**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 5588-84-1 |Triisopropoxyvanadium(V) oxide | 100 | 226-997-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 20/21/22 37/38 41
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if
swallowed. Irritating to respiratory system and skin. Risk of
serious damage to eyes.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause severe irritation of the digestive
tract. Hydrolyzes in the presence of water and body fluids to
isopropanol, which can cause headache, nausea, narcosis, and mental
depresssion.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Get medical aid. Wash
clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Flammable liquid and vapor. Will hydrolyze in mildly exothermic
manner in the presence of water to form isopropanol and vanadic
acids.
Extinguishing Media:
DO NOT USE WATER! Use dry chemical, dry sand, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Isolate area and deny entry. Provide
ventilation. Do not expose spill to water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Keep away from heat, sparks and flame. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames. Avoid breathing
vapor or mist. Do not get in eyes. Avoid contact with skin and
clothing.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 5588-84-1:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: gold
Odor: alcohol-like
pH: Not available.
Vapor Pressure: 10 mm Hg @ 0 deg C
Viscosity: 3 cps @ 37.8 deg C
Boiling Point: 80-82 deg C @ 2 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 44 deg C ( 111.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Hydrolysis.
Specific Gravity/Density: 1.035
Molecular Formula: C9H21O4V
Molecular Weight: 244.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Will hydrolyze in
mildly exothermic manner in the presence of water to form
isopropanol and vanadic acids.
Conditions to Avoid:
Ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, water.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, vanadium oxide (VOx) gases.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 5588-84-1 unlisted.
LD50/LC50:
Not available.
Very similar chemical, triisobutyl vanadate, CAS 19120-62-8, has oral
LD50 (rat) = 293 mg/kg and is corrosive to rabbit eyes.
Carcinogenicity:
Triisopropoxyvanadium(V) oxide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Flammable liquid, toxic, n.o.s.*
Hazard Class: 3
UN Number: 1992
Packing Group: III
IMO
Shipping Name: Flammable liquid, toxic, n.o.s.
Hazard Class: 3.3
UN Number: 1992
Packing Group: III
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 37/38 Irritating to respiratory system and skin.
R 41 Risk of serious damage to eyes.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 5588-84-1: No information available.
Canada
CAS# 5588-84-1 is listed on Canada's NDSL List.
CAS# 5588-84-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5588-84-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/16/2002 Revision #1 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Bis(cyclopentadienyl)tungsten dichloride, 98%
| 12184-26-8 |
|
Bis(isopropylcyclopentadienyl)zirconium dichloride, 98%
| 58628-40-3 |
|
Tetrakis(diethylamino)zirconium
| 13801-49-5 |
|
Cyclopentadienyltungsten tricarbonyl dimer
| 12566-66-4 |
|
Triisopropoxyvanadium(V) oxide
| 5588-84-1 |
|
Bis(cyclopentadienyl)vanadium
| 1277-47-0 |
|
Bis(cyclopentadienyl)vanadium dichloride
| 12083-48-6 |
|
Cellulose Ester: UV Curable (25% in n-Propyl Acetate)
| 0-00-1 |
|
Bis(pentamethylcyclopentadienyl)zirconium dichloride
| 54039-38-2 |
|
Dichlorobis(indenyl)zirconium(IV)
| 12148-49-1 |
|
2,4,6-Trimethylbenzylamine
| 40393-99-5 |
|
2,5-Dimethylbenzylamine, 99%
| 93-48-1 |
|
2-Methylphenethylamine, 97%
| 55755-16-3 |
|
3-Methylphenethylamine, 98%
| 55755-17-4 |
|
2,5-Dimethylphenethylamine
| 23068-44-2 |
|
2,4,6-Trimethylphenethylamine
| 76935-65-4 |
|
2-Bromobenzylamine
| 3959-05-5 |
|
3-Bromobenzylamine
| 10269-01-9 |
|
4-Bromobenzylamine, 99%
| 3959-07-7 |
|
2-Bromophenethylamine, 99%
| 65185-58-2 |
|
3-Bromophenethylamine, 99%
| 58971-11-2 |
|
2-Chloroethylamine Hydrochloride, 98%
| 870-24-6 |
|
2,6-Dichlorophenethylamine, 99%
| 14573-23-0 |
|
3,4-Dichlorophenethylamine, 99%
| 21581-45-3 |
|
Isophorondiamine, 99+%
| 2855-13-2 |
|
3-Methoxyacrylonitrile, mixture of cis and trans, 96%
| 60838-50-8 |
|
4-Methoxyphenethyl alcohol, 96%
| 702-23-8 |
|
2-Methylbutyraldehyde, tech. 90%
| 96-17-3 |
|
2,6-Dichlorobenzylamine
| 6575-27-5 |
|
2-Methylphenylacetone, 97%
| 51052-00-7 |
|
3-Methylphenylacetone, 99%
| 18826-61-4 |
|
4-Methylphenylacetone, 98%
| 2096-86-8 |
|
2,5-Dimethylphenylacetone
| 53291-89-7 |
|
3,4,5-Trimethylphenylacetone
| 0-01-1 |
|
2-Chloro-6-Fluorophenylacetone, 99%
| 93839-16-8 |
|
2-Bromophenylacetone, 99%
| 21906-31-0 |
|
Bismuth
| 7440-69-9 |
|
3-Bromophenylacetone, 99%
| 21906-32-1 |
|
4-Bromophenylacetone, 99%
| 6186-22-7 |
|
2-Chlorophenylacetone, 97%
| 6305-95-9 |
|
3-Chlorophenylacetone, 94%
| 14123-60-5 |
|
Diethyl acetylsuccinate, 99%
| 1115-30-6 |
|
4-Chlorophenylacetone, 98%
| 5586-88-9 |
|
2,4-Dichlorophenylacetone, 98%
| 93457-07-9 |
|
2,6-Dichlorophenylacetone, 98%
| 93457-06-8 |
|
2,6-Dichlorophenylacetone, 99%
| 6097-32-1 |
|
Bismuth nitrate pentahydrate
| 10035-06-0 |
|
3-Fluorophenylacetone, 98%
| 1737-19-5 |
|
5-Amino-4,6-dihydroxypyrimidine
| 69340-97-2 |
|
Cetyldimethylethylammonium Bromide, 99%
| 124-03-8 |
|
|