**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 50-14-6 |Ergocalciferol | 99 | 200-014-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 28
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic if swallowed.Air sensitive.Light sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May be fatal if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause weight loss and
irritability.
Inhalation:
May cause effects similar to those described for ingestion. Causes
irritation of the mucous membrane and upper respiratory tract.
Chronic:
Chronic exposure may cause reproductive disorders and teratogenic
effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure. Destroy contaminated shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Induce vomiting only when instructed to do so by a
physician.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively. Effects may be delayed.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Wash area with soap and water. Clean up spills immediately,
observing precautions in the Protective Equipment section. Sweep up,
then place into a suitable container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Do not
ingest or inhale. Store protected from light. Store protected from
air. Use only in a chemical fume hood.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Poison room locked/refrigerator. Keep containers tightly
closed. Store protected from light and air. Store under nitrogen.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits. Use only under a chemical fume hood.
Exposure Limits
CAS# 50-14-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white to yellow white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Sublimes
Freezing/Melting Point: 115 - 119 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: Not available.
Molecular Formula: C28H44O
Molecular Weight: 396.65
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Decomposes on
exposure to air and light.
Conditions to Avoid:
Incompatible materials, light, exposure to air, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, air, direct
light.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 50-14-6: KE1050000
LD50/LC50:
CAS# 50-14-6: Oral, mouse: LD50 = 23700 ug/kg; Oral, rat: LD50 = 10
mg/kg.
Oral, woman: TDLo = 12600 ug/kg/72W (Anorexia, nausea, vomiting,
weight
Carcinogenicity:
Ergocalciferol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 28 Very toxic if swallowed.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 50-14-6: 2
Canada
CAS# 50-14-6 is listed on Canada's DSL List.
CAS# 50-14-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 50-14-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/21/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Piperonal, 99%
| 120-57-0 |
|
5-Chlorouracil, 99%
| 1820-81-1 |
|
Benzáa??anthracene-7,12-dione, 97% (uv-vis)
| 2498-66-0 |
|
(3,4-Dimethoxyphenyl)acetic acid, 99%
| 93-40-3 |
|
1-Naphthaleneacetamide, 98%
| 86-86-2 |
|
Chlorosulfonyl isocyanate, 98+%
| 1189-71-5 |
|
4-Chloro-4'-Fluorobutyrophenone, 97+% (GC)
| 3874-54-2 |
|
Vitamin d2 (calciferol),99% (hplc)
| 50-14-6 |
|
Diethyl Phosphonoacetaldehyde Diethyl Acetal, Tech. 90%
| 7598-61-0 |
|
3,5-Dimethoxyacetophenone, 97%
| 39151-19-4 |
|
Palladium on Activated Carbon (5% Pd)
| |
|
Cyclododecene, Tech., Predominantly Trans
| 1501-82-2 |
|
4-Hydroxy-6-methyl-2-pyrone
| 675-10-5 |
|
Benzoyl bromide, 97%
| 618-32-6 |
|
Prostaglandin e1, 98+%
| 745-65-3 |
|
4,4'-Dimethylbenzil, 99+%
| 3457-48-5 |
|
Chrysoidin
| 532-82-1 |
|
d-Limonene
| 5989-27-5 |
|
Mitomycin C (Contains 2mg Mitomycin C and 48mg Sodium Chloride)
| 50-07-7 |
|
Butyl methacrylate/isobutyl methacrylate copolymer, high molecular
| 9011-53-4 |
|
Bis-(2-Methylallyl)Cycloocta-1,5-Diene Ruthenium(II) Complex
| 0-00-1 |
|
d-Lysergic acid hydrate, 95% *** controled product kb 11.6.87 ***
| 82-58-6 |
|
2-Bromo-1-Indanol, 99%
| 5400-80-6 |
|
Ruthenium(IV) oxide hydrate
| 32740-79-7 |
|
2-Chlorocyclohexanol, Tech., 90%
| 1561-86-0 |
|
5-Amino-2,2,4-Trimethyl-1-Cyclopentane-Methylamine, 99%, Mixture of
| 67907-32-8 |
|
2,3,4-Trimethoxybenzoic acid, 98+%
| 573-11-5 |
|
1,3-Dibromo-5,5-dimethylhydantoin, 98%
| 77-48-5 |
|
Dicumarol, 99%
| 66-76-2 |
|
Tetraphenylphosphonium Chloride 99%
| 2001-45-8 |
|
Benzo[k]fluoranthene, 99+% (tlc)
| 207-08-9 |
|
Dihexylamine, 99+% (GC)
| 143-16-8 |
|
Propargyl Alcohol, 99%
| 107-19-7 |
|
Borane-tert-butylamine complex, powder
| 7337-45-3 |
|
Tri-n-butyltin methoxide, 97%
| 1067-52-3 |
|
5-Methoxyindole-3-Carboxaldehyde, 99+%
| 10601-19-1 |
|
2,4-Dichlorophenoxyacetic acid
| 94-75-7 |
|
4-Phenylpyridine, 99%
| 939-23-1 |
|
2-Naphthalenesulfonic acid hydrate, 99%
| 120-18-3 |
|
Benzanthrone, 99%
| 82-05-3 |
|
Tripentylamine, 99%
| 621-77-2 |
|
BOC-D-Arginine Hydrochloride, Hydrate, 99%
| 114622-81-0 |
|
Phenylphosphonothioic dichloride, 97%
| 3497-00-5 |
|
3,3,5,5-Tetramethylpyrroline-N-Oxide, 98%
| 10135-38-3 |
|
1-(2-Aminoethyl)-2-Methyl-5-Nitroimidazole Dihydrochloride
| 49575-10-2 |
|
Bis(2-ethylhexyl) adipate
| 103-23-1 |
|
M-Tolyl Acetate
| 122-46-3 |
|
1,4-Dioxa-8-azaspiro(4.5)decane, 98%
| 177-11-7 |
|
DL-Homocysteinethiolactone Hydrochloride, 99%
| 6038-19-3 |
|
Ethyl Benzoate, 99+%
| 93-89-0 |
|
|