**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 95-00-1 |2,4-Dichlorobenzylamine | 98 | 202-382-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Air sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
None
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode in
the heat of a fire. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Place under an inert atmosphere.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Keep container tightly closed. Do not get on skin or in eyes. Do not
ingest or inhale. Use with adequate ventilation. Handle under an
inert atmosphere. Store protected from air. Use and store under
nitrogen. Wash clothing before reuse. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Keep under a nitrogen
blanket. Keep away from strong acids. Corrosives area. Keep
containers tightly closed. Do not expose to air.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 95-00-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 258-260C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.3080g/cm3
Molecular Formula: C7H7Cl2N
Molecular Weight: 176.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Absorbs carbon
dioxide from the air.
Conditions to Avoid:
Incompatible materials, exposure to air, excess heat, strong acids.
Incompatibilities with Other Materials:
Air.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 95-00-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,4-Dichlorobenzylamine -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: III
IMO
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: III
RID/ADR
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 95-00-1: No information available.
Canada
CAS# 95-00-1 is listed on Canada's NDSL List.
CAS# 95-00-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 95-00-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/04/1998 Revision #5 Date: 9/17/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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ALL MSDS PAGES IN THIS GROUP
| NAME | CAS |
4-(Chlorosulfonyl)benzoic acid,96% (titr.)
| 10130-89-9 |
1,2,3-Trichloro-4-nitrobenzene
| 17700-09-3 |
Manganese atomic absorption standard solution, 1 mg/ml Mn in 2% HNO3
| 7439-96-5 |
2-Bromopropene, 99+%
| 557-93-7 |
2-Aminoethanethiol hydrochloride
| 156-57-0 |
Benzeneseleninic acid, 99%
| 6996-92-5 |
Trans-1,2-Cyclohexanediol, 98%
| 1460-57-7 |
Triphenyltin hydride
| 892-20-6 |
1,9-Decadiene, 97%
| 1647-16-1 |
Benzo[b]tellurophene-2-carboxylic acid, 98%
| 0-01-0 |
Unsym-dimethylethylenediamine, 99%
| 108-00-9 |
2,4,6-tri-tert-butylaniline, 97+%
| 961-38-6 |
alpha-Furil, 99%
| 492-94-4 |
Isonicotinamide, 99%
| 1453-82-3 |
N,N'-Bis (Methoxymethyl) Diaza-12-Crown-4 90%
| 0-01-1 |
4-Bromo-2,6-Dimethylphenol, 99%
| 2374-05-2 |
2-Isopropylphenol, 97%
| 88-69-7 |
2,4,5,6-Tetrachloro-m-xylene, 96% (gc)
| 877-09-8 |
4-(N-ethyl-N-2-methoxyethyl)-2-methylphenylenediamine di-p-toluene
| 50928-80-8 |
Silver Carbonate, Dihydrate, 98% (titr.)
| 534-16-7 |
Diethylaminoacetaldehyde diethyl acetal, 99%
| 3616-57-7 |
Tetrabutylammonium hydrogen sulfate, hplc grade
| 32503-27-8 |
Dibenzo-18-crown-6, 98%
| 14187-32-7 |
1-Bromotetradecane, 98%
| 112-71-0 |
5-Nitro-2-furoic acid, 98%
| 645-12-5 |
Aminomethanesulfonic Acid, 97%
| 13881-91-9 |
Muramic Acid, Hydrate
| 1114-41-6 |
3-[3-(2-Iodoacetamido)propylcarbamoyl]- proxyl, free radical
| 77695-02-4 |
Dichloromethylvinylsilane, 97%
| 124-70-9 |
Poly(acrylamide), carboxyl modified, low carboxyl content,
| |
D-alpha-Tocopherol, 99%
| 59-02-9 |
2H-1,4-Benzothiazin-3(4H)-one, 99+%
| 5325-20-2 |
Quinaldic acid, 99%
| 93-10-7 |
L-Alanine Ethyl Ester Hydrochloride, 98%
| 1115-59-9 |
4-Amino-Meta-Cresol, 99+%
| 2835-99-6 |
Triisopropylorthoformate, 98+%
| 4447-60-3 |
2,4-Dichlorobenzylamine, 98%
| 95-00-1 |
(+)-Hexahydro-3a-hydroxy-7a-methyl-1H-inden-1,5(6H)-dione, 95%
| 33879-04-8 |
4-Phenylcyclohexanone, 98+%
| 4894-75-1 |
Ethyl 3-Ethoxypropionate, 99+%
| 763-69-9 |
Ethyl 5-bromovalerate, 99%
| 14660-52-7 |
Tetraethylenepentamine, tech.
| 112-57-2 |
2,2,6,6-Tetramethyl-3,5-heptanedione, 98%
| 1118-71-4 |
1,3-Dihydroxyacetone, Dimer, 98%
| 62147-49-3 |
Europium(III) Fluoride 99+%
| 13765-25-8 |
1-Piperidinepropionitrile, 99%
| 3088-41-3 |
4,4'-Dihydroxybenzophenone, 97%
| 611-99-4 |
1-Acenaphthenol, 99%
| 6306-07-6 |
5-Chloro-2-nitrobenzonitrile, 97%
| 34662-31-2 |
3-Methyl-1-adamantaneacetic acid, 99%
| 14202-13-2 |
|
|