**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 892-20-6 |Triphenyltin hydride | 100 | 212-967-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.Light
sensitive.Moisture sensitive.Air sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon
dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. May form flammable
dust-air mixtures. Avoid contact with eyes, skin, and clothing.
Avoid ingestion and inhalation. Do not allow contact with water.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Water free
area - refrigerator.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 892-20-6:
United Kingdom, WEL - TWA: (listed as tin organic compounds): 0.1
mg/m3 TWA (except cyhexatin, as Sn)
United Kingdom, WEL - STEL: (listed as tin organic compounds): 0.
mg/m3 STEL (except cyhexatin, as Sn)
United States OSHA: 0.1 mg/m3 TWA (as Sn) (listed under Tin orga
compounds).
Belgium - TWA: (listed as tin organic compounds): 0.1 mg/m3 VLE (
Sn)
Belgium - STEL: (listed as tin organic compounds): 0.2 mg/m3 VLE
Sn)
France - VME: (listed as tin organic compounds): 0.1 mg/m3 VME (a
Sn)
France - VLE: (listed as tin organic compounds): 0.2 mg/m3 VLE (a
Sn)
Germany: (listed as tin organic compounds): 0.1 mg/m3 VME (as Sn)
Germany: (listed as tin organic compounds): Skin absorber
Malaysia: (listed as tin organic compounds): 0.1 mg/m3 TWA (as Sn
Netherlands: (listed as tin organic compounds): 0.2 mg/m3 STEL (a
Sn)
Netherlands: (listed as tin organic compounds): 0.1 mg/m3 MAC (as
Spain: (listed as tin organic compounds): 0.1 mg/m3 VLA-ED (as Sn
Spain: (listed as tin organic compounds): 0.2 mg/m3 VLA-EC (as Sn
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid above room te
Color: white - colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 163 - 165 deg C @ .30mm Hg
Freezing/Melting Point: 28 deg C
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: may decompose in water
Specific Gravity/Density: 1.3740g/cm3
Molecular Formula: C18H16Sn
Molecular Weight: 351.01
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May discolor on
exposure to light.
Conditions to Avoid:
Incompatible materials, light, moisture, exposure to air, contact
with water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, tin/tin oxides.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 892-20-6: WH8882000
LD50/LC50:
CAS# 892-20-6: Oral, mouse: LD50 = 81 mg/kg; Oral, rat: LD50 = 491
mg/kg.
Carcinogenicity:
Triphenyltin hydride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ORGANOTIN COMPOUND, LIQUID, N.O.S.
Hazard Class: 6.1
UN Number: 2788
Packing Group: III
IMO
Shipping Name: ORGANOTIN COMPOUND, LIQUID, N.O.S.
Hazard Class: 6.1
UN Number: 2788
Packing Group: III
RID/ADR
Shipping Name: ORGANOTIN COMPOUND, LIQUID, N.O.S.
Hazard Class: 6.1
UN Number: 2788
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 892-20-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 892-20-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 892-20-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/04/1998 Revision #3 Date: 4/27/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-(Chlorosulfonyl)benzoic acid,96% (titr.)
| 10130-89-9 |
|
1,2,3-Trichloro-4-nitrobenzene
| 17700-09-3 |
|
Manganese atomic absorption standard solution, 1 mg/ml Mn in 2% HNO3
| 7439-96-5 |
|
2-Bromopropene, 99+%
| 557-93-7 |
|
2-Aminoethanethiol hydrochloride
| 156-57-0 |
|
Benzeneseleninic acid, 99%
| 6996-92-5 |
|
Trans-1,2-Cyclohexanediol, 98%
| 1460-57-7 |
|
Triphenyltin hydride
| 892-20-6 |
|
1,9-Decadiene, 97%
| 1647-16-1 |
|
Benzo[b]tellurophene-2-carboxylic acid, 98%
| 0-01-0 |
|
Unsym-dimethylethylenediamine, 99%
| 108-00-9 |
|
2,4,6-tri-tert-butylaniline, 97+%
| 961-38-6 |
|
alpha-Furil, 99%
| 492-94-4 |
|
Isonicotinamide, 99%
| 1453-82-3 |
|
N,N'-Bis (Methoxymethyl) Diaza-12-Crown-4 90%
| 0-01-1 |
|
4-Bromo-2,6-Dimethylphenol, 99%
| 2374-05-2 |
|
2-Isopropylphenol, 97%
| 88-69-7 |
|
2,4,5,6-Tetrachloro-m-xylene, 96% (gc)
| 877-09-8 |
|
4-(N-ethyl-N-2-methoxyethyl)-2-methylphenylenediamine di-p-toluene
| 50928-80-8 |
|
Silver Carbonate, Dihydrate, 98% (titr.)
| 534-16-7 |
|
Diethylaminoacetaldehyde diethyl acetal, 99%
| 3616-57-7 |
|
Tetrabutylammonium hydrogen sulfate, hplc grade
| 32503-27-8 |
|
Dibenzo-18-crown-6, 98%
| 14187-32-7 |
|
1-Bromotetradecane, 98%
| 112-71-0 |
|
5-Nitro-2-furoic acid, 98%
| 645-12-5 |
|
Aminomethanesulfonic Acid, 97%
| 13881-91-9 |
|
Muramic Acid, Hydrate
| 1114-41-6 |
|
3-[3-(2-Iodoacetamido)propylcarbamoyl]- proxyl, free radical
| 77695-02-4 |
|
Dichloromethylvinylsilane, 97%
| 124-70-9 |
|
Poly(acrylamide), carboxyl modified, low carboxyl content,
| |
|
D-alpha-Tocopherol, 99%
| 59-02-9 |
|
2H-1,4-Benzothiazin-3(4H)-one, 99+%
| 5325-20-2 |
|
Quinaldic acid, 99%
| 93-10-7 |
|
L-Alanine Ethyl Ester Hydrochloride, 98%
| 1115-59-9 |
|
4-Amino-Meta-Cresol, 99+%
| 2835-99-6 |
|
Triisopropylorthoformate, 98+%
| 4447-60-3 |
|
2,4-Dichlorobenzylamine, 98%
| 95-00-1 |
|
(+)-Hexahydro-3a-hydroxy-7a-methyl-1H-inden-1,5(6H)-dione, 95%
| 33879-04-8 |
|
4-Phenylcyclohexanone, 98+%
| 4894-75-1 |
|
Ethyl 3-Ethoxypropionate, 99+%
| 763-69-9 |
|
Ethyl 5-bromovalerate, 99%
| 14660-52-7 |
|
Tetraethylenepentamine, tech.
| 112-57-2 |
|
2,2,6,6-Tetramethyl-3,5-heptanedione, 98%
| 1118-71-4 |
|
1,3-Dihydroxyacetone, Dimer, 98%
| 62147-49-3 |
|
Europium(III) Fluoride 99+%
| 13765-25-8 |
|
1-Piperidinepropionitrile, 99%
| 3088-41-3 |
|
4,4'-Dihydroxybenzophenone, 97%
| 611-99-4 |
|
1-Acenaphthenol, 99%
| 6306-07-6 |
|
5-Chloro-2-nitrobenzonitrile, 97%
| 34662-31-2 |
|
3-Methyl-1-adamantaneacetic acid, 99%
| 14202-13-2 |
|
|