenzylamine
| 40393-99-5 |
|
2,5-Dimethylbenzylamine, 99%
| 93-48-1 |
|
2-Methylphenethylamine, 97%
| 55755-16-3 |
|
3-Methylphenethylamine, 98%
| 55755-17-4 |
|
2,5-Dimethylphenethylamine
| 23068-44-2 |
|
2,4,6-Trimethylphenethylamine
| 76935-65-4 |
|
2-Bromobenzylamine
| 3959-05-5 |
|
3-Bromobenzylamine
| 10269-01-9 |
|
4-Bromobenzylamine, 99%
| 3959-07-7 |
|
2-Bromophenethylamine, 99%
| 65185-58-2 |
|
3-Bromophenethylamine, 99%
| 58971-11-2 |
|
2-Chloroethylamine Hydrochloride, 98%
| 870-24-6 |
|
2,6-Dichlorophenethylamine, 99%
| 14573-23-0 |
|
3,4-Dichlorophenethylamine, 99%
| 21581-45-3 |
|
Isophorondiamine, 99+%
| 2855-13-2 |
|
3-Methoxyacrylonitrile, mixture of cis and trans, 96%
| 60838-50-8 |
|
4-Methoxyphenethyl alcohol, 96%
| 702-23-8 |
|
2-Methylbutyraldehyde, tech. 90%
| 96-17-3 |
|
2,6-Dichlorobenzylamine
| 6575-27-5 |
|
2-Methylphenylacetone, 97%
| 51052-00-7 |
|
3-Methylphenylacetone, 99%
| 18826-61-4 |
|
4-Methylphenylacetone, 98%
| 2096-86-8 |
|
2,5-Dimethylphenylacetone
| 53291-89-7 |
|
3,4,5-Trimethylphenylacetone
| 0-01-1 |
|
2-Chloro-6-Fluorophenylacetone, 99%
| 93839-16-8 |
|
2-Bromophenylacetone, 99%
| 21906-31-0 |
|
Bismuth
| 7440-69-9 |
|
3-Bromophenylacetone, 99%
| 21906-32-1 |
|
4-Bromophenylacetone, 99%
| 6186-22-7 |
|
2-Chlorophenylacetone, 97%
| 6305-95-9 |
|
3-Chlorophenylacetone, 94%
| 14123-60-5 |
|
Diethyl acetylsuccinate, 99%
| 1115-30-6 |
|
4-Chlorophenylacetone, 98%
| 5586-88-9 |
|
2,4-Dichlorophenylacetone, 98%
| 93457-07-9 |
|
2,6-Dichlorophenylacetone, 98%
| 93457-06-8 |
|
2,6-Dichlorophenylacetone, 99%
| 6097-32-1 |
|
Bismuth nitrate pentahydrate
| 10035-06-0 |
|
3-Fluorophenylacetone, 98%
| 1737-19-5 |
|
5-Amino-4,6-dihydroxypyrimidine
| 69340-97-2 |
|
Cetyldimethylethylammonium Bromide, 99%
| 124-03-8 |
|
|