**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3088-41-3 |1-Piperidinepropionitrile | 99 | 221-417-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The
toxicological properties of this material have not been fully
investigated.Harmful.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause systemic toxic effects on the heart, liver, and
kidneys. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to
those described for ingestion. The toxicological properties of this
substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Water may be ineffective. Use agent most appropriate to extinguish
fire. Use water spray, dry chemical, carbon dioxide, or appropriate
foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Absorb spill using an absorbent, non-combustible
material such as earth, sand, or vermiculite. Do not use combustible
materials such as sawdust. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not get in eyes, on skin, or on clothing. Keep container tightly
closed. Do not ingest or inhale. Use only in a chemical fume hood.
Do not breathe vapor.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 3088-41-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear faint yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 110.0 - 111.0 deg C @ 16.00mm
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 102 deg C ( 215.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: .9330g/cm3
Molecular Formula: C8H14N2
Molecular Weight: 138.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong acids, strong
bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, cyanide fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3088-41-3: TN3714000
LD50/LC50:
Not available.
Carcinogenicity:
1-Piperidinepropionitrile -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITRILES, LIQUID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
IMO
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
RID/ADR
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 3088-41-3: No information available.
Canada
CAS# 3088-41-3 is listed on Canada's NDSL List.
CAS# 3088-41-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3088-41-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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| 156-57-0 |
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Benzeneseleninic acid, 99%
| 6996-92-5 |
|
Trans-1,2-Cyclohexanediol, 98%
| 1460-57-7 |
|
Triphenyltin hydride
| 892-20-6 |
|
1,9-Decadiene, 97%
| 1647-16-1 |
|
Benzo[b]tellurophene-2-carboxylic acid, 98%
| 0-01-0 |
|
Unsym-dimethylethylenediamine, 99%
| 108-00-9 |
|
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| 961-38-6 |
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alpha-Furil, 99%
| 492-94-4 |
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| 1453-82-3 |
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| 0-01-1 |
|
4-Bromo-2,6-Dimethylphenol, 99%
| 2374-05-2 |
|
2-Isopropylphenol, 97%
| 88-69-7 |
|
2,4,5,6-Tetrachloro-m-xylene, 96% (gc)
| 877-09-8 |
|
4-(N-ethyl-N-2-methoxyethyl)-2-methylphenylenediamine di-p-toluene
| 50928-80-8 |
|
Silver Carbonate, Dihydrate, 98% (titr.)
| 534-16-7 |
|
Diethylaminoacetaldehyde diethyl acetal, 99%
| 3616-57-7 |
|
Tetrabutylammonium hydrogen sulfate, hplc grade
| 32503-27-8 |
|
Dibenzo-18-crown-6, 98%
| 14187-32-7 |
|
1-Bromotetradecane, 98%
| 112-71-0 |
|
5-Nitro-2-furoic acid, 98%
| 645-12-5 |
|
Aminomethanesulfonic Acid, 97%
| 13881-91-9 |
|
Muramic Acid, Hydrate
| 1114-41-6 |
|
3-[3-(2-Iodoacetamido)propylcarbamoyl]- proxyl, free radical
| 77695-02-4 |
|
Dichloromethylvinylsilane, 97%
| 124-70-9 |
|
Poly(acrylamide), carboxyl modified, low carboxyl content,
| |
|
D-alpha-Tocopherol, 99%
| 59-02-9 |
|
2H-1,4-Benzothiazin-3(4H)-one, 99+%
| 5325-20-2 |
|
Quinaldic acid, 99%
| 93-10-7 |
|
L-Alanine Ethyl Ester Hydrochloride, 98%
| 1115-59-9 |
|
4-Amino-Meta-Cresol, 99+%
| 2835-99-6 |
|
Triisopropylorthoformate, 98+%
| 4447-60-3 |
|
2,4-Dichlorobenzylamine, 98%
| 95-00-1 |
|
(+)-Hexahydro-3a-hydroxy-7a-methyl-1H-inden-1,5(6H)-dione, 95%
| 33879-04-8 |
|
4-Phenylcyclohexanone, 98+%
| 4894-75-1 |
|
Ethyl 3-Ethoxypropionate, 99+%
| 763-69-9 |
|
Ethyl 5-bromovalerate, 99%
| 14660-52-7 |
|
Tetraethylenepentamine, tech.
| 112-57-2 |
|
2,2,6,6-Tetramethyl-3,5-heptanedione, 98%
| 1118-71-4 |
|
1,3-Dihydroxyacetone, Dimer, 98%
| 62147-49-3 |
|
Europium(III) Fluoride 99+%
| 13765-25-8 |
|
1-Piperidinepropionitrile, 99%
| 3088-41-3 |
|
4,4'-Dihydroxybenzophenone, 97%
| 611-99-4 |
|
1-Acenaphthenol, 99%
| 6306-07-6 |
|
5-Chloro-2-nitrobenzonitrile, 97%
| 34662-31-2 |
|
3-Methyl-1-adamantaneacetic acid, 99%
| 14202-13-2 |
|
|