**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7787-60-2 |Bismuth(III) chloride, anhydrous | >98 | 232-123-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Hygroscopic (absorbs moisture from the
air).Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause corrosion and permanent tissue destruction of the
esophagus and digestive tract.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema.
Causes severe irritation of upper respiratory tract with coughing,
burns, breathing difficulty, and possible coma. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
Repeated or prolonged exposure may cause a bismuth line or black
spots on the gums, foul breath and salivation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Substance
may react with water, and may release corrosive and/or toxic gases.
Extinguishing Media:
Use dry chemical to fight fire. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation. Do
not get water on spilled substances or inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Do not ingest or inhale. Keep from contact
with moist air and steam.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep away from water. Keep away from metals. Corrosives
area. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Local exhaust ventilation may be necessary to control any air
contaminants to within their TLVs during the use of this product.
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Exposure Limits
CAS# 7787-60-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white to yellow
Odor: hydrochloric odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 447 deg C
Freezing/Melting Point: 230 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: sublimes @430C
Solubility in water: Decomposes in water.
Specific Gravity/Density: 4.56-4.75
Molecular Formula: BiCl3
Molecular Weight: 315.33
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Forms hydrochloric acid with water.
Conditions to Avoid:
Dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Aluminum, potassium, sodium, perchloric acid.
Hazardous Decomposition Products:
Hydrogen chloride.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7787-60-2: EB2690000
LD50/LC50:
CAS# 7787-60-2: Oral, mouse: LD50 = 2250 mg/kg; Oral, rat: LD50 =
3334 mg/kg.
Carcinogenicity:
Bismuth(III) chloride, anhydrous -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Corrosive Solid, Acidic, Inorganic, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing Group: II
IMO
Shipping Name: Corrosive Solid, Acidic, Inorganic, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing Group: II
RID/ADR
Shipping Name: Corrosive Solid, Acidic, Inorganic, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 7787-60-2: No information available.
Canada
CAS# 7787-60-2 is listed on Canada's DSL List.
CAS# 7787-60-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7787-60-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/01/1997 Revision #3 Date: 5/29/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(S)-(+)-6,6'-Dibromo-1,1'-Bi-2-Naphthol, 99%
| 80655-81-8 |
|
1,10-Decanediol, 96%
| 112-47-0 |
|
1,10-Decanediol, 99%
| 112-47-0 |
|
Norit SA II
| 7440-44-0 |
|
(R)-(-)-6,6'-Dibromo-1,1'-Bi-2-Naphthol, 99%
| 65283-60-5 |
|
N-((2S, 3R)-3-Amino-2-hydroxy-4-phenylbutyryl)-L-leucine, 95%
| 0-01-1 |
|
3-(2-Naphthyl)-L-Alanine, 98%
| 0-01-1 |
|
(2R)-2-[(4-Ethyl-2,3-dioxopiperazinyl)carbonylamino]-2-phenylacetic
| 63422-71-9 |
|
Adenosine 5'-Triphosphate Disodium Salt Trihydrate
| 51963-61-2 |
|
N,N-Dichlorourethane, 98%
| 13698-16-3 |
|
cis-Decahydronaphthalene-d18, 99.5 atom % D, 97% cis, 3% trans
| 91-17-8 |
|
Adipic acid
| 124-04-9 |
|
4,6-Diaminoresorcinol dihydrochloride, 98%
| 15791-87-4 |
|
1,3-Diiminoisoindoline, 97%
| 57500-34-2 |
|
Carbon Disulfide, P.A., Low in Benzene Content
| 75-15-0 |
|
2-[(4S)-2,2-Dimethyl-5-Oxo-1,3-Dioxolan-4-yl]Acetic Acid
| 73991-95-4 |
|
Carnauba wax (flakes)
| 8015-86-9 |
|
Castor Oil
| 8001-79-4 |
|
Pyrocatechol, 98% (Titr.)
| 120-80-9 |
|
OPD tablets, 2 mg/tablet
| 95-54-5 |
|
Ammonium cerium(IV) sulfate dihydrate
| 7637-03-8 |
|
(+/-)-Bay K 8644, 98%
| 71145-03-4 |
|
4-Nitrophenyl Bromoacetate, 98%
| 19199-82-7 |
|
Tetraethyl Ethylenediphosphonate, 97%
| 995-32-4 |
|
Cesium Chloride, 99.999%
| 7647-17-8 |
|
Boc-L-Isoleucine, 99+%
| 13139-16-7 |
|
Aerosol OT Solid
| 577-11-7 |
|
Bismuth(III) chloride, anhydrous, 98+%
| 7787-60-2 |
|
Glutaric Dialdehyde, 24 wt. % Solution in Water
| 111-30-8 |
|
Chlorobenzene, 99+%, Spectrophotometric Grade
| 108-90-7 |
|
4-(Aminomethyl)-Piperidine, 97%
| 7144-05-0 |
|
2-Chloromethylbenzimidazole
| 4857-04-9 |
|
Cinnamyl Bromide, predominantly trans.
| 4392-24-9 |
|
1,3-Diamino-2-Hydroxypropane
| 616-29-5 |
|
2,5-DICHLOROPHENOL
| 583-78-8 |
|
8-Bromoadenosine, 98%
| 2946-39-6 |
|
1-Phenyl-1,2-Ethanediol, 97%
| 93-56-1 |
|
2,6-Dimethoxybenzoyl Chloride
| 1989-53-3 |
|
2-Amino-5-Methylbezoic Acid, 97%
| 2941-78-8 |
|
Diethyl(Chloromethyl)Phosphonate
| 3167-63-3 |
|
Diethyl(Phenylthiomethyl)Phosphonate
| 38066-16-9 |
|
Trimethyl 4-Phosphonocrotonate
| 86120-40-3 |
|
9H-Fluorene-9-Acetic Acid
| 6284-80-6 |
|
5-Amino-2-Nitrobenzoic Acid, 97%
| 132080-60-5 |
|
4-Bromoindole
| 52488-36-5 |
|
Diethyl(aminomethyl)phosphonate oxalate, 95%
| 117196-73-3 |
|
Diethyl(aminoethyl)phosphonate oxalate
| 203192-98-7 |
|
Diethyl(aminopropyl)phosphonate oxalate
| 0-01-1 |
|
Diethyl(aminobutyl)phosphonate oxalate
| 0-01-1 |
|
Diethyl(4-Chlorobenzyl)Phosphonate
| 39225-17-7 |
|
|