**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 402-49-3 |alpha'-Bromo-alpha,alpha,alpha-trifluo| 98 | 206-947-8 |
| |ro-p-xylene | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.The toxicological properties of this material have not
been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
No information regarding skin irritation and other potential effects
was found.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
The toxicological properties of this substance have not been fully
investigated.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable solid. May burn rapidly with flare
burning effect. May re-ignite after fire is extinguished.
Extinguishing Media:
Use agent most appropriate to extinguish fire. For large fires, use
water spray, fog or regular foam. Contact professional fire-fighters
immediately. For small fires, use dry chemical, carbon dioxide, sand,
earth, water spray or regular foam. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid generating dusty conditions. Remove all sources of ignition.
Use a spark-proof tool. With a clean shovel, carefully pick up the
material and place it into a clean dry container and cover for
disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Ground and bond
containers when transferring material. Avoid contact with eyes, skin,
and clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 402-49-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 65 - 69 deg C @ 5.00mm Hg
Freezing/Melting Point: 31 - 34 deg C
Autoignition Temperature: Not available.
Flash Point: 88 deg C ( 190.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.5460g/cm3
Molecular Formula: C8H6BrF3
Molecular Weight: 239.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Ignition sources, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas, hydrogen
bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 402-49-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
alpha'-Bromo-alpha,alpha,alpha-trifluoro-p-xylene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 402-49-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 402-49-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 402-49-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/22/1997 Revision #3 Date: 8/05/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,3,6-Trifluorobenzoyl chloride, 98%
| |
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3-Bromo-4-fluorotoluene, 99%
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|
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| 94108-56-2 |
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| 727-99-1 |
|
3-(Trifluoromethyl)benzophenone, 99%
| 728-81-4 |
|
2-(Trifluoromethyl)benzoyl chloride, 98%
| 312-94-7 |
|
2-Cyclohexyl-1-Propanol, 99%
| 5442-00-2 |
|
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| 3048-01-9 |
|
alpha'-Bromo-alpha,alpha,alpha-trifluoro-o-xylene, 98%
| 395-44-8 |
|
alpha'-Bromo-alpha,alpha,alpha-trifluoro-m -xylene, 98%
| 402-23-3 |
|
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| 402-49-3 |
|
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| 21742-00-7 |
|
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| 939-99-1 |
|
2-(Trifluoromethyl)cinnamic acid, 99%
| 2062-25-1 |
|
4-(Trifluoromethyl)Mandelic Acid, 98%
| 395-35-7 |
|
4-(Trifluoromethyl)phenylacetonitrile, 98%
| 2338-75-2 |
|
3-(Trifluoromethyl)Phenylhydrazine, 97%
| 368-78-5 |
|
2-(Trifluoromethyl)acrylic acid, 98%
| 381-98-6 |
|
4-Ethoxybenzyl-triphenylphosphonium bromide, 98%
| 82105-88-2 |
|
2,3,5-Trifluorophenol, 98%
| 2268-15-7 |
|
2,3,6-Trifluorophenol, 98%
| 113798-74-6 |
|
Tris(pentafluorophenyl)phosphine, 97%
| 1259-35-4 |
|
Vanadium(v)oxytrifluoride, 99%
| 13709-31-4 |
|
Vinyl trifluoroacetate, 98%
| 433-28-3 |
|
Trifluoromethanesulfonyl chloride, 99+%
| 421-83-0 |
|
2,3,4,6-Tetrafluoronitrobenzene, 97+%
| 314-41-0 |
|
3-(Trifluoromethyl)benzylamine, 98%
| 2740-83-2 |
|
Trans-p-(trifluoromethyl)cinnamic acid, 98 %
| 16642-92-5 |
|
(alpha,alpha,alpha-Trifluoro-m-tolyl)acetic acid, 98%
| 351-35-9 |
|
1,5-Diaminonaphthalene, 97%
| 2243-62-1 |
|
(alpha,alpha,alpha-Trifluoro-p-tolyl)acetic acid, 98%
| 32857-62-8 |
|
Alpha,Alpha,Alpha-Trifluoro-Meta-Tolyl Isocyanate, 97%
| 329-01-1 |
|
1,3,5-Trifluoro-2-nitrobenzene, 98%
| 315-14-0 |
|
Erbium (III) Oxide, 99.9%
| 12061-16-4 |
|
Gadolinium (III) Oxide, 99.9%
| 12064-62-9 |
|
Cyclopentadienylmanganese Tricarbonyl
| 12079-65-1 |
|
Tris(2-(Diphenylphosphino)ethyl)Phosphine, 97%
| 23582-03-8 |
|
Barium 2-ethylhexanoate, 30% in xylene
| 1330-20-7 |
|
Triethyltin Bromide, 97%
| 2767-54-6 |
|
Niobium(V)Ethoxide, 99.95%
| 3236-82-6 |
|
Scandium(III)Acetate Hydrate, 99.9%
| 3804-23-7 |
|
Neodymium(III)Carbonate Hydrate, 99.9%
| 38245-38-4 |
|
3,5-Dichloro-4-Hydroxybenzoic Acid, 97%
| 3336-41-2 |
|
4-Nitro-3-(trifluoromethyl)phenol, 99%
| 88-30-2 |
|
3,4,5-Trichlorobenzotrifluoride, 97%
| 50594-82-6 |
|
alpha-Methyl-3-(trifluoromethyl)benzyl alcohol, 96%
| 454-91-1 |
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| 41203-22-9 |
|
Triruthenium dodecacarbonyl, 99%
| 15243-33-1 |
|
|