**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 329-01-1 |Alpha,Alpha,Alpha-Trifluoro-mToyl Isoc| 97 | 206-341-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22 33 36/37/38 42
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Danger of cumulative
effects. Irritating to eyes, respiratory system and skin. May cause
sensitization by inhalation.Moisture sensitive.Lachrymator (substance
which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Flammable
liquid and vapor.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 329-01-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 2.44PSI @20 deg C
Viscosity: Not available.
Boiling Point: 54 deg C @ 11.00mm Hg
Freezing/Melting Point: -26 deg C
Autoignition Temperature: > 600 deg C (> 1,112.00 deg F)
Flash Point: 58 deg C ( 136.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >300 deg C
Solubility in water:
Specific Gravity/Density: 1.3590g/cm3
Molecular Formula: C8H4F3NO
Molecular Weight: 187.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Ignition sources, excess heat, exposure to moist air or water,
electrical sparks.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, strong bases, amines.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide,
hydrogen fluoride gas, fluoride fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 329-01-1: NR0200000
LD50/LC50:
CAS# 329-01-1: Inhalation, mouse: LC50 = 3300 mg/m3; Oral, mouse:
LD50 = 975 mg/kg; Oral, rat: LD50 = 975 mg/kg.
Carcinogenicity:
Alpha,Alpha,Alpha-Trifluoro-mToyl Isocyanate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ISOCYANATES, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2206
Packing Group: II
IMO
Shipping Name: ISOCYANATES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2206
Packing Group:
RID/ADR
Shipping Name: ISOCYANATES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2206
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 33 Danger of cumulative effects.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 42 May cause sensitization by inhalation.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 329-01-1: 2
Canada
CAS# 329-01-1 is listed on Canada's NDSL List.
CAS# 329-01-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 329-01-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/18/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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| 312-94-7 |
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| 402-23-3 |
|
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| 402-49-3 |
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| 21742-00-7 |
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| 939-99-1 |
|
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| 2062-25-1 |
|
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| 395-35-7 |
|
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| 2338-75-2 |
|
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| 368-78-5 |
|
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| 381-98-6 |
|
4-Ethoxybenzyl-triphenylphosphonium bromide, 98%
| 82105-88-2 |
|
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| 2268-15-7 |
|
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| 113798-74-6 |
|
Tris(pentafluorophenyl)phosphine, 97%
| 1259-35-4 |
|
Vanadium(v)oxytrifluoride, 99%
| 13709-31-4 |
|
Vinyl trifluoroacetate, 98%
| 433-28-3 |
|
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| 421-83-0 |
|
2,3,4,6-Tetrafluoronitrobenzene, 97+%
| 314-41-0 |
|
3-(Trifluoromethyl)benzylamine, 98%
| 2740-83-2 |
|
Trans-p-(trifluoromethyl)cinnamic acid, 98 %
| 16642-92-5 |
|
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| 351-35-9 |
|
1,5-Diaminonaphthalene, 97%
| 2243-62-1 |
|
(alpha,alpha,alpha-Trifluoro-p-tolyl)acetic acid, 98%
| 32857-62-8 |
|
Alpha,Alpha,Alpha-Trifluoro-Meta-Tolyl Isocyanate, 97%
| 329-01-1 |
|
1,3,5-Trifluoro-2-nitrobenzene, 98%
| 315-14-0 |
|
Erbium (III) Oxide, 99.9%
| 12061-16-4 |
|
Gadolinium (III) Oxide, 99.9%
| 12064-62-9 |
|
Cyclopentadienylmanganese Tricarbonyl
| 12079-65-1 |
|
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| 23582-03-8 |
|
Barium 2-ethylhexanoate, 30% in xylene
| 1330-20-7 |
|
Triethyltin Bromide, 97%
| 2767-54-6 |
|
Niobium(V)Ethoxide, 99.95%
| 3236-82-6 |
|
Scandium(III)Acetate Hydrate, 99.9%
| 3804-23-7 |
|
Neodymium(III)Carbonate Hydrate, 99.9%
| 38245-38-4 |
|
3,5-Dichloro-4-Hydroxybenzoic Acid, 97%
| 3336-41-2 |
|
4-Nitro-3-(trifluoromethyl)phenol, 99%
| 88-30-2 |
|
3,4,5-Trichlorobenzotrifluoride, 97%
| 50594-82-6 |
|
alpha-Methyl-3-(trifluoromethyl)benzyl alcohol, 96%
| 454-91-1 |
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| 41203-22-9 |
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Triruthenium dodecacarbonyl, 99%
| 15243-33-1 |
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|