**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4870-65-9 |DL-ALPHA-BROMOPHENYLACETIC ACID | | 225-477-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). Lachrymator (substance which increases the flow of
tears).
Skin:
Causes skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
Causes respiratory tract irritation. Inhalation may be fatal as a
result of spasm, inflammation, edema of the larynx and bronchi,
chemical pneumonitis and pulmonary edema.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
and eyes. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 4870-65-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: light yellow to green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 82 - 83 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H7BrO2
Molecular Weight: 215.05
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4870-65-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
DL-ALPHA-BROMOPHENYLACETIC ACID -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 4870-65-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 4870-65-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4870-65-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Hydroxy-4-iodobenzoic acid, 97%
| 58123-77-6 |
|
Ethyl 1-cyclopropyl-4-formyl-2,5-dimethyl-1h-pyrrole-3-carboxylate,
| 423768-53-0 |
|
5-Chloro-3-methyl-1-benzothiophene-2-carboxylic acid, tech
| 50451-84-8 |
|
Tri-(2-Furyl)Phosphine, 98%
| 5518-52-5 |
|
4-[(4-Chlorophenyl)sulfonyl]-3-thiophenecarboxylic acid, 97%
| 423769-77-1 |
|
5-(Dihydroxyboryl)-2-thiophenecarboxylic acid, 95+%
| 465515-31-5 |
|
tert-Butyl n-[(5-bromo-2-thienyl)methyl]carbamate, 97%
| 215183-27-0 |
|
4-Acetyl-1-cyclopropyl-2,5-dimethyl-1h-pyrrole-3-carboxylic acid, 97%
| 423769-78-2 |
|
2-Bromo-1-[2-(trifluoromethyl)phenyl]-1-ethanone, 95+%
| 54109-16-9 |
|
Methyl 5-(chlorosulfonyl)-4-methyl-2-thiophenecarboxylate, 97%
| 423768-46-1 |
|
[5-[1-Methyl-5-(trifluoromethyl)-1h-pyrazol-3-yl]-2-thienyl]methanol,
| 465514-19-6 |
|
5-Nitro-1-benzothiophene-2-carboxylic acid, 97%
| 6345-55-7 |
|
Methyl 3-(chlorosulfonyl)-4-(isopropylsulf
| 423768-47-2 |
|
4-[4-(Trifluoromethyl)phenyl]-1,2,3-thiadiazol-5-amine, 97%
| 423769-76-0 |
|
Dl-alpha-bromophenylacetic acid, 99.5%
| 4870-65-9 |
|
Lead atomic absorption standard solution, 1 mg/ml Pb in 2% HNO3
| 7439-92-1 |
|
Methyl 5-formyl-2-methyl-3-furoate, 97%
| 81661-26-9 |
|
2-Bromo-1-[3-(trifluoromethyl)phenyl]-1-ethanone, tech
| 2003-10-3 |
|
Ethyl 4-acetyl-1-cyclopropyl-2,5-dimethyl-1h-pyrrole-3-carboxylate,
| 423768-51-8 |
|
3-(Aminomethyl)-N,N-dimethyltetrahydro-3-thiophenamine, 97%
| 176445-79-7 |
|
3-(2-Methyl-4-pyrimidinyl)benzenesulfonyl chloride, 90+%
| 465514-07-2 |
|
4-Bromo-1,3-dimethyl-1h-pyrazole-5-carboxylic acid, 97%
| 5775-88-2 |
|
3,5-Dimethyl-1-phenyl-1h-pyrazole-4-carboxylic acid, 97%
| 61226-19-5 |
|
Ethyl 2-bromo-4-methyl-1,3-thiazole-5-carboxylate, 97%
| 22900-83-0 |
|
2-Bromo-4-methyl-1,3-thiazole-5-carboxylic acid, 97%
| 40003-41-6 |
|
2-Cyano-5-methylbenzenesulfonyl chloride, 97%
| 197960-31-9 |
|
3-Aminothieno[2,3-b]pyridine-2-carboxylic acid, 97%
| 58327-75-6 |
|
(S)-(-)-N,N-Dimethyl-1-Phenethylamine, 99+%
| 17279-31-1 |
|
[1-(4-Fluorophenyl)-5-methyl-1h-pyrazol-4-yl]methanol, 97%
| 465514-37-8 |
|
6-Chloro-imidazo[2,1-b]thiazole-5-sulfonic acid amide, 97%
| 112582-89-5 |
|
Ethyl 2-(chlorosulfonyl)-4-methyl-1,3-thiazole-5-carboxylate, 97%
| 89694-92-8 |
|
4-Methyl-thiazole-5-carboxylic acid, 97%
| 20485-41-0 |
|
2,3-Dihydroxy-benzoic acid ethyl ester, 97%
| 3943-73-5 |
|
Benzyl 4-hydroxytetrahydro-1(2h)-pyridinecarboxylate, 97+%
| 95798-23-5 |
|
Diethylene Glycol
| 111-46-6 |
|
2,3-Dihydro-1,4-benzodioxine-5-carboxamide, 97%
| 349550-81-8 |
|
1H-Benzimidazol-4-ylboronic acid, 97%
| 499769-95-8 |
|
4-Iodo-2-methyl-1h-imidazole, 97%
| 73746-45-9 |
|
1-Benzyl-1h-indol-5-ylamine, 97%
| 26807-73-8 |
|
1,3-Dinitrobenzene
| 99-65-0 |
|
3-(Benzyloxy)-4-methylphenylamine, 97%
| 219492-12-3 |
|
5-(Benzyloxy)-2-bromo-4-methylaniline, 97%
| 499770-88-6 |
|
4-(Bromomethyl)-1-methyl-1,2,3,6-tetrahydropyridine, 97%
| 499770-89-7 |
|
Bis(2-methoxyethyl) Ether
| 111-96-6 |
|
2,6-Dichloro-4-(chloromethyl)pyridine, tech
| 101990-72-1 |
|
4-(Benzyloxy)-3-fluorophenylboronic acid, 97%
| 133057-83-7 |
|
4-(Benzyloxy)-2-fluorophenylboronic acid, 97%
| 166744-78-1 |
|
5-Cyano-2-thienylboronic acid, 97%
| 305832-67-1 |
|
Alpha, Alpha, Alpha-Trifluoro-P-Tolualdehyde, 95%
| 455-19-6 |
|
5-(Methylsulfanyl)-2-thienylboronic acid, 97%
| 499769-93-6 |
|
|