**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 35120-10-6 |(Methylthio)acetonitrile | 99 | 252-383-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if
swallowed.Stench.Lachrymator (substance which increases the flow of
tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin irritation. Causes blistering of the skin. May cause
cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingestion may cause headache, nausea, and vomiting.
Inhalation:
Inhalation at high concentrations may cause CNS depression and
asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Remove contaminated clothing
and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Combustible liquid. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Cover with an activated carbon adsorbent and place into a closed
container for disposal. Remove all sources of ignition. Use a
spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not get in eyes, on skin, or on clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame. Do
not ingest or inhale. Use only in a chemical fume hood. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Do not breathe vapor.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 35120-10-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear, colorless
Odor: stench
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 61.0 - 63.0 deg C @ 15.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 67 deg C ( 152.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: 1.0390g/cm3
Molecular Formula: C3H5NS
Molecular Weight: 87.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide,
nitrogen, hydrogen sulfide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 35120-10-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(Methylthio)acetonitrile -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 35120-10-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 35120-10-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 35120-10-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
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N-(2-Chloroacetyl)-L-tyrosine
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4-Nitrophenylhydrazine hydrochloride, 98% (titr.)
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4-Hydroxyvalerophenone
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2,5-Dimethylaniline, 99%
| 95-78-3 |
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| 92-53-5 |
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Tributylphosphine oxide, 98%
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5-Methoxygramine, 99%
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(-)-Di-P-Toluoyl-L-Tartaric Acid, 97%
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|
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| 2516-33-8 |
|
Octyltrichlorosilane, 97%
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|
(-)-Caryophyllene Oxide, 97%
| 13877-94-6 |
|
4-Acetamidoantipyrine, 97%
| 83-15-8 |
|
(-)-(2S,8AR)-(Camphorylsulfonyl)Oxaziridine, 99+% (99+% e.e.)
| 104372-31-8 |
|
Ethyl 2-Bromo-3-Methylbutyrate, 95% (GC)
| 609-12-1 |
|
Azadirachtin, 98% (HPLC)
| 11141-17-6 |
|
Heptamethyldisilazane, 99%
| 920-68-3 |
|
1-Nonen-3-Ol, 98%
| 21964-44-3 |
|
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| 118-92-3 |
|
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| 35120-10-6 |
|
Alpha-Bromo-3'-Nitroacetophenone, 97%
| 2227-64-7 |
|
D(-)-Salicin, 99+%
| 138-52-3 |
|
Palatine Fast Yellow Bln
| 10127-05-6 |
|
3,3-Dichloro-2-Hydroxytetrahydropyran, 99+%
| 0-00-1 |
|
Ethyl isodehydracetate, 97%
| 3385-34-0 |
|
1-(3-Chloropropyl)-1,3-dihydro-2H-benzimidazol-2-one, balance mainly
| 62780-89-6 |
|
4-Amino-1,1-diethoxy-2-butyne, 96%
| 124744-14- |
|
2-Amino-3-Chloro-5-Trifluoromethylpyridine 98%
| 79456-26-1 |
|
m-Xylylenediamine, 99%
| 1477-55-0 |
|
Allyl methyl sulfide, 99%
| 10152-76-8 |
|
5-Bromo-2-Fluorobenzonitrile, 97%
| 179897-89-3 |
|
2,9-Dimethyl-4,7-Diphenyl-1,10-Phenanthroline, 98%
| 4733-39-5 |
|
Poly(butadiene), phenyl terminated
| 25038-44-2 |
|
2-tert-Butylphenol, 99%
| 88-18-6 |
|
D(+)-Fucose, 99%
| 3615-37-0 |
|
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| 119-93-7 |
|
1-Bromopentadecane, 98%
| 629-72-1 |
|
Piperazine hexahydrate, 98%
| 142-63-2 |
|
4-(5)-Nitroindan, Mixture
| |
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Ouabain Octahydrate, 96.0 -104.0% (On the Anhydrous Substance)
| 11018-89-6 |
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Homovanillyl alcohol, 99%
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| 822-36-6 |
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| 16595-80-5 |
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| 107-88-0 |
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