**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4392-24-9 |Cinnamyl Bromide | 95-97% | 224-511-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Lachrymator
(substance which increases the flow of tears).
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury. Lachrymator
(substance which increases the flow of tears). May cause chemical
conjunctivitis and corneal damage.
Skin:
Causes skin irritation. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Can produce delayed
pulmonary edema. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Will burn if involved in a fire. Use water spray to keep
fire-exposed containers cool. Combustible solid. Containers may
explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Use a spark-proof tool. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Avoid breathing dust,
vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep container tightly closed. Keep away from heat,
sparks and flame. Avoid ingestion and inhalation. Wash clothing
before reuse. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Keep refrigerated. (Store below 4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 4392-24-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: light yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 103 deg C @ 22.00mmHg
Freezing/Melting Point: 26 - 29 deg C
Autoignition Temperature: Not available.
Flash Point: 87 deg C ( 188.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.3320g/cm3
Molecular Formula: C6H5CH=CHCH2Br
Molecular Weight: 197.07
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4392-24-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Cinnamyl Bromide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 4392-24-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 4392-24-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4392-24-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/01/1998 Revision #5 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(S)-(+)-6,6'-Dibromo-1,1'-Bi-2-Naphthol, 99%
| 80655-81-8 |
|
1,10-Decanediol, 96%
| 112-47-0 |
|
1,10-Decanediol, 99%
| 112-47-0 |
|
Norit SA II
| 7440-44-0 |
|
(R)-(-)-6,6'-Dibromo-1,1'-Bi-2-Naphthol, 99%
| 65283-60-5 |
|
N-((2S, 3R)-3-Amino-2-hydroxy-4-phenylbutyryl)-L-leucine, 95%
| 0-01-1 |
|
3-(2-Naphthyl)-L-Alanine, 98%
| 0-01-1 |
|
(2R)-2-[(4-Ethyl-2,3-dioxopiperazinyl)carbonylamino]-2-phenylacetic
| 63422-71-9 |
|
Adenosine 5'-Triphosphate Disodium Salt Trihydrate
| 51963-61-2 |
|
N,N-Dichlorourethane, 98%
| 13698-16-3 |
|
cis-Decahydronaphthalene-d18, 99.5 atom % D, 97% cis, 3% trans
| 91-17-8 |
|
Adipic acid
| 124-04-9 |
|
4,6-Diaminoresorcinol dihydrochloride, 98%
| 15791-87-4 |
|
1,3-Diiminoisoindoline, 97%
| 57500-34-2 |
|
Carbon Disulfide, P.A., Low in Benzene Content
| 75-15-0 |
|
2-[(4S)-2,2-Dimethyl-5-Oxo-1,3-Dioxolan-4-yl]Acetic Acid
| 73991-95-4 |
|
Carnauba wax (flakes)
| 8015-86-9 |
|
Castor Oil
| 8001-79-4 |
|
Pyrocatechol, 98% (Titr.)
| 120-80-9 |
|
OPD tablets, 2 mg/tablet
| 95-54-5 |
|
Ammonium cerium(IV) sulfate dihydrate
| 7637-03-8 |
|
(+/-)-Bay K 8644, 98%
| 71145-03-4 |
|
4-Nitrophenyl Bromoacetate, 98%
| 19199-82-7 |
|
Tetraethyl Ethylenediphosphonate, 97%
| 995-32-4 |
|
Cesium Chloride, 99.999%
| 7647-17-8 |
|
Boc-L-Isoleucine, 99+%
| 13139-16-7 |
|
Aerosol OT Solid
| 577-11-7 |
|
Bismuth(III) chloride, anhydrous, 98+%
| 7787-60-2 |
|
Glutaric Dialdehyde, 24 wt. % Solution in Water
| 111-30-8 |
|
Chlorobenzene, 99+%, Spectrophotometric Grade
| 108-90-7 |
|
4-(Aminomethyl)-Piperidine, 97%
| 7144-05-0 |
|
2-Chloromethylbenzimidazole
| 4857-04-9 |
|
Cinnamyl Bromide, predominantly trans.
| 4392-24-9 |
|
1,3-Diamino-2-Hydroxypropane
| 616-29-5 |
|
2,5-DICHLOROPHENOL
| 583-78-8 |
|
8-Bromoadenosine, 98%
| 2946-39-6 |
|
1-Phenyl-1,2-Ethanediol, 97%
| 93-56-1 |
|
2,6-Dimethoxybenzoyl Chloride
| 1989-53-3 |
|
2-Amino-5-Methylbezoic Acid, 97%
| 2941-78-8 |
|
Diethyl(Chloromethyl)Phosphonate
| 3167-63-3 |
|
Diethyl(Phenylthiomethyl)Phosphonate
| 38066-16-9 |
|
Trimethyl 4-Phosphonocrotonate
| 86120-40-3 |
|
9H-Fluorene-9-Acetic Acid
| 6284-80-6 |
|
5-Amino-2-Nitrobenzoic Acid, 97%
| 132080-60-5 |
|
4-Bromoindole
| 52488-36-5 |
|
Diethyl(aminomethyl)phosphonate oxalate, 95%
| 117196-73-3 |
|
Diethyl(aminoethyl)phosphonate oxalate
| 203192-98-7 |
|
Diethyl(aminopropyl)phosphonate oxalate
| 0-01-1 |
|
Diethyl(aminobutyl)phosphonate oxalate
| 0-01-1 |
|
Diethyl(4-Chlorobenzyl)Phosphonate
| 39225-17-7 |
|
|