**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 592-57-4 |1,3-Cyclohexadiene | 99 | 209-764-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to respiratory system.Stench.Highly
flammable.The toxicological properties of this material have not been
fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause cardiac disturbances. The toxicological
properties of this substance have not been fully investigated.
Ingestion of large amounts may cause CNS depression.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Aspiration may lead
to pulmonary edema. Vapors may cause dizziness or suffocation. May
cause burning sensation in the chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Flammable liquid
and vapor. Vapors may be heavier than air. They can spread along
the ground and collect in low or confined areas. Will be easily
ignited by heat, sparks or flame. Containers may explode if exposed
to fire. Runoff from fire control or dilution water may cause
pollution.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Water may be ineffective. Water may spread
fire. If water is the only media available, use in flooding amounts.
Use agent most appropriate to extinguish fire. For large fires, use
water spray, fog or alcohol-resistant foam. Do NOT use straight
streams of water. Cool containers with flooding quantities of water
until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat and flame. Keep away from sources of ignition.
Store in a tightly closed container. Flammables-area.
Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 592-57-4:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles. Wear appropriate
protective eyeglasses or chemical safety goggles as
described by OSHA's eye and face protection
regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 80 deg C
Freezing/Melting Point: -98 deg C
Autoignition Temperature: Not available.
Flash Point: -6 deg C ( 21.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Immiscible.
Specific Gravity/Density: .8410g/cm3
Molecular Formula: C6H8
Molecular Weight: 80.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 592-57-4: GU4702350
LD50/LC50:
CAS# 592-57-4: Inhalation, mouse: LC50 = 45000 mg/m3/2H.
Carcinogenicity:
1,3-Cyclohexadiene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 37 Irritating to respiratory system.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 592-57-4: No information available.
Canada
CAS# 592-57-4 is listed on Canada's NDSL List.
CAS# 592-57-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 592-57-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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Trimethyl phosphite
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Lithium Hexafluorophosphate, 98%
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Methyl-1-benzyl-4-oxo-3-piperidine carboxylate hydrochloride, 97%
| 3939-01-3 |
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4-Methyl-2-pyrazolin-5-one, 98%
| 13315-23-6 |
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1-Bromo-3,4-difluorobenzene, 98%
| 348-61-8 |
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17-alpha-Hydroxy-16 beta-methylpregnenolone
| 13900-61-3 |
|
4-Hydroxy-2-Mercapto-6-Methylpyrimidine, 98%
| 56-04-2 |
|
alpha-Bromo-2,3,4,5,6-pentafluorotoluene, 97%
| 1765-40-8 |
|
Phloroglucide, 95+%
| 491-45-2 |
|
3,4-Methylenedioxycinnamic Acid, 99%, Predominantly Trans
| 2373-80-0 |
|
3-(2-Methoxyphenyl)-Propionic Acid 98%
| 6342-77-4 |
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Ethyl diphenylphosphinite, 99%
| 719-80-2 |
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2,3-Dichlorophenoxyacetic Acid
| 2976-74-1 |
|
Antipyrine, 99%
| 60-80-0 |
|
1,3,5,7-Cyclooctatetraene, 98% stabilzed with 0.1% hydroquinon
| 629-20-9 |
|
2',4',6'-Trimethylacetophenone, 98%
| 1667-01-2 |
|
n-Butyl phenyl ether, 99%
| 1126-79-0 |
|
4-Bromo-3,5-Dimethylphenol, 99%
| 7463-51-6 |
|
tert-Butyl isocyanide, 97% (gc)
| 7188-38-7 |
|
2',5'-Dichloroacetoacetanilide, 98% (uv-vis)
| 2044-72-6 |
|
L-(-)-Glucose, 98%
| 921-60-8 |
|
1-Hydroxy-N-(2-tetradecyloxyphenyl)-2- naphthalenecarboxamide, 98%
| 39163-92-3 |
|
2,3,4,5,6 -Pentafluorobenzamide, 99%
| 652-31-3 |
|
2-Chloro-6-Fluorobenzyl Alcohol, 97%
| 56456-50-9 |
|
2,2-Dimethyl-5-Phenyl-1,3-Dioxane-4,6-Dione, 98%
| 15231-78-4 |
|
Dl-alpha-aminocaprylic acid, 99% (titr.)
| 644-90-6 |
|
2,2-Dimethylbutane, 98%
| 75-83-2 |
|
N,N-Dimethyl-5-Methoxytryptamine, 99%
| 1019-45-0 |
|
Isobutylbenzene, 99.5%
| 538-93-2 |
|
4'-Chloroacetophenone, 95% (GC)
| 99-91-2 |
|
1-Methylnaphthalene, 97%
| 90-12-0 |
|
Ethyl chloroformate
| 541-41-3 |
|
Remazol Brilliant Blue R
| 2580-78-1 |
|
Tris(2,2,6,6-Tetramethyl-3,5-Heptane-Dionato)Ytterbium, 99+%
| 15492-52-1 |
|
Histamine, 96% (titr.)
| 51-45-6 |
|
Dl-valine, 99+%
| 516-06-3 |
|
2,3,6-Trichlorophenol, 99%
| 933-75-5 |
|
(2R)-(-)-Glycidyl Tosylate, 99+%
| 113826-06-5 |
|
6-Chloro-1-Hexanol, 90% (GC)
| 2009-83-8 |
|
2-Nitrophenylselenocyanate, 99%
| 51694-22-5 |
|
Alizarin Yellow GG
| 584-42-9 |
|
1,2-Dipiperidinoethane, 98%
| 1932-04-3 |
|
Succinaldehyde Disodium Bisulfite
| 5450-96-4 |
|
(+)-Griseofulvin, 97%
| 126-07-8 |
|
N-Allylrhodanine
| 1457-47-2 |
|
Acid Blue 92
| 3861-73-2 |
|
2,3,5-Trimethylpyrazine, 99%
| 14667-55-1 |
|
1,3-Cyclohexadiene, 99% (GC)
| 592-57-4 |
|
4-Chlorothiophenol, 98%
| 106-54-7 |
|
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| 5691-09-8 |
|
|